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Amines: AQA A‑Level Chemistry questions

Every AQA A-Level Chemistry exam question on 3.3.11 Amines, 2016–2025, with its mark scheme and examiner’s report.

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2,301 questions

  1. Q07

    June 2025 · Paper 3

    The whole paper ↗
    June 2025 Paper 3, question 07: The reaction between methylamine (CH3NH2) and excess bromoethane (C2H5Br) produces a quaternary ammonium salt. What is the formula for the cation in this salt?
  2. Q35

    June 2025 · Paper 3

    The whole paper ↗
    June 2025 Paper 3, question 35: Which compound can be used as a cationic surfactant? [1 mark] A [C16H33N(CH3)3]Br B C16H33N(CH3)2 C C17H35COONa D C17H35COOH
  3. Q09.1

    June 2024 · Paper 2

    The whole paper ↗
    June 2024 Paper 2, question 09.1: An incomplete equation for Step 1 in the reaction between bromoethane and an amine is shown. Complete the equation. In Step 2 of this reaction, the product of S
  4. Q09.2

    June 2024 · Paper 2

    The whole paper ↗
    June 2024 Paper 2, question 09.2: CH3CHBrCH2CH3 reacts with NH3 Draw the skeletal formula of the major organic product formed when • an excess of NH3 is used • an excess of CH3CHBrCH2CH3 is used
  5. Q09.3

    June 2024 · Paper 2

    The whole paper ↗
    June 2024 Paper 2, question 09.3: Figure 3 shows a two-step synthesis to make amine G. Figure 3 Complete Figure 3 by drawing the mechanism for Step 1 and the displayed formula of amine G. [3 mar
  6. Q09.4

    June 2024 · Paper 2

    The whole paper ↗
    June 2024 Paper 2, question 09.4: Figure 4 shows two amines, P and Q. Figure 4 Explain why P is a stronger base than Q. [2 marks]
  7. Q10.4

    June 2024 · Paper 2

    The whole paper ↗
    June 2024 Paper 2, question 10.4: State the reagent(s) needed for Step 2. [1 mark]
  8. Q10.5

    June 2024 · Paper 2

    The whole paper ↗
    June 2024 Paper 2, question 10.5: State a possible use for the amine formed in Step 2. [1 mark]
  9. Q04.4

    June 2023 · Paper 2

    The whole paper ↗
    June 2023 Paper 2, question 04.4: State the reagent and reaction conditions needed for reaction 3. Give an equation for reaction 3. [2 marks] Reagent and conditions Equation
  10. Q34

    June 2023 · Paper 3

    The whole paper ↗
    June 2023 Paper 3, question 34: Which compound is the strongest base? [1 mark] A B C NH3 D NH4Cl
  11. Q10.4

    June 2022 · Paper 2

    The whole paper ↗
    June 2022 Paper 2, question 10.4: Amine A is formed in step 2 and amine B is formed in step 5. Explain why the yield of B in step 5 is less than the yield of A in step 2. [2 marks]
  12. Q10.5

    June 2022 · Paper 2

    The whole paper ↗
    June 2022 Paper 2, question 10.5: Explain why amine B is a stronger base than amine A. [2 marks]
  13. Q02.4

    November 2021 · Paper 2

    The whole paper ↗
    November 2021 Paper 2, question 02.4: Compound Z (HOCH2CH2NH2) can be used to remove carbon dioxide from the mixture of waste gases produced in some power stations. Figure 1 shows part of a suggeste
  14. Q30

    November 2021 · Paper 3

    The whole paper ↗
    November 2021 Paper 3, question 30: A two-step preparation of propylamine is shown. bromoethane → X → propylamine What is X? [1 mark] A CH3CH2CH2NH2 B CH3CH2CN C CH3CH2CH2Br D CH3CH2NH2
  15. Q32

    November 2021 · Paper 3

    The whole paper ↗
    November 2021 Paper 3, question 32: Methylamine reacts with bromoethane by nucleophilic substitution to produce a mixture of products. Which is not a possible product of this reaction? [1 mark] A
  16. Q05.2

