Entropy and feasibility of reactions: WJEC A‑Level Chemistry questions
Every WJEC A-Level Chemistry exam question on 3.7 Entropy and feasibility of reactions, 2016–2025, with its mark scheme and examiner’s report.
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Q7(a)(i)
The whole paper ↗![Summer 2025 Unit 3, question 7(a)(i): Give a reason why all the entropy changes are positive. [1]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/1410u30-jun25-07-ai-qp.webp)
Q7(a)(ii)
The whole paper ↗![Summer 2025 Unit 3, question 7(a)(ii): The minimum temperature for decomposition of calcium nitrate is 1500 °C. Find the standard enthalpy change for this reaction. [3] kJ mol–1 Standard enthalpy cha](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/1410u30-jun25-07-aii-qp.webp)
Q8(d)(ii)
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Q10(c)(ii)
The whole paper ↗![Summer 2024 Unit 3, question 10(c)(ii): aqueous solution. [Cu(NH3)4(H2O)2]2+(aq) [Cu(cyclen)(H2O)2]2+(aq) + cyclen(aq) + 4NH3(aq) ΔHθ = +1.2 kJ mol–1 Measurements show that the strengths of the Cu―N b](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/1410u30-jun24-10-cii-qp.webp)
Q8(d)(ii)
The whole paper ↗![Summer 2023 Unit 3, question 8(d)(ii): Calculate the minimum temperature required for this reaction. [2] minimum temperature = K](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/1410u30-jun23-08-dii-qp.webp)
Q10(a)
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![Summer 2022 Unit 3, question 7: Give a reason why the entropy of Hg(l) is greater than that of Au(s). [1]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/1410u30-jun22-07-qp.webp)
Q8(b)(iii)
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Q10(e)
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![Summer 2019 Unit 3, question 6: The entropy change of the reaction shown below is positive. Give a reason for this. [1] Na2CO3(aq) + 2HCl(aq) 2NaCl(aq) + CO2(g) + H2O(l)](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/1410u30-jun19-06-qp.webp)
Q9(b)(i)
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![Summer 2018 Unit 3, question 6: The enthalpy of solution of sodium chloride is +4 kJ mol–1. Explain why this compound is soluble 6 in water despite this value being positive. [1]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/1410u30-jun18-06-qp.webp)
Q11(d)
The whole paper ↗![Summer 2018 Unit 3, question 11(d): State whether you would expect the entropy change for the decomposition of hydrogen peroxide to be positive or negative. Give a reason for your answer. [1]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/1410u30-jun18-11-d-qp.webp)
![Summer 2017 Unit 3, question 6: Place the following substances in order of increasing entropy under standard conditions. [1] nitrogen gas copper metal water air Lowest Highest](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/1410u30-jun17-06-qp.webp)
Q10(d)(i)
The whole paper ↗![Summer 2017 Unit 3, question 10(d)(i): [3] ΔGθ = kJ mol−1](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/1410u30-jun17-10-di-qp.webp)
Q10(d)(ii)
The whole paper ↗
All 16 questions on Entropy and feasibility of reactions, as a list
- Summer 2025, Unit 3, Q7(a)(i) (1 mark): Give a reason why all the entropy changes are positive. [1]
- Summer 2025, Unit 3, Q7(a)(ii) (3 marks): The minimum temperature for decomposition of calcium nitrate is 1500 °C. Find the standard enthalpy change for this reaction. [3] kJ mol–1 Standard enthalpy cha
- Summer 2024, Unit 3, Q8(d)(ii) (9 marks): This catalyst is used to catalyse the oxidation of sulfur dioxide. ΔHθ = –197 kJ mol–1 2SO2(g) + O2(g) 2SO3(g) ΔSθ = –187 J K–1 mol–1 The standard enthalpy chan
- Summer 2024, Unit 3, Q10(c)(ii) (6 marks): aqueous solution. [Cu(NH3)4(H2O)2]2+(aq) [Cu(cyclen)(H2O)2]2+(aq) + cyclen(aq) + 4NH3(aq) ΔHθ = +1.2 kJ mol–1 Measurements show that the strengths of the Cu―N b
- Summer 2023, Unit 3, Q8(d)(ii) (2 marks): Calculate the minimum temperature required for this reaction. [2] minimum temperature = K
- Summer 2023, Unit 3, Q10(a) (3 marks): Some thermodynamic data for F2O and Cl2O are given below. Standard enthalpy change of Standard molar entropy, Substance formation, ∆fHθ / kJ mol−1 Sθ / J K−1 mo
- Summer 2022, Unit 3, Q7 (1 mark): Give a reason why the entropy of Hg(l) is greater than that of Au(s). [1]
- Summer 2022, Unit 3, Q8(b)(iii) (2 marks): A student suggests that the entropy change for the formation of sodium chloride must be positive as the reaction occurs easily. Is the student correct? Justify
- Summer 2022, Unit 3, Q10(e) (3 marks): Some data regarding the dissociation of another weak acid, HX, at two different temperatures are given in the table. H+ X– HX + HX HX at 298 K at temperature T
- Summer 2019, Unit 3, Q6 (1 mark): The entropy change of the reaction shown below is positive. Give a reason for this. [1] Na2CO3(aq) + 2HCl(aq) 2NaCl(aq) + CO2(g) + H2O(l)
- Summer 2019, Unit 3, Q9(b)(i) (3 marks): A laboratory manual suggests a minimum temperature of 200 °C to remove all the water from the hydrated calcium chloride. At this temperature the reaction occurr
- Summer 2018, Unit 3, Q6 (1 mark): The enthalpy of solution of sodium chloride is +4 kJ mol–1. Explain why this compound is soluble 6 in water despite this value being positive. [1]
- Summer 2018, Unit 3, Q11(d) (1 mark): State whether you would expect the entropy change for the decomposition of hydrogen peroxide to be positive or negative. Give a reason for your answer. [1]
- Summer 2017, Unit 3, Q6 (1 mark): Place the following substances in order of increasing entropy under standard conditions. [1] nitrogen gas copper metal water air Lowest Highest
- Summer 2017, Unit 3, Q10(d)(i) (3 marks): [3] ΔGθ = kJ mol−1
- Summer 2017, Unit 3, Q10(d)(ii) (1 mark): An alternative method of preparing aqua regia is to use concentrated hydrochloric acid with concentrated nitric acid. State, giving a reason, the effect of this
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