Tests for organic functional groups: Edexcel International A Level Chemistry questions
Edexcel International A Level Chemistry past-paper questions on P.1.6 Tests for organic functional groups, 2019–2025, with mark schemes and examiner’s reports where available.
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Calculations
Q16(a)
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Q1(a)
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Q1(b)(i)
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Q1(b)(ii)
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Q3(a)
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Q3(b)(i)
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Q3(b)(ii)
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Q20(c)
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Q2(j)
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Q1(a)
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Q1(b)
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Q2(b)(i)
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Q21(a)(iii)
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Q17(a)
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Q2(a)
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Q2(b)
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Q2(c)
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Q2(d)(i)
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Q2(a)(i)
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Q2(d)(ii)
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All 50 questions on Tests for organic functional groups, as a list
- June 2025, AS Unit 2, Q16(a) (2 marks): Give a chemical test, including the result, to show that alcohols contain an OH group. (2)
- June 2025, AS Unit 3, Q1(a) (1 mark): Phosphorus(V) chloride is added to separate samples of P and Q. A gas, R, is evolved in each reaction. Identify R, by name or formula. (1)
- June 2025, AS Unit 3, Q1(b)(i) (1 mark): Give the colour change of the mixtures during heating. (1) From To
- June 2025, AS Unit 3, Q1(b)(ii) (1 mark): Identify the functional group present in P and Q. (1)
- January 2025, Unit 6, Q3(a) (4 marks): Qualitative tests on X show that it • burns in air with a very smoky flame • forms an orange precipitate with 2,4-dinitrophenylhydrazine (Brady’s reagent) does
- October 2024, AS Unit 3, Q3(b)(i) (1 mark): The purified product was treated with a small volume of bromine water and shaken. The bromine water was not decolourised. State the most likely conclusion that
- October 2024, AS Unit 3, Q3(b)(ii) (1 mark): The purified product was also treated with Fehling’s reagent. No colour change was observed. State the most likely conclusion that can be made from this informa
- June 2024, AS Unit 2, Q20(c) (6 marks): Three students were asked to carry out a single chemical test to unambiguously identify the presence of the ‒OH group in the three terpenoid compounds, menthol,
- June 2024, AS Unit 3, Q2(j) (4 marks): State a chemical test for the –OH group in ethanol and a chemical test for the –Br group in bromoethane. Include the expected positive observations. (4) –OH gro
- June 2024, Unit 6, Q1(a) (2 marks): Test 1 A small amount of phosphorus(V) chloride, PCl5, is added to 2 cm3 of A. Observation misty fumes given off Test 2 Aqueous sodium hydrogencarbonate, NaHCO3
- June 2024, Unit 6, Q1(b) (1 mark): Test 3 A few drops of A are added to 2 cm3 of Tollens’ reagent (ammoniacal silver nitrate solution). The mixture is placed in a warm water bath. Observation sil
- January 2024, Unit 6, Q2(b)(i) (1 mark): Name the functional group in X identified by this test. (1)
- October 2023, AS Unit 2, Q21(a)(iii) (2 marks): Reagents were added to separate samples of X to identify the functional groups in the molecule. Complete Table 1. (2) Table 1 Reagent Observation Functional gro
- October 2023, Unit 4, Q17(a) (6 marks): These four isomers can be identified using three chemical tests. Each test gives a positive result for only one isomer. All three tests give a negative result f
- June 2023, AS Unit 3, Q2(a) (1 mark): A small amount of phosphorus(V) chloride, PCl5 , is added to separate 2 cm3 samples of each compound. Observations C D Misty fumes are given off Misty fumes are
- June 2023, AS Unit 3, Q2(b) (1 mark): 2 cm3 of aqueous sodium hydrogencarbonate, NaHCO3(aq), is added to separate 2 cm3 samples of each compound. Any gas given off is tested with limewater. Observat
- June 2023, AS Unit 3, Q2(c) (2 marks): 2 cm3 of Benedict’s or Fehling’s solution is added to separate 2 cm3 samples of each compound. The test tubes are placed in a warm water bath. Observations C D
- June 2023, AS Unit 3, Q2(d)(i) (3 marks): Deduce the structure of C and the two possible structures of D. Use the molecular formula and the results from (a), (b) and (c). (3) Structure of C Possible str
- June 2023, Unit 6, Q2(a)(i) (3 marks): Deduce the functional group in X. Justify your answer by referring to the observations. (3)
- June 2023, Unit 6, Q2(d)(ii) (2 marks): A student prepared an ester using X and a suitable compound. Explain why the student added aqueous sodium hydrogencarbonate to the reaction mixture to allow the
- January 2023, AS Unit 3, Q4(a) (2 marks): Give a chemical test, with the expected result, which would show the presence of the –OH group in any alcohol. (2) Test Result
- January 2023, AS Unit 3, Q4(b)(iv) (3 marks): Give one chemical test, with the expected results, which would distinguish these oxidation products of isomers L and M. (3) Test Result for oxidation product of
- October 2022, AS Unit 3, Q4(c)(iv) (4 marks): Give a further chemical test and the positive result for each of the oxidation products of propan‑1‑ol. (4)
- June 2022, AS Unit 3, Q3(g)(i) (2 marks): State a chemical test and the expected observation for a C C double bond. (2)
- June 2022, AS Unit 3, Q3(g)(ii) (2 marks): State a chemical test and the expected observation for an –OH group. (2)
- June 2022, AS Unit 3, Q3(g)(iii) (1 mark): State whether or not the test in (g)(ii) could be used on the organic product to show if cyclohexanol remains when Step 5 is complete. Justify your answer. (1)
- June 2022, Unit 6, Q2(a)(i) (3 marks): The student carries out three tests on separate samples of each compound. Complete Table 1 to show the observations that the student makes. (3) Observations on
- January 2022, AS Unit 3, Q2(b) (1 mark): When phosphorus(V) chloride is added to X, steamy white fumes are seen. State what can be deduced about compound X from this observation only. (1)
- January 2022, Unit 6, Q2(b) (3 marks): Three chemical tests are carried out on X. Test 1 When Brady’s reagent (2,4‑dinitrophenylhydrazine solution) is added to X, an orange precipitate is observed.
