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Energetics: AQA A‑Level Chemistry questions

Every AQA A-Level Chemistry exam question on 3.1.4 Energetics, 2016–2025, with its mark scheme and examiner’s report.

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2,301 questions

  1. Q04.1

    June 2025 · Paper 1

    The whole paper ↗
    June 2025 Paper 1, question 04.1: Give the standard conditions indicated by the symbol o in ΔfH o and S o [1 mark]
  2. Q04.3

    June 2025 · Paper 1

    The whole paper ↗
    June 2025 Paper 1, question 04.3: Assume that the bonds between N and O in NO2 are the same. Calculate the mean bond enthalpy, in kJ mol–1, for a bond between N and O in NO2 [3 marks] Bond entha
  3. Q01.1

    June 2025 · Paper 3

    The whole paper ↗
    June 2025 Paper 3, question 01.1: Give the equation, including state symbols, for the process that occurs when the enthalpy of solution of potassium hydroxide is determined. [1 mark]
  4. Q01.2

    June 2025 · Paper 3

    The whole paper ↗
    June 2025 Paper 3, question 01.2: A student does an experiment to determine a value for the enthalpy of solution of potassium hydroxide. The student uses this method. • Add some distilled water
  5. Q01.4

    June 2025 · Paper 3

    The whole paper ↗
    June 2025 Paper 3, question 01.4: Suggest why the value calculated in Question 01.3 is different from the experimental value given in Question 01.2. [1 mark]
  6. Q18

    June 2025 · AS Paper 1

    The whole paper ↗
    June 2025 AS Paper 1, question 18: The reaction between hydrochloric acid and sodium hydroxide is exothermic. Which row shows the solutions that will give the greatest temperature increase when m
  7. Q07.1

    June 2025 · AS Paper 2

    The whole paper ↗
    June 2025 AS Paper 2, question 07.1: Define enthalpy change. [1 mark]
  8. Q07.2

    June 2025 · AS Paper 2

    The whole paper ↗
    June 2025 AS Paper 2, question 07.2: The enthalpy of combustion of ethanol is –1371 kJ mol–1 A sample of ethanol is burned completely in air to raise the temperature of 55.0 g of water by 46.2 °C C
  9. Q07.3

    June 2025 · AS Paper 2

    The whole paper ↗
    June 2025 AS Paper 2, question 07.3: Use Table 2 to show that an expression for the sum of the bond enthalpies for all the bonds in the products is 2536n + 926 [1 mark]
  10. Q07.4

    June 2025 · AS Paper 2

    The whole paper ↗
    June 2025 AS Paper 2, question 07.4: An expression for the sum of the bond enthalpies for all the bonds in the reactants is 1916n + 724 A calculated value for the enthalpy of combustion of an alkan
  11. Q18

    June 2025 · AS Paper 2

    The whole paper ↗
    June 2025 AS Paper 2, question 18: The standard enthalpies of combustion for carbon, hydrogen and benzene (C6H6) are –394, –286 and –3273 kJ mol–1 respectively. What is the standard enthalpy of f
  12. Q22

    June 2025 · AS Paper 2

    The whole paper ↗
    June 2025 AS Paper 2, question 22: Which reaction at 298 K has a standard enthalpy change equal to the standard enthalpy of formation of liquid iodoethane? [1 mark] A 1 2 I2(I) + 2 C(s) + 5 2 H2(
  13. Q11.1

    June 2024 · Paper 2

    The whole paper ↗
    June 2024 Paper 2, question 11.1: Limonene is found in the skin of citrus fruits. Figure 6 shows a diagram of the apparatus used in an experiment to determine a value for the enthalpy of combust
  14. Q11.2

    June 2024 · Paper 2

    The whole paper ↗
    June 2024 Paper 2, question 11.2: Table 3 shows values, obtained by different methods, for the enthalpy of combustion of a different liquid hydrocarbon. Table 3 Method Enthalpy of combustion / k
  15. Q08.1

    June 2024 · AS Paper 1

    The whole paper ↗
    June 2024 AS Paper 1, question 08.1: Define standard enthalpy of formation. [2 marks]
  16. Q08.2

