Alkenes: AQA A‑Level Chemistry questions
Every AQA A-Level Chemistry exam question on 3.3.4 Alkenes, 2016–2025, with its mark scheme and examiner’s report.
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Q01.5
The whole paper ↗![June 2025 Paper 2, question 01.5: Identify the reagent and name the mechanism for reaction 3. [2 marks] Reagent Name of mechanism](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/74052-jun25-01-5-qp.webp)
Q02.3
The whole paper ↗
Q03.1
The whole paper ↗![June 2025 Paper 2, question 03.1: A section of the polymer PVC is shown. Name the monomer used to make PVC. Draw the structure of the monomer used to make PVC. [2 marks] Monomer name Structure](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/74052-jun25-03-1-qp.webp)
Q03.2
The whole paper ↗![June 2025 Paper 2, question 03.2: State why PVC is not biodegradable. [1 mark]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/74052-jun25-03-2-qp.webp)
Q03.3
The whole paper ↗


Q04.3
The whole paper ↗
Q06.1
The whole paper ↗![June 2025 AS Paper 2, question 06.1: Complete the equation for the conversion of cyclohexene to cyclohexanol in this reaction. [1 mark]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/74042-jun25-06-1-qp.webp)
Q06.2
The whole paper ↗![June 2025 AS Paper 2, question 06.2: Complete the mechanism for this reaction by adding curly arrows in the relevant places. [3 marks]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/74042-jun25-06-2-qp.webp)
Q08.1
The whole paper ↗![June 2024 Paper 2, question 08.1: Name the mechanism in Step 1. State the reagent(s) used for Step 1. [2 marks] Name of mechanism Reagent(s)](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/74052-jun24-08-1-qp.webp)
Q09.3
The whole paper ↗
Q04.2
The whole paper ↗![June 2024 AS Paper 2, question 04.2: Compound J reacts with hydrogen bromide to form compounds K and L. K is the major product. Name and outline the mechanism for the formation of K. [5 marks] Name](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/74042-jun24-04-2-qp.webp)
Q04.3
The whole paper ↗![June 2024 AS Paper 2, question 04.3: Explain why compound K is the major product in the reaction in Question 04.2. [3 marks]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/74042-jun24-04-3-qp.webp)
![June 2024 AS Paper 2, question 15: Which is the structure of poly(1-chloropropene)? [1 mark] A B C D](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/74042-jun24-15-qp.webp)
Q04.2
The whole paper ↗
![June 2023 Paper 3, question 31: Compound X can be converted into an alcohol in a two-stage process. What is the name of compound X? [1 mark] A propene B propanal C methylbenzene D ethanamide](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/74053-jun23-31-qp.webp)
Q04.1
The whole paper ↗
Q04.2
The whole paper ↗![June 2023 AS Paper 2, question 04.2: Draw the skeletal formula of the minor product formed in the reaction in Question 04.1. Explain why the products are formed in different amounts. [4 marks] Skel](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/74042-jun23-04-2-qp.webp)
Q04.3
The whole paper ↗![June 2023 AS Paper 2, question 04.3: Draw the structure of the major product when an excess of HBr reacts with limonene. [1 mark]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/74042-jun23-04-3-qp.webp)
All 78 questions on Alkenes, as a list
- June 2025, Paper 2, Q01.5 (2 marks): Identify the reagent and name the mechanism for reaction 3. [2 marks] Reagent Name of mechanism
- June 2025, Paper 2, Q02.3 (2 marks): Figure 1 shows part of the mechanism when L reacts with hydrogen bromide. Figure 1 Complete Figure 1 to show the next step in the mechanism that gives the major
- June 2025, Paper 2, Q03.1 (2 marks): A section of the polymer PVC is shown. Name the monomer used to make PVC. Draw the structure of the monomer used to make PVC. [2 marks] Monomer name Structure
- June 2025, Paper 2, Q03.2 (1 mark): State why PVC is not biodegradable. [1 mark]
- June 2025, Paper 2, Q03.3 (1 mark): Diisobutyl phthalate (DIBP) is a plasticiser added to PVC to modify its properties. State how the properties of PVC are modified by the addition of DIBP. [1 mar