- January 2022, Unit 6, Q2(d)(i) (1 mark): When aqueous sodium carbonate is added to Y, effervescence is observed. Identify, by name or formula, the functional group present in Y. (1)
- October 2021, AS Unit 3, Q2(a) (4 marks): Geraniol has two different types of functional group. Name the functional groups, giving a chemical test and its positive result to show the presence of each gr
- October 2021, AS Unit 3, Q2(e) (1 mark): State the appearance of the flame when geraniol is ignited. (1)
- October 2021, Unit 6, Q2(a)(i) (2 marks): Complete the statements in the inference column by writing the names or formulae of the functional groups. (2) Test Observation Inference Test 1 A could contain
- October 2021, Unit 6, Q2(c)(i) (2 marks): Complete the statements in the observation and inference columns. (2) Test Observation Inference Test 3 2 drops of B were dissolved in 2 cm3 of water The colour
- October 2021, Unit 6, Q4(b) (2 marks): The distillate collected in Step 3 is the alcohol ROH. Describe a chemical test, and its positive result, to show the presence of an –OH group in any alcohol. (
- June 2021, AS Unit 3, Q2(a) (2 marks): Give a chemical test to show the presence of the OH group in all three compounds, including the expected result. (2)
- June 2021, AS Unit 3, Q2(b)(i) (2 marks): Give a chemical test to show the presence of the carbon-carbon double bond in Z-hex-3-en-1-ol, including the expected result. (2)
- June 2021, AS Unit 3, Q2(b)(ii) (1 mark): The test you have given in (b)(i) is repeated with 1-methylcyclopentanol. Give the observation for this test with 1-methylcyclopentanol. (1)
- June 2021, Unit 6, Q3(b)(i) (2 marks): A and B O O OH OH O B A (2)
- June 2021, Unit 6, Q3(b)(ii) (2 marks): C and D O O O C D (2)
- January 2021, Unit 4, Q17(d)(ii) (1 mark): Aqueous sodium hydrogencarbonate is added to a sample of E. No effervescence occurs. State what can be deduced by this observation. (1)
- October 2020, AS Unit 2, Q17(b)(iii) (2 marks): Give a chemical test, and its positive result, that could be used to confirm the functional group in methanoic acid. (2)
- October 2020, AS Unit 3, Q3(a)(i) (1 mark): Identify, by name or formula, the steamy fumes produced in Test 1. (1) Test 2 About 1 cm3 of sodium hydrogencarbonate solution was added to 1 cm3 of each liquid
- October 2020, AS Unit 3, Q3(a)(ii) (1 mark): Identify, by name or formula, the gas produced in Test 2. (1)
- October 2020, AS Unit 3, Q3(a)(iii) (2 marks): Using the results from Tests 1 and 2 and the information at the start of the question, name the functional groups present in F and G. (2) Functional group in F
- October 2020, AS Unit 3, Q3(b) (4 marks): The organic liquid H is a pheromone thought to be involved in communication between rabbits. H O H3C CH3 State the initial and final appearance of each mixture
- January 2020, AS Unit 3, Q1(c)(ii) (2 marks): Give a chemical test, with the expected observation, to confirm the presence of the hydroxy group. (2) Test Observation
- June 2019, AS Unit 2, Q22(a) (2 marks): Describe a chemical test and its positive result for the alcohol functional group in Y. (2)
- June 2019, AS Unit 3, Q2(a) (2 marks): A chemical test may be used to confirm the presence of the hydroxyl group in A. Identify a suitable reagent for this test, giving the positive result. (2)
- June 2019, AS Unit 3, Q2(b)(iii) (2 marks): A chemical test may be used to confirm the presence of an aldehyde. Identify the reagent used, giving the positive result of the test. (2)
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