    June 2024 · AS Paper 1

    The whole paper ↗
    June 2024 AS Paper 1, question 08.2: Silver nitrate(V) is formed when silver nitrate(III) undergoes thermal decomposition. 2 AgNO2(s) ⟶ Ag(s) + AgNO3(s) + NO(g) ΔH = +56.2 kJ mol–1 The standard ent
  17. Q08.3

    June 2024 · AS Paper 1

    The whole paper ↗
    June 2024 AS Paper 1, question 08.3: Suggest why the enthalpy change for the thermal decomposition of solid silver nitrate(III) is difficult to determine experimentally. [1 mark]
  18. Q08.4

    June 2024 · AS Paper 1

    The whole paper ↗
    June 2024 AS Paper 1, question 08.4: Identify three aspects of this method which could cause inaccurate results. Describe how the student could improve these three aspects of the method to obtain m
  19. Q19

    June 2024 · AS Paper 2

    The whole paper ↗
    June 2024 AS Paper 2, question 19: What is the enthalpy of combustion, in kJ mol–1, of propane? [1 mark] A −211.7 B −419.7 C −2220 D −2878
  20. Q20

    June 2024 · AS Paper 2

    The whole paper ↗
    June 2024 AS Paper 2, question 20: What is the enthalpy change, in kJ mol–1, when butane reacts to form propane, hydrogen and carbon? [1 mark] A +21.2 B +17.5 C −17.5 D −21.2
All 112 questions on Energetics, as a list
  1. June 2025, Paper 1, Q04.1 (1 mark): Give the standard conditions indicated by the symbol o in ΔfH o and S o [1 mark]
  2. June 2025, Paper 1, Q04.3 (3 marks): Assume that the bonds between N and O in NO2 are the same. Calculate the mean bond enthalpy, in kJ mol–1, for a bond between N and O in NO2 [3 marks] Bond entha
  3. June 2025, Paper 3, Q01.1 (1 mark): Give the equation, including state symbols, for the process that occurs when the enthalpy of solution of potassium hydroxide is determined. [1 mark]
  4. June 2025, Paper 3, Q01.2 (5 marks): A student does an experiment to determine a value for the enthalpy of solution of potassium hydroxide. The student uses this method. • Add some distilled water
  5. June 2025, Paper 3, Q01.4 (1 mark): Suggest why the value calculated in Question 01.3 is different from the experimental value given in Question 01.2. [1 mark]
  6. June 2025, AS Paper 1, Q18 (1 mark): The reaction between hydrochloric acid and sodium hydroxide is exothermic. Which row shows the solutions that will give the greatest temperature increase when m
  7. June 2025, AS Paper 2, Q07.1 (1 mark): Define enthalpy change. [1 mark]
  8. June 2025, AS Paper 2, Q07.2 (5 marks): The enthalpy of combustion of ethanol is –1371 kJ mol–1 A sample of ethanol is burned completely in air to raise the temperature of 55.0 g of water by 46.2 °C C
  9. June 2025, AS Paper 2, Q07.3 (1 mark): Use Table 2 to show that an expression for the sum of the bond enthalpies for all the bonds in the products is 2536n + 926 [1 mark]
  10. June 2025, AS Paper 2, Q07.4 (3 marks): An expression for the sum of the bond enthalpies for all the bonds in the reactants is 1916n + 724 A calculated value for the enthalpy of combustion of an alkan
  11. June 2025, AS Paper 2, Q18 (1 mark): The standard enthalpies of combustion for carbon, hydrogen and benzene (C6H6) are –394, –286 and –3273 kJ mol–1 respectively. What is the standard enthalpy of f
  12. June 2025, AS Paper 2, Q22 (1 mark): Which reaction at 298 K has a standard enthalpy change equal to the standard enthalpy of formation of liquid iodoethane? [1 mark] A 1 2 I2(I) + 2 C(s) + 5 2 H2(
  13. June 2024, Paper 2, Q11.1 (4 marks): Limonene is found in the skin of citrus fruits. Figure 6 shows a diagram of the apparatus used in an experiment to determine a value for the enthalpy of combust