- June 2025, Paper 3, Q13 (1 mark): Compound X reacts with concentrated sulfuric acid to produce compound Y. Compound Y reacts with an excess of water to produce an alcohol. Which compound could b
- June 2025, Paper 3, Q36 (1 mark): The hydration of 1-methylcyclopent-1-ene uses a catalyst of sulfuric acid and produces a mixture of products. Which ion is formed during the mechanism for this
- June 2025, AS Paper 2, Q04.3 (1 mark): Vinyl acetate (VA) has the molecular formula C4H6O2 The structure of vinyl acetate is shown. PVA is an addition polymer of vinyl acetate. Draw the repeating uni
- June 2025, AS Paper 2, Q06.1 (1 mark): Complete the equation for the conversion of cyclohexene to cyclohexanol in this reaction. [1 mark]
- June 2025, AS Paper 2, Q06.2 (3 marks): Complete the mechanism for this reaction by adding curly arrows in the relevant places. [3 marks]
- June 2024, Paper 2, Q08.1 (2 marks): Name the mechanism in Step 1. State the reagent(s) used for Step 1. [2 marks] Name of mechanism Reagent(s)
- June 2024, Paper 2, Q09.3 (3 marks): Figure 3 shows a two-step synthesis to make amine G. Figure 3 Complete Figure 3 by drawing the mechanism for Step 1 and the displayed formula of amine G. [3 mar
- June 2024, AS Paper 2, Q04.2 (5 marks): Compound J reacts with hydrogen bromide to form compounds K and L. K is the major product. Name and outline the mechanism for the formation of K. [5 marks] Name
- June 2024, AS Paper 2, Q04.3 (3 marks): Explain why compound K is the major product in the reaction in Question 04.2. [3 marks]
- June 2024, AS Paper 2, Q15 (1 mark): Which is the structure of poly(1-chloropropene)? [1 mark] A B C D
- June 2023, Paper 2, Q04.2 (6 marks): Reaction 1 produces a mixture of W and two other isomers. Draw the structures of the two other isomers. Explain, by considering the mechanism of this reaction,
- June 2023, Paper 3, Q31 (1 mark): Compound X can be converted into an alcohol in a two-stage process. What is the name of compound X? [1 mark] A propene B propanal C methylbenzene D ethanamide
- June 2023, AS Paper 2, Q04.1 (5 marks): 1-Methylcyclohexene reacts with HBr to form two structural isomers. The major product is 1-bromo-1-methylcyclohexane. Name and outline the mechanism for the for
- June 2023, AS Paper 2, Q04.2 (4 marks): Draw the skeletal formula of the minor product formed in the reaction in Question 04.1. Explain why the products are formed in different amounts. [4 marks] Skel
- June 2023, AS Paper 2, Q04.3 (1 mark): Draw the structure of the major product when an excess of HBr reacts with limonene. [1 mark]
- June 2023, AS Paper 2, Q09 (1 mark): Which monomer forms this polymer? [1 mark] A but-1-ene B E-but-2-ene C Z-but-2-ene D methylpropene
- June 2023, AS Paper 2, Q15 (1 mark): Which reaction results in an overall change in shape around a carbon atom? [1 mark] A oxidation of propanal with acidified potassium dichromate(VI) B polymerisa
- June 2022, Paper 2, Q03.1 (5 marks): Name the mechanism for the reaction of 2-methylbut-1-ene with concentrated sulfuric acid. Outline the mechanism for this reaction to form the major product. [5
- June 2022, Paper 2, Q03.2 (3 marks): Draw the structure of the minor product formed in the reaction in Question 03.1 Explain why this is the minor product. [3 marks] Structure of minor product Expl
- June 2022, AS Paper 2, Q07.6 (5 marks): Name and outline a mechanism to show the conversion of but-1-ene into compound W in the first part of this process. [5 marks] Name of mechanism Outline of mecha
- June 2022, AS Paper 2, Q07.7 (2 marks): There is a very low yield of butan-1-ol from but-1-ene in this manufacturing process. Explain why. [2 marks] Section B Answer all questions in this section. Onl
- June 2022, AS Paper 2, Q10 (1 mark): Which statement about poly(ethene) is correct? [1 mark] A It has a lower relative molecular mass than ethene. B It has a lower density than ethene at standard t
- June 2022, AS Paper 2, Q11 (1 mark): A polymer is formed from the monomer CH2=CHCN Which statement is not correct? [1 mark] A The monomer is propanenitrile. B The monomer is unsaturated. C The poly
- November 2021, Paper 2, Q08.2 (4 marks): State the reagents needed and give equations for step 2 and step 3. Show the structure of Compound G in your equations. [4 marks] Step 2 reagent Step 2 equation
