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Reactions of carboxylic acids: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 15.C.3 Reactions of carboxylic acids, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. Q15(a)(iii)

    June 2025 · Unit 4

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  2. Q15(a)(iv)

    June 2025 · Unit 4

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  3. Q15(a)(v)

    June 2025 · Unit 4

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  4. Q1

    January 2025 · Unit 4

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  5. Q20(f)

    January 2025 · Unit 4

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  6. Q10(a)

    October 2024 · Unit 4

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  7. The start of question 14

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  8. Q14(b)

    October 2024 · Unit 4

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  9. Q17(b)(i)

    June 2024 · Unit 4

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  10. Q17(b)(iii)

    June 2024 · Unit 4

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  11. Q17(b)(iv)

    June 2024 · Unit 4

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  12. The start of question 1

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  13. Q4(b)

    June 2024 · Unit 6

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  15. Q13

    January 2024 · Unit 4

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  16. Q18(c)(i)

    January 2024 · Unit 4

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  17. The start of question 2

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  19. Q10(a)

    October 2023 · Unit 4

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  20. Q10(c)

    October 2023 · Unit 4

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All 45 questions on Reactions of carboxylic acids, as a list
  1. June 2025, Unit 4, Q15(a)(iii) (2 marks): Give the structural formula and name of Substance C. (2)
  2. June 2025, Unit 4, Q15(a)(iv) (2 marks): Identify, by name or formula, the reagent required to carry out Reaction D, giving one observation. (2) Reagent Observation
  3. June 2025, Unit 4, Q15(a)(v) (1 mark): Write the full equation for the formation of Substance E. State symbols are not required. (1)
  4. January 2025, Unit 4, Q1 (1 mark): Which reducing reagent is used to convert carboxylic acids to alcohols? A acidified potassium dichromate(VI) B concentrated sulfuric acid C hydrogen gas with a
  5. January 2025, Unit 4, Q20(f) (2 marks): Write the equation for the reaction of oxalic acid with excess phosphorus(V) chloride. (2)
  6. October 2024, Unit 4, Q10(a) (1 mark): O OH and OH (1) A warm each compound with Tollens’ reagent B add sodium carbonate solution to each compound C warm each compound with iodine under alkaline cond
  7. October 2024, Unit 4, Q14(a) (1 mark): What solvent is used in this reaction? (1) A ethanol B ether C ethyl ethanoate D water
  8. October 2024, Unit 4, Q14(b) (1 mark): What is the organic product that forms? (1) O A OH B O C OH D
  9. June 2024, Unit 4, Q17(b)(i) (1 mark): Give the reagents and conditions for Reaction 1. (1)
  10. June 2024, Unit 4, Q17(b)(iii) (2 marks): Give the structure of the organic product formed in Reaction 3. (2)
  11. June 2024, Unit 4, Q17(b)(iv) (1 mark): Give the structure of the organic product formed in Reaction 4. (1)
  12. June 2024, Unit 6, Q1(a) (2 marks): Test 1 A small amount of phosphorus(V) chloride, PCl5, is added to 2 cm3 of A. Observation misty fumes given off Test 2 Aqueous sodium hydrogencarbonate, NaHCO3
  13. June 2024, Unit 6, Q4(b) (1 mark): State the purpose of the sulfuric acid. (1)
  14. January 2024, Unit 4, Q12 (1 mark): From which two reactants could CH3(CH2)2COO(CH2)4CH3 be made? A butanoic acid and pentan‑1‑ol B butanoyl chloride and butan‑1‑ol C butanal and pentan‑1‑ol D pen
  15. January 2024, Unit 4, Q13 (1 mark): The reaction between ethanoic acid and lithium tetrahydridoaluminate(III) is best described as A elimination B oxidation C reduction D substitution
  16. January 2024, Unit 4, Q18(c)(i) (1 mark): State the type of reaction in Step 3. (1)
  17. January 2024, Unit 6, Q2(b)(i) (1 mark): Name the functional group in X identified by this test. (1)
  18. January 2024, Unit 6, Q2(d) (1 mark): A sample of Z produced bubbles when sodium carbonate solution was added. Draw the displayed formula of Z, showing all the bonds. (1)
  19. October 2023, Unit 4, Q10(a) (1 mark): Which reagent is required for Reaction 1? (1) A acidified potassium dichromate(VI) B concentrated sulfuric acid C hydrogen with a nickel catalyst D lithium tetr