  14. June 2024, Paper 2, Q11.2 (5 marks): Table 3 shows values, obtained by different methods, for the enthalpy of combustion of a different liquid hydrocarbon. Table 3 Method Enthalpy of combustion / k
  15. June 2024, AS Paper 1, Q08.1 (2 marks): Define standard enthalpy of formation. [2 marks]
  16. June 2024, AS Paper 1, Q08.2 (2 marks): Silver nitrate(V) is formed when silver nitrate(III) undergoes thermal decomposition. 2 AgNO2(s) ⟶ Ag(s) + AgNO3(s) + NO(g) ΔH = +56.2 kJ mol–1 The standard ent
  17. June 2024, AS Paper 1, Q08.3 (1 mark): Suggest why the enthalpy change for the thermal decomposition of solid silver nitrate(III) is difficult to determine experimentally. [1 mark]
  18. June 2024, AS Paper 1, Q08.4 (6 marks): Identify three aspects of this method which could cause inaccurate results. Describe how the student could improve these three aspects of the method to obtain m
  19. June 2024, AS Paper 2, Q19 (1 mark): What is the enthalpy of combustion, in kJ mol–1, of propane? [1 mark] A −211.7 B −419.7 C −2220 D −2878
  20. June 2024, AS Paper 2, Q20 (1 mark): What is the enthalpy change, in kJ mol–1, when butane reacts to form propane, hydrogen and carbon? [1 mark] A +21.2 B +17.5 C −17.5 D −21.2
  21. June 2023, Paper 2, Q08.2 (5 marks): Palmitic acid burns in air. In a calorimetry experiment, combustion of 387 mg of palmitic acid increases the temperature of 0.150 kg of water from 23.9 °C to 37
  22. June 2023, Paper 2, Q08.3 (2 marks): State how the value calculated in Question 08.2 is likely to differ from data book values. Give one reason, other than heat loss, for this difference. [2 marks]
  23. June 2023, Paper 2, Q08.6 (3 marks): Ethanol is a biofuel that can be produced by the fermentation of glucose. C6H12O6 → 2 C2H5OH + 2 CO2 Glucose has the structural formula shown. Table 3 shows som
  24. June 2023, Paper 2, Q08.7 (2 marks): The carbon dioxide produced from fermentation can be reacted with steam to make more ethanol. The equation for this reaction is 2 CO2(g) + 3 H2O(g) → C2H5OH(g)
  25. June 2023, Paper 3, Q05.1 (3 marks): Calculate ∆Hvap for water. [1 kW = 1 kJ s–1] [3 marks] ∆Hvap kJ mol–1
  26. June 2023, Paper 3, Q10 (1 mark): Which reaction has a standard enthalpy change equal to the standard enthalpy of formation for barium chloride? [1 mark] A Ba(g) + Cl2(g) → BaCl2(s) B Ba2+(g) +
  27. June 2023, AS Paper 1, Q15 (1 mark): Which reaction has an enthalpy change equal to the standard enthalpy of formation of potassium oxide? [1 mark] A 4 K(s) + O2(g) → 2 K2O(s) B 2 K(s) + O(g) → K2O
  28. June 2023, AS Paper 2, Q05.1 (3 marks): The student finds that when all the alcohol is burned, the temperature of the water increases from 18.9 °C to 78.1 °C Calculate the enthalpy of combustion, in k
  29. June 2023, AS Paper 2, Q05.2 (2 marks): Table 2 shows the enthalpies of combustion of some alcohols. Table 2 Alcohol Enthalpy of combustion / kJ mol –1 Ethanol –1367 Propan-1-ol –2021 Butan-1-ol –2676
  30. June 2023, AS Paper 2, Q05.3 (3 marks): The equation for the complete combustion of gaseous pentan-1-ol is shown. CH3(CH2)3CH2OH(g) + 7 1 2 O2(g) → 5 CO2(g) + 6 H2O(g) ΔH= –3388 kJ mol–1 Table 3 shows
  31. June 2023, AS Paper 2, Q05.4 (2 marks): The energy stored in fuels can be compared using energy density values measured in kJ dm–3 Calculate the energy density of butan-1-ol. enthalpy of combustion of