- November 2021, AS Paper 2, Q02.1 (5 marks): Name and outline the mechanism for the reaction of cyclohexene with Br2 [5 marks] Name of mechanism Outline of mechanism
- November 2021, AS Paper 2, Q02.2 (3 marks): Explain why there is an attraction between a C=C double bond and Br2 [3 marks]
- November 2021, AS Paper 2, Q02.3 (1 mark): Draw the skeletal formula of the halogenoalkane formed when buta-1,3-diene (CH2=CHCH=CH2) reacts with an excess of Br2 [1 mark]
- November 2021, AS Paper 2, Q05.2 (1 mark): Poly(propene) is not biodegradable because it is unreactive. Explain why poly(propene) is unreactive. [1 mark]
- November 2021, AS Paper 2, Q05.3 (1 mark): Scientists are developing new polymers, including some that are biodegradable. Suggest why it is beneficial for some polymers to be biodegradable. [1 mark]
- November 2021, AS Paper 2, Q07.3 (1 mark): Prop-2-en-1-ol forms an addition polymer. Draw the repeating unit of poly(prop-2-en-1-ol). [1 mark]
- November 2021, AS Paper 2, Q18 (1 mark): Which compound reacts with hydrogen bromide to give 2-bromo-3-methylbutane as the major product? [1 mark] A (CH3)2C=CHCH3 B (CH3)2C=CH2 C CH2=C(CH3)CH2CH3 D (CH
- November 2020, Paper 2, Q06.4 (1 mark): Draw the repeating unit of polystyrene. [1 mark]
- November 2020, Paper 3, Q24 (1 mark): Which compound decolourises bromine water in the absence of sunlight? [1 mark] A CH3CH2CH2Br B C D CH3CH2CHCH2
- November 2020, Paper 3, Q28 (1 mark): Which compound reacts with hydrogen bromide to give 2-bromo-3-methylbutane as the major product? [1 mark] A (CH3)2C=CHCH3 B CH3(CH2)2CH=CH2 C CH3CH2C(CH3)=CH2 D
- November 2020, AS Paper 2, Q06.1 (3 marks): Give an equation, showing structural formulas, for the conversion of chloroethene into poly(chloroethene). [3 marks]
- November 2020, AS Paper 2, Q06.2 (2 marks): State what you would observe if bromine water was added to poly(chloroethene). Explain this observation. [2 marks] Observation Explanation
- November 2020, AS Paper 2, Q06.3 (2 marks): Plasticisers are often added during the manufacture of PVC. The structure of the plasticiser DEHP is shown. Deduce the molecular formula of DEHP and state why a
- November 2020, AS Paper 2, Q12 (1 mark): What is the IUPAC name of the major product of the reaction between 2-ethylbut-1-ene and hydrogen bromide? [1 mark] A 1-bromo-2-ethylbutane B 2-bromo-2-ethylbut
- November 2020, AS Paper 2, Q15 (1 mark): In which reaction does the inorganic reagent act initially as an electrophile? [1 mark] A bromoethane with ethanolic potassium hydroxide B chloroethane with aqu
- June 2019, Paper 2, Q02.5 (3 marks): Cyclohexene reacts with bromine. Complete the mechanism for this reaction. [3 marks]
- June 2019, Paper 2, Q03.1 (4 marks): Deduce the molecular formula of isoprene and suggest a possible structure. [4 marks] Molecular formula Structure
- June 2019, Paper 2, Q03.3 (2 marks): A second polymer in the mixture has a repeating unit with the structure shown. The third polymer in the mixture is a stereoisomer of this polymer. Draw the stru
- June 2019, Paper 2, Q11.3 (2 marks): The compound C19H34O2 is the methyl ester of Z,Z-octadeca-9,12-dienoic acid. Part of the structure of the acid is shown. Complete the skeletal formula to show t
- June 2019, Paper 3, Q04.4 (1 mark): Draw a section of the polymer polyacrylonitrile, showing three repeating units. [1 mark]
- June 2019, Paper 3, Q33 (1 mark): Which alkene reacts with hydrogen bromide to give 2-bromo-3-methylbutane as the major product? [1 mark] A (CH3)2C=CHCH3 B CH3CH2CH=CHCH3 C CH3CH2C(CH3)=CH2 D (C
- June 2019, AS Paper 2, Q06.1 (5 marks): Name and outline the mechanism for the formation of E in this reaction. [5 marks] Name of mechanism Mechanism
- June 2019, AS Paper 2, Q06.2 (1 mark): Draw the structure of F. [1 mark]
- June 2019, AS Paper 2, Q06.3 (2 marks): Explain why more of isomer E than isomer F is formed in this reaction. [2 marks]
- June 2019, AS Paper 2, Q17 (1 mark): Which statement is not correct about CH2═C(CH3)CH2Br? [1 mark] A It displays E-Z isomerism. B It forms an addition polymer. C It reacts with electrophiles. D It
