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Reactions of halogenoalkanes: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 10.B.2 Reactions of halogenoalkanes, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. Q14(c)(i)

    June 2025 · AS Unit 2

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  2. Q14(c)(iii)

    June 2025 · AS Unit 2

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  3. Q16(d)

    June 2025 · AS Unit 2

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  4. Q18(b)

    June 2025 (A) · Unit 5

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  5. Q19(b)(i)

    January 2025 · AS Unit 2

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  6. Q19(b)(ii)

    January 2025 · AS Unit 2

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  8. The start of question 13

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  9. Q17(c)(i)

    October 2024 · AS Unit 2

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  10. Q17(c)(ii)

    October 2024 · AS Unit 2

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  11. Q16(a)(i)

    June 2024 · AS Unit 2

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  12. Q16(a)(ii)

    June 2024 · AS Unit 2

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  13. Q16(b)(i)

    June 2024 · AS Unit 2

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  14. The start of question 2

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  15. Q23(c)(i)

    January 2024 · AS Unit 2

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  16. Q17

    October 2023 · AS Unit 2

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  17. Q18(c)(iii)

    October 2023 · AS Unit 2

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  18. Q19(b)

    June 2023 · AS Unit 2

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  19. Q19(c)

    June 2023 · AS Unit 2

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  20. Q19(e)(ii)

    June 2023 · AS Unit 2

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All 36 questions on Reactions of halogenoalkanes, as a list
  1. June 2025, AS Unit 2, Q14(c)(i) (2 marks): State the conditions for this reaction. (2)
  2. June 2025, AS Unit 2, Q14(c)(iii) (2 marks): Further substitution of the ethylamine molecule may occur if the halogenoalkane is in excess. State two features of the ethylamine molecule that make this possi
  3. June 2025, AS Unit 2, Q16(d) (6 marks): Discuss the reactions between sodium hydroxide and 2-chlorobutane. The hydroxide ion acts in two different ways depending on the reaction conditions. Include th
  4. June 2025 (A), Unit 5, Q18(b) (2 marks): State the reagent and conditions used for the reaction in Step 3. (2)
  5. January 2025, AS Unit 2, Q19(b)(i) (1 mark): Name this type of reaction. (1)
  6. January 2025, AS Unit 2, Q19(b)(ii) (2 marks): Draw the structure of the two isomers. (2) Isomer 1 Isomer 2
  7. January 2025, AS Unit 2, Q19(d) (2 marks): State the role of the hydroxide ion in each of the reactions (b) and (c). (2) Role in (b) Role in (c)
  8. October 2024, AS Unit 2, Q13(a) (1 mark): What is the role of the hydroxide ion in this reaction? (1) A reducing agent B nucleophile C electrophile D base
  9. October 2024, AS Unit 2, Q17(c)(i) (2 marks): Write an equation for the reaction of B with an alcoholic solution of potassium cyanide and name the organic product. (2) Equation: Name
  10. October 2024, AS Unit 2, Q17(c)(ii) (1 mark): Suggest why this type of reaction is important in organic synthesis. (1)
  11. June 2024, AS Unit 2, Q16(a)(i) (1 mark): State what condition, other than a suitable temperature and concentration of potassium hydroxide, would give a high yield of but‑1‑ene and but‑2‑ene from 2‑chlo
  12. June 2024, AS Unit 2, Q16(a)(ii) (1 mark): Give the type of reaction occurring in (a)(i). (1)
  13. June 2024, AS Unit 2, Q16(b)(i) (1 mark): State what condition, other than a suitable temperature and concentration of potassium hydroxide, would give a high yield of butan‑1‑ol from 1‑chlorobutane. (1)
  14. June 2024, AS Unit 3, Q2(j) (4 marks): State a chemical test for the –OH group in ethanol and a chemical test for the –Br group in bromoethane. Include the expected positive observations. (4) –OH gro
  15. January 2024, AS Unit 2, Q23(c)(i) (4 marks): Complete the table. (4) Formula Reaction Name of mechanism of Condition(s) reagent R1 nucleophilic substitution R2 heat in ethanol R3 NH3 R4 heat in ethanol
  16. October 2023, AS Unit 2, Q17 (1 mark): Which compound reacts with ammonia to form CH3CH(NH2)CH3? A 1‑chloropropane B 2‑chloropropane C propane D propene
  17. October 2023, AS Unit 2, Q18(c)(iii) (2 marks): Under different conditions, sodium hydroxide reacts with 1‑bromopropane to form propene. Name the type of reaction and a suitable solvent. (2) Type of reaction
  18. June 2023, AS Unit 2, Q19(b) (2 marks): Give the IUPAC name and the structure of compound M. (2)
  19. June 2023, AS Unit 2, Q19(c) (2 marks): State the reagent and conditions required for Reaction 1. (2)
  20. June 2023, AS Unit 2, Q19(e)(ii) (1 mark): Suggest one advantage of using silver(I) oxide rather than sodium hydroxide or potassium hydroxide. (1)
  21. January 2023, AS Unit 2, Q14 (1 mark): CH3CH2CHBrCH2CH2CH3 is heated with ethanolic potassium hydroxide. How many alkene products are possible? A one B two C three D four
  22. January 2023, AS Unit 2, Q20(b) (1 mark): Give the structure of organic compound W. (1)
  23. January 2023, AS Unit 2, Q20(d)(i) (2 marks): Give the conditions for this reaction. (2)
  24. January 2023, AS Unit 2, Q20(d)(ii) (1 mark): Suggest why the yield of CH3CH2CH2NH2 obtained using Step Z is low. (1)
  25. October 2022, AS Unit 2, Q23(d)(iv) (2 marks): For Reaction 4, the reagent used is potassium hydroxide (KOH). Give the conditions required for this reaction, stating the role of the hydroxide ions in this re
  26. June 2022, AS Unit 2, Q17(c)(i) (1 mark): Give a reason why this reaction should be carried out by heating the reactants in a sealed tube rather than heating under reflux. (1)
  27. June 2022, AS Unit 2, Q17(e) (6 marks): The reaction between 2-bromopropane and potassium hydroxide takes place under two different conditions: • in aqueous solution • in ethanolic solution. Compare a
  28. January 2022, AS Unit 2, Q20(a) (2 marks): State the type and mechanism of this reaction. (2)
  29. October 2021, AS Unit 2, Q20(d) (3 marks): In another experiment, 2-bromobutane is heated with ethanolic potassium hydroxide and an elimination reaction occurs. Draw the skeletal formulae of the three po
  30. June 2021, AS Unit 2, Q18(b)(i) (1 mark): Give the conditions for the formation of propene. (1)
  31. June 2021, AS Unit 2, Q18(b)(ii) (1 mark): Give the molecular formula of product B. (1)
  32. June 2021, AS Unit 2, Q18(b)(iii) (2 marks): Name the type and mechanism of the reaction taking place in reaction C. (2)
  33. October 2020, AS Unit 2, Q16(a) (4 marks): Complete the table about these reactions. (4) Reaction Reagent Solvent Type of reaction 1 potassium hydroxide 2 ammonia 3 ethanol 4 elimination
  34. October 2020, AS Unit 2, Q16(b) (1 mark): Give the IUPAC name of the product of Reaction 3. (1)
  35. January 2020, AS Unit 2, Q11(a) (1 mark): What type of reaction occurs in this preparation? (1) A addition B elimination C reduction D substitution
  36. June 2019, AS Unit 2, Q21(a)(i) (1 mark): Name a suitable solvent for the potassium hydroxide in this reaction. (1)

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