  32. June 2022, Paper 1, Q03.5 (5 marks): Hydrazine (N2H4) is used as a rocket fuel that is oxidised by hydrogen peroxide. The equation for this reaction in the gas phase is The enthalpy change for this
  33. June 2022, Paper 3, Q01.3 (3 marks): A student does an experiment to determine a value for the enthalpy of solution for ammonium nitrate. The student uses this method. • Measure 25.0 cm3 of distill
  34. June 2022, Paper 3, Q01.4 (1 mark): The uncertainty in each of the temperature readings from the thermometer used in this experiment is ±0.1°C Calculate the percentage uncertainty in the temperatu
  35. June 2022, Paper 3, Q01.5 (2 marks): Suggest a change to the student’s method, using the same apparatus, that would reduce the percentage uncertainty in the temperature change. Give a reason for yo
  36. June 2022, Paper 3, Q01.6 (1 mark): Another student obtained a value of +15 kJ mol−1 using the same method. Suggest the main reason for the difference between this experimental value for the entha
  37. June 2022, AS Paper 2, Q07.3 (2 marks): Table 2 shows the enthalpies of combustion of the three fuels from the fermentation of silverskin. Table 2 Fuel Standard enthalpy of combustion / kJ mol–1 Energ
  38. June 2022, AS Paper 2, Q07.4 (4 marks): A student investigated the combustion of propanone (C3H6O) using calorimetry. A copper calorimeter containing water was heated by the complete combustion of som
  39. June 2022, AS Paper 2, Q07.5 (3 marks): Butan-1-ol can be added to petrol for cars. An equation for the complete combustion of gaseous butan-1-ol is shown. C4H9OH(g) + 6 O2(g) → 4 CO2(g) + 5 H2O(g) ΔH
  40. November 2021, Paper 1, Q01.1 (1 mark): State the meaning of the term enthalpy change. [1 mark]
  41. November 2021, Paper 2, Q03.1 (2 marks): Design a table to record all the readings necessary to determine an experimental value for the enthalpy of combustion for heptane in this experiment. [2 marks]
  42. November 2021, Paper 2, Q03.2 (2 marks): The student considered using a glass beaker on a tripod and gauze instead of the clamped copper calorimeter. Suggest two disadvantages of using a glass beaker o
  43. November 2021, Paper 2, Q03.3 (2 marks): Suggest two reasons why the value of enthalpy of combustion from this experiment is less exothermic than a data book value. [2 marks] Reason 1 Reason 2
  44. November 2021, Paper 2, Q03.4 (1 mark): Suggest one addition to this apparatus that would improve the accuracy of the enthalpy value obtained. [1 mark]
  45. November 2021, Paper 2, Q04.1 (3 marks): Use Figure 3 and the data shown in Table 1 to calculate ΔH2 [3 marks] Table 1 ΔH / kJ mol–1 Enthalpy of atomisation for carbon +715 Enthalpy of atomisation for
  46. November 2021, AS Paper 1, Q07.1 (2 marks): State the meaning of the term standard enthalpy of combustion. [2 marks]
  47. November 2021, AS Paper 1, Q07.2 (3 marks): A student does an experiment to determine the enthalpy of combustion of propan-1-ol (CH3CH2CH2OH, Mr = 60.0). Combustion of 0.497 g of propan-1-ol increases the
  48. November 2021, AS Paper 1, Q07.3 (1 mark): The enthalpy of combustion determined experimentally is less exothermic than that calculated using enthalpies of formation. Give one possible reason for this, o
  49. November 2021, AS Paper 2, Q08.1 (1 mark): Define the term enthalpy change. [1 mark]
  50. November 2021, AS Paper 2, Q08.2 (4 marks): Propane undergoes complete combustion. C3H8(g) + 5 O2(g) ⟶ 3 CO2(g) + 4 H2O(l) ∆H = –2046 kJ mol–1 Table 3 shows some bond enthalpy data. Table 3 Bond C–H C=O O