- June 2018, Paper 2, Q03.6 (2 marks): A pair of stereoisomers is also formed in the reaction in Question 03.5. Name the less polar stereoisomer formed. Explain how this type of stereoisomerism arise
- June 2018, Paper 3, Q03.2 (2 marks): Describe a test-tube reaction, on the product, to show that the cyclohexanol had been dehydrated. State what you would observe. [2 marks]
- June 2018, AS Paper 2, Q04.6 (1 mark): The main use of propene, formed from cracking, is to make poly(propene). Draw the repeating unit of poly(propene). [1 mark]
- June 2018, AS Paper 2, Q05.1 (6 marks): A hydrocarbon contains 87.8% by mass of carbon and has a relative molecular mass (Mr) of 82.0 The hydrocarbon decolourises bromine water. Determine the empirica
- June 2018, AS Paper 2, Q11 (1 mark): Which is the major product of the reaction between 2-methylbut-2-ene and iodine monochloride (ICl)? [1 mark] A B C D
- June 2018, AS Paper 2, Q19 (1 mark): Which statement is correct about poly(chloroethene)? [1 mark] A It has the empirical formula CHCl B It decolourises bromine water. C Its brittleness is reduced
- June 2017, Paper 3, Q02.1 (1 mark): Name the mechanism for the reaction of concentrated sulfuric acid with an alkene. [1 mark]
- June 2017, Paper 3, Q02.2 (4 marks): Outline the mechanism for the reaction of concentrated sulfuric acid with propene to show the formation of the major product. [4 marks]
- June 2017, Paper 3, Q02.3 (1 mark): Draw the structure of the minor product of the reaction between concentrated sulfuric acid and propene. [1 mark] 7
- June 2017, Paper 3, Q02.4 (2 marks): Explain why the product shown in your answer to Question 2.2 is the major product. [2 marks]
- June 2017, Paper 3, Q18 (1 mark): This structure shows a section of a polymer chain formed from the random polymerisation of two different monomers. Which pair of monomers could produce this pol
- June 2017, AS Paper 2, Q08.2 (1 mark): Draw the displayed formula of C5H11Br that is the major product of the reaction of 2-methylbut-2-ene with hydrogen bromide. [1 mark]
- June 2017, AS Paper 2, Q08.3 (1 mark): Thermal cracking of hydrocarbons produces molecules that are attacked by electrophiles because they have a region of high electron density. Draw the structure o
- June 2017, AS Paper 2, Q09.2 (1 mark): This structure shows a molecule that has been used as a plasticiser in PVC. Deduce the number of hydrogen atoms in this molecule. [1 mark]
- June 2017, AS Paper 2, Q09.3 (1 mark): Use your understanding of the properties of PVC to explain whether you would expect to find a plasticiser in the PVC used to insulate electrical cables. [1 mark
- June 2017, AS Paper 2, Q09.4 (1 mark): A section of the polymer poly(chloroprene), a synthetic rubber, is shown. Draw the displayed formula for the repeating unit of poly(chloroprene). [1 mark] Secti
- June 2016, AS Paper 2, Q03.7 (2 marks): Oleic acid (C18H34O2) is a straight-chain fatty acid obtained from plant oils. Isooctane can be made from oleic acid. The skeletal formula of oleic acid is show
- June 2016, AS Paper 2, Q07.2 (7 marks): Name and outline the mechanism for the formation of 3-bromo-3-methylpentane from this reaction of 3-methylpent-2-ene with hydrogen bromide. Explain why more 3-b
- June 2016, AS Paper 2, Q15 (1 mark): The repeating unit of a polymer is Which of the following molecules would form a polymer containing this repeating unit? [1 mark] A But-1-ene B E-but-2-ene C Z-
- Specimen, Paper 2, Q07.1 (2 marks): Monomer Type of polymerisation
- Specimen, Paper 2, Q12.1 (1 mark): 12 But-1-ene reacts with a reagent of the form HY to form a saturated compound. Suggest a reagent of the form HY which reacts with but-1-ene. [1 mark] 1 2 . 1
- Specimen, Paper 2, Q12.2 (5 marks): Name of mechanism Mechanism
- Specimen, Paper 2, Q12.3 (3 marks): 12 But-1-ene reacts with a reagent of the form HY to form a saturated compound. Explain how three isomeric products are formed when HY reacts with but-1-ene. [3
- Specimen, Paper 3, Q27 (1 mark): What is the major product of the reaction between but-1-ene and DBr? (D is deuterium and represents 2H) [1 mark] A CH2DCH2CH2CH2Br B CH2DCH2CHBrCH3 C CH3CH2CHBr
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