    November 2020 · Paper 2

    The whole paper ↗
    November 2020 Paper 2, question 05.2: Outline the mechanism for the reaction of 2-bromopropane with an excess of ammonia. [4 marks]
  17. Q05.3

    November 2020 · Paper 2

    The whole paper ↗
    November 2020 Paper 2, question 05.3: Draw the skeletal formula of the main organic species formed in the reaction between a large excess of 2-bromopropane and ammonia. Give a use for the organic pr
  18. Q01.1

    June 2019 · Paper 2

    The whole paper ↗
    June 2019 Paper 2, question 01.1: Give an equation for the preparation of 1,6-diaminohexane by the reaction of 1,6-dibromohexane with an excess of ammonia. [2 marks]
  19. Q01.2

    June 2019 · Paper 2

    The whole paper ↗
    June 2019 Paper 2, question 01.2: Complete the mechanism for the reaction of ammonia with 6-bromohexylamine to form 1,6-diaminohexane. Suggest the structure of a cyclic secondary amine that can
  20. Q01.3

    June 2019 · Paper 2

    The whole paper ↗
    June 2019 Paper 2, question 01.3: 1,6-Diaminohexane can also be formed in a two-stage synthesis starting from 1,4-dibromobutane. Suggest the reagent and a condition for each stage in this altern
All 35 questions on Amines, as a list
  1. June 2025, Paper 3, Q07 (1 mark): The reaction between methylamine (CH3NH2) and excess bromoethane (C2H5Br) produces a quaternary ammonium salt. What is the formula for the cation in this salt?
  2. June 2025, Paper 3, Q35 (1 mark): Which compound can be used as a cationic surfactant? [1 mark] A [C16H33N(CH3)3]Br B C16H33N(CH3)2 C C17H35COONa D C17H35COOH
  3. June 2024, Paper 2, Q09.1 (2 marks): An incomplete equation for Step 1 in the reaction between bromoethane and an amine is shown. Complete the equation. In Step 2 of this reaction, the product of S
  4. June 2024, Paper 2, Q09.2 (2 marks): CH3CHBrCH2CH3 reacts with NH3 Draw the skeletal formula of the major organic product formed when • an excess of NH3 is used • an excess of CH3CHBrCH2CH3 is used
  5. June 2024, Paper 2, Q09.3 (3 marks): Figure 3 shows a two-step synthesis to make amine G. Figure 3 Complete Figure 3 by drawing the mechanism for Step 1 and the displayed formula of amine G. [3 mar
  6. June 2024, Paper 2, Q09.4 (2 marks): Figure 4 shows two amines, P and Q. Figure 4 Explain why P is a stronger base than Q. [2 marks]
  7. June 2024, Paper 2, Q10.4 (1 mark): State the reagent(s) needed for Step 2. [1 mark]
  8. June 2024, Paper 2, Q10.5 (1 mark): State a possible use for the amine formed in Step 2. [1 mark]
  9. June 2023, Paper 2, Q04.4 (2 marks): State the reagent and reaction conditions needed for reaction 3. Give an equation for reaction 3. [2 marks] Reagent and conditions Equation
  10. June 2023, Paper 3, Q34 (1 mark): Which compound is the strongest base? [1 mark] A B C NH3 D NH4Cl
  11. June 2022, Paper 2, Q10.4 (2 marks): Amine A is formed in step 2 and amine B is formed in step 5. Explain why the yield of B in step 5 is less than the yield of A in step 2. [2 marks]
  12. June 2022, Paper 2, Q10.5 (2 marks): Explain why amine B is a stronger base than amine A. [2 marks]
  13. November 2021, Paper 2, Q02.4 (4 marks): Compound Z (HOCH2CH2NH2) can be used to remove carbon dioxide from the mixture of waste gases produced in some power stations. Figure 1 shows part of a suggeste
  14. November 2021, Paper 3, Q30 (1 mark): A two-step preparation of propylamine is shown. bromoethane → X → propylamine What is X? [1 mark] A CH3CH2CH2NH2 B CH3CH2CN C CH3CH2CH2Br D CH3CH2NH2