  51. November 2021, AS Paper 2, Q08.3 (1 mark): Explain why the value given for the O=O bond enthalpy in Question 08.2 is not a mean value. [1 mark] Section B Answer all questions in this section. Only one an
  52. November 2020, Paper 3, Q05.1 (3 marks): The heat energy released in the calorimeter, q = Ccal∆T Calculate the heat capacity (Ccal) in kJ K−1 [3 marks] Ccal kJ K−1
  53. November 2020, Paper 3, Q05.2 (2 marks): When the experiment is repeated with 2.00 g of octane (Mr = 114.0) the temperature change recorded is 12.2 °C Calculate the heat change, in kJ mol−1, for octane
  54. November 2020, Paper 3, Q05.3 (1 mark): State why the heat change calculated from the bomb calorimeter experiment is not an enthalpy change. [1 mark]
  55. November 2020, Paper 3, Q05.4 (2 marks): The thermometer used to measure the temperature change of 12.2 °C in Question 05.2 has an uncertainty of ± 0.1 °C in each reading. Calculate the percentage unce
  56. November 2020, Paper 3, Q09 (1 mark): Which reaction has an enthalpy change equal to the standard enthalpy of formation of silver iodide? [1 mark] A Ag(g) + 1 2 I2(g) → AgI(s) B Ag(s) + 1 2 I2(s) →
  57. November 2020, Paper 3, Q10 (1 mark): Some bond enthalpies are given. Bond C H O H O=O C=O Bond enthalpy/ kJ mol–1 412 463 496 743 Which is the enthalpy change of this reaction in kJ mol−1? CH4(g) +
  58. November 2020, AS Paper 1, Q04.1 (1 mark): State the meaning of the term enthalpy change as applied to a chemical reaction. [1 mark]
  59. November 2020, AS Paper 1, Q04.2 (6 marks): A student determines the enthalpy change for the reaction between calcium carbonate and hydrochloric acid. CaCO3(s) + 2 HCl(aq) → CaCl2(aq) + CO2(g) + H2O(l) Th
  60. November 2020, AS Paper 1, Q04.3 (5 marks): In a different experiment 50.0 cm3 of 0.500 mol dm–3 aqueous hydrochloric acid are reacted with 50.0 cm3 of 0.500 mol dm–3 aqueous sodium hydroxide. NaOH(aq) +
  61. November 2020, AS Paper 1, Q04.4 (1 mark): Suggest how, without changing the apparatus, the experiment in Question 04.3 could be improved to reduce the percentage uncertainty in the temperature change. [
  62. November 2020, AS Paper 1, Q12 (1 mark): Which reaction has an enthalpy change equal to the standard enthalpy of formation of lithium fluoride? [1 mark] A Li(g) + 1 2 F2(g) → LiF(s) B Li+(g) + F–(g) →
  63. November 2020, AS Paper 1, Q20 (1 mark): Two reactions of iron with oxygen are shown. Fe(s) + 1 2 O2(g) → FeO(s) ΔH = – 272 kJ mol–1 2 Fe(s) + 3 2 O2(g) → Fe2O3(s) ΔH = – 822 kJ mol–1 What is the entha
  64. November 2020, AS Paper 2, Q01.1 (2 marks): Define the term standard enthalpy of formation. [2 marks]
  65. November 2020, AS Paper 2, Q01.2 (3 marks): The equation for a reaction used to manufacture 1-chloropropane is 3 CH3CH2CH2OH(l) + PCl3(l) → 3 CH3CH2CH2Cl(l) + H3PO3(s) The enthalpy change for this reactio
  66. November 2020, AS Paper 2, Q21 (1 mark): Some enthalpy change data are shown. C(s) + 2 H2(g) → CH4(g) ΔH = –75 kJ mol–1 H2(g) → 2 H(g) ΔH = +436 kJ mol–1 What is the enthalpy change, in kJ mol–1, for t
  67. November 2020, AS Paper 2, Q22 (1 mark): The temperature changed from 21.8 °C to 19.2 °C during a calorimetry experiment. The uncertainty of each reading of the thermometer is ±0.1 °C What is the perce
  68. November 2020, AS Paper 2, Q23 (1 mark): An experiment is done to determine the enthalpy of combustion of a fuel using a calorimeter containing water. b = mass of fuel burned / g w = mass of water heat