  20. October 2023, Unit 4, Q10(c) (1 mark): Which condition is essential for Reaction 2? (1) A acid catalyst B anhydrous C high temperature D ether solvent
  21. October 2023, Unit 4, Q17(a) (6 marks): These four isomers can be identified using three chemical tests. Each test gives a positive result for only one isomer. All three tests give a negative result f
  22. October 2023, Unit 5, Q14 (1 mark): An organic compound, J, reacts with • sodium hydroxide to form an ionic compound • hydrogen in the presence of a nickel catalyst • ethanol in the presence of su
  23. October 2023, Unit 5, Q21(d) (1 mark): Identify, by name or formula, the reagent needed to convert salicylic acid into methyl salicylate. (1)
  24. June 2023, Unit 5, Q24(a)(iii) (2 marks): The structure of PAA in aqueous solution is pH-dependent. Below pH 4, the structure of PAA is compact due to the formation of intramolecular hydrogen bonds. Abo
  25. June 2023, Unit 6, Q2(d)(i) (1 mark): Name the compound that would react with both X and Y to form ethyl esters. (1)
  26. June 2023, Unit 6, Q2(d)(ii) (2 marks): A student prepared an ester using X and a suitable compound. Explain why the student added aqueous sodium hydrogencarbonate to the reaction mixture to allow the
  27. June 2023, Unit 6, Q2(e) (2 marks): Both X and Y react with concentrated ammonia but form different products. Identify these products, by name or formula. (2) Product with X Product with Y
  28. June 2022, Unit 5, Q15(b) (2 marks): N‑phenylanthranilic acid has the structure shown. O OH H N The solution used as an indicator was prepared by mixing 100 mg of this acid in 5 cm3 of sodium hydro
  29. January 2022, Unit 4, Q14 (1 mark): Compound X, C4H10O, is oxidised to form compound Y. Compound Y reacts with ethanol in the presence of concentrated sulfuric acid to give an ester, Z. Which of t
  30. January 2022, Unit 4, Q21(b)(ii) (4 marks): Explain one advantage and one disadvantage of using Reaction 2 rather than Reaction 1. (4)
  31. January 2022, Unit 6, Q2(d)(i) (1 mark): When aqueous sodium carbonate is added to Y, effervescence is observed. Identify, by name or formula, the functional group present in Y. (1)
  32. October 2021, Unit 6, Q4(c)(i) (1 mark): Write an equation for the reaction taking place in Step 4. Use structural formulae for the organic substances. State symbols are not required. (1)
  33. June 2021, Unit 4, Q17(b)(ii) (1 mark): Draw the structures of two organic compounds that would react together to form Y. (1)
  34. June 2021, Unit 4, Q19(b) (1 mark): Sodium hydrogencarbonate, NaHCO3 , has been used by some athletes to help prevent lactic acid causing muscle pain during exercise. Write an equation for the rea
  35. June 2021, Unit 6, Q1(c) (3 marks): A white solid with a slight vinegar-like smell contains ammonium ions, NH4 an anion represented by Y−. The smell of vinegar intensifies on the addition of a few
  36. June 2021, Unit 6, Q3(b)(i) (2 marks): A and B O O OH OH O B A (2)
  37. January 2021, Unit 4, Q17(b) (3 marks): A reaction scheme involving butanoic acid is shown. O O acidified K2Cr2O7 reagent Y alcohol X Cl OH heat under reflux butanoic acid CH3NH2 compound Z Identify X
  38. January 2021, Unit 4, Q17(d)(ii) (1 mark): Aqueous sodium hydrogencarbonate is added to a sample of E. No effervescence occurs. State what can be deduced by this observation. (1)
  39. October 2020, Unit 4, Q14 (1 mark): An organic compound that reacts with both lithium tetrahydridoaluminate(III) (lithium aluminium hydride) and magnesium could be A an aldehyde B a carboxylic aci
  40. October 2020, Unit 4, Q17(c)(i) (4 marks): Identify, by name or formula, compounds V, W and F. Justify your answer by using all the available information. (4)
  41. October 2020, Unit 4, Q17(c)(iii) (1 mark): State the role of sulfuric acid in the formation of F. (1)
  42. October 2020, Unit 6, Q2(b)(i) (2 marks): When sodium hydrogencarbonate solution is added to separate samples of Q and R, effervescence occurs and a gas is evolved which turns limewater milky. Deduce th
  43. January 2020, Unit 4, Q4 (1 mark): The compound HOOCCH CHCOOH reacts with excess sodium hydroxide solution. What is the organic product formed in the reaction? A NaOOCCH CHCOONa B HOOCCH CHCOONa
  44. January 2020, Unit 4, Q6 (1 mark): Which of these reacts directly with ethanoic acid to form ethanoyl chloride? A chlorine B chloroethane C hydrogen chloride D phosphorus(V) chloride
  45. January 2020, Unit 4, Q20(a)(v) (1 mark): Describe how the sodium ethanoate in the final reaction mixture could be converted into ethanoic acid. (1)

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