  15. November 2021, Paper 3, Q32 (1 mark): Methylamine reacts with bromoethane by nucleophilic substitution to produce a mixture of products. Which is not a possible product of this reaction? [1 mark] A
  16. November 2020, Paper 2, Q05.2 (4 marks): Outline the mechanism for the reaction of 2-bromopropane with an excess of ammonia. [4 marks]
  17. November 2020, Paper 2, Q05.3 (2 marks): Draw the skeletal formula of the main organic species formed in the reaction between a large excess of 2-bromopropane and ammonia. Give a use for the organic pr
  18. June 2019, Paper 2, Q01.1 (2 marks): Give an equation for the preparation of 1,6-diaminohexane by the reaction of 1,6-dibromohexane with an excess of ammonia. [2 marks]
  19. June 2019, Paper 2, Q01.2 (4 marks): Complete the mechanism for the reaction of ammonia with 6-bromohexylamine to form 1,6-diaminohexane. Suggest the structure of a cyclic secondary amine that can
  20. June 2019, Paper 2, Q01.3 (3 marks): 1,6-Diaminohexane can also be formed in a two-stage synthesis starting from 1,4-dibromobutane. Suggest the reagent and a condition for each stage in this altern
  21. June 2019, Paper 2, Q01.4 (2 marks): Explain why 3-aminopentane is a stronger base than ammonia. [2 marks]
  22. June 2019, Paper 2, Q08.2 (1 mark): Complete the equation for the reaction in Step 2. [1 mark]
  23. June 2019, Paper 3, Q27 (1 mark): Methylamine reacts with bromoethane by substitution to produce a mixture of products. Which compound is not a possible product of this reaction? [1 mark] A C2H5
  24. June 2018, Paper 2, Q10.2 (2 marks): There are three secondary amines that contain four carbon atoms per molecule. Draw the skeletal formulas of these three secondary amines. [2 marks]
  25. June 2018, Paper 2, Q10.3 (2 marks): Primary amines can be prepared by the reaction of halogenoalkanes with ammonia or by the reduction of nitriles. Justify the statement that it is better to prepa
  26. June 2018, Paper 2, Q10.4 (1 mark): Draw the structure of a primary amine with four carbon atoms that cannot be formed from a nitrile. [1 mark]
  27. June 2018, Paper 2, Q10.5 (2 marks): A student dissolves a few drops of propylamine in 1 cm3 of water in a test tube. Give an equation for the reaction that occurs. Describe what is observed when U
  28. June 2018, Paper 2, Q10.6 (2 marks): Phenylamine can be prepared by a process involving the reduction of nitrobenzene using tin and an excess of hydrochloric acid. Give an equation for the reductio
  29. June 2018, Paper 3, Q24 (1 mark): Aqueous solutions of ammonia, ethylamine and phenylamine are prepared. Each solution has the same concentration. Which is the correct order for the pH values of
  30. June 2017, Paper 2, Q01.2 (2 marks): Name the mechanism for Reaction 2 and give an essential condition used to ensure that CH3CH2CH2NH2 is the major product. [2 marks Name of mechanism Condition
  31. June 2017, Paper 2, Q01.4 (2 marks): When Reaction 2 is carried out under different conditions, a compound with molecular formula C9H21N is produced. Draw the skeletal formula of the compound. Iden
  32. June 2017, Paper 2, Q11.1 (6 marks): Amines E, F and G are weak bases. Explain the difference in base strength of the three amines and give the order of increasing base strength. [6 marks
  33. Specimen, Paper 2, Q06.3 (1 mark): Draw the structure of the species formed when glycine reacts with an excess of bromomethane. [1 mark] 0 6 . 3
  34. Specimen, Paper 2, Q09.8 (1 mark): 6
  35. Specimen, Paper 3, Q31: How many secondary amines have the molecular formula C4H11N? [1 mar A 2 B 3 C 4 D 5 3 1

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