  69. June 2019, Paper 3, Q08 (1 mark): Nitrogen dioxide is produced from ammonia and air as shown in these equations 4 NH3(g) + 5 O2(g) → 4 NO(g) + 6 H2O(g) ΔH = –909 kJ mol–1 2 NO(g) + O2(g) → 2 NO2
  70. June 2019, AS Paper 1, Q01.5 (3 marks): Hydrogen fluoride reacts with ethyne (C2H2) as shown in the equation. All compounds are in the gaseous state. ∆H = –179 kJ mol–1 Table 1 shows some mean bond en
  71. June 2019, AS Paper 1, Q14 (1 mark): Which equation represents the reaction that has a standard enthalpy change equal to the standard enthalpy of formation for barium chloride? [1 mark] A Ba(g) + C
  72. June 2019, AS Paper 1, Q20 (1 mark): Some fuel in a spirit burner is burned, and the heat produced is used to heat a container of water. In this experiment: The mass of water heated = m g The tempe
  73. June 2019, AS Paper 2, Q03.1 (4 marks): A student determined the enthalpy of combustion of cyclohexane (C6H12). The student • placed a pure sample of cyclohexane in a spirit burner • placed the spirit
  74. June 2019, AS Paper 2, Q03.2 (1 mark): A data book value for the enthalpy of combustion of cyclohexane is –3920 kJ mol−1 The student concluded that the temperature rise recorded in the experiment was
  75. June 2019, AS Paper 2, Q03.3 (3 marks): Table 2 gives some values of standard enthalpies of combustion (∆cHo). Table 2 Substance C(s) H2(g) C6H12(l) Standard enthalpy of combustion, ∆cHo / kJ mol–1 –3
  76. June 2018, Paper 2, Q03.4 (3 marks): A student carried out an experiment to determine the enthalpy of combustion of ethanol. Combustion of 457 mg of ethanol increased the temperature of 150 g of wa
  77. June 2018, Paper 3, Q04.1 (5 marks): Plot a graph of temperature against time on the grid opposite. Use your graph to find the temperature rise, ∆T, at the fourth minute. Show your working on the g
  78. June 2018, Paper 3, Q04.2 (1 mark): The uncertainty in each of the temperature readings from the thermometer used in this experiment was ±0.1° C Calculate the percentage uncertainty in the value f
  79. June 2018, Paper 3, Q04.3 (1 mark): Suggest a change to the experiment that would minimise heat loss. [1 mark]
  80. June 2018, Paper 3, Q04.4 (2 marks): Suggest and explain another change to the experiment that would decrease the percentage uncertainty in the use of the same thermometer. [2 marks]
  81. June 2018, Paper 3, Q04.5 (5 marks): A second student completed an experiment to determine the enthalpy of neutralisation for the reaction between ethanedioic acid solution (HOOCCOOH) and potassium
  82. June 2018, Paper 3, Q04.6 (2 marks): In a similar experiment to that in Question 04.5, the enthalpy of neutralisation for the reaction between sulfuric acid and potassium hydroxide solution was fou
  83. June 2018, AS Paper 1, Q07.5 (2 marks): Potassium chlorate(VII), KClO4, is used in fireworks. When potassium chlorate(VII) decomposes, it produces potassium chloride and oxygen. Give an equation for t
  84. June 2018, AS Paper 2, Q03.1 (4 marks): When ethanoic acid reacts with sodium hydroxide, the enthalpy change, ∆H, is –56.1 kJ mol–1 CH3COOH(aq) + NaOH(aq) ⟶ CH3COONa(aq) + H2O(l) Calculate the tempera
  85. June 2018, AS Paper 2, Q03.2 (2 marks): A student recorded the temperature of aqueous ethanoic acid in a polystyrene cup for three minutes. At the fourth minute, the student added sodium hydrogencarbo
  86. June 2018, AS Paper 2, Q20 (1 mark): What is the enthalpy of formation of buta-1,3-diene, C4H6(g)? Substance Enthalpy of combustion / kJ mol–1 C4H6(g) –2546 C(s) –394 H2(g) –286 [1 mark] A +112 kJ
  87. June 2017, Paper 3, Q01.1 (1 mark): Suggest one reason why the enthalpy change for this reaction cannot be determined directly by calorimetry. [1 mark]
  88. June 2017, Paper 3, Q01.2 (2 marks): Some enthalpies of solution are shown in Table 1. Table 1 Salt Enthalpy of solution / kJ mol−1 MgCl2(s) −155 MgCl2.4H2O(s) −39 Calculate the enthalpy change for
  89. June 2017, Paper 3, Q01.3 (6 marks): Describe how you would carry out an experiment to determine the enthalpy of solution of anhydrous magnesium chloride. You should use about 0.8 g of anhydrous ma
  90. June 2017, AS Paper 1, Q02.1 (1 mark): Write an equation, including state symbols, for the reaction with an enthalpy change equal to the enthalpy of formation for iron(III) oxide. [1 mark
  91. June 2017, AS Paper 1, Q02.2 (3 marks): Table 2 contains some standard enthalpy of formation data. Table 2 CO(g) Fe2O3(s) ΔfH o / kJ mol−1 −111 −822 Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g) ΔH = −19 kJ mo
  92. June 2017, AS Paper 1, Q02.3 (3 marks): Some enthalpy data are given in Table 3. Table 3 Process ΔH / kJ mol−1 N2(g) + 3H2(g) → 2NH3(g) −92 N2(g) → 2N(g) +944 H2(g) → 2H(g) +436 Use the data from Tabl
  93. June 2017, AS Paper 1, Q02.4 (1 mark): Give one reason why the bond enthalpy that you calculated in Question 2.3 is different from the mean bond enthalpy quoted in a data book (388 kJ mol−1). [1 mark
  94. June 2017, AS Paper 1, Q03.1 (6 marks): Show by calculation which reactant was in excess. Use the data to calculate the experimental value for enthalpy of reaction in kJ mol−1(Assume that the specific
  95. June 2017, AS Paper 1, Q03.2 (1 mark): Another student used the same method and obtained a value for the enthalpy of reaction of −142 kJ mol−1 A data book value for the enthalpy of reaction is −310 k
  96. June 2017, AS Paper 1, Q03.3 (6 marks): Suggest how the students’ method, and the analysis of the results, could be improved in order to determine a more accurate value for the enthalpy of reaction. J
  97. June 2017, AS Paper 2, Q04.2 (2 marks): An expression can be derived using bond enthalpy data to estimate the enthalpy of combustion (∆cH) of an alkane. For an alkane with n carbon atoms: ∆cH = – (496
  98. June 2017, AS Paper 2, Q04.3 (1 mark): Suggest one reason, other than the use of mean bond enthalpies, why a value for the enthalpy of combustion of a liquid alkane is different from the value obtain
  99. June 2017, AS Paper 2, Q04.4 (3 marks): Values of the enthalpy change for combustion of 1 g of some alkanes are shown in Table 2. Table 2 methane ethane propane butane pentane Enthalpy change in kJ fo
  100. June 2017, AS Paper 2, Q04.5 (2 marks): Isooctane (2,2,4-trimethylpentane) is an important component of petrol used in cars. When isooctane is burned, the enthalpy change is −47.8 kJ g−1 Isooctane is
  101. June 2016, AS Paper 2, Q02.1 (4 marks): A student carried out an experiment to determine the enthalpy of combustion of methanol. Methanol was placed in a spirit burner and the mass of the spirit burne
  102. June 2016, AS Paper 2, Q02.2 (1 mark): Suggest one reason, other than incomplete combustion or heat transfer to the atmosphere, why the student’s value for the enthalpy of combustion of methanol is d
  103. June 2016, AS Paper 2, Q02.3 (1 mark): The uncertainty in each of the temperature readings from the thermometer in this experiment was ±0.25 °C. This gave an overall uncertainty in the temperature ri
  104. June 2016, AS Paper 2, Q02.4 (1 mark): The student said correctly that using a thermometer with an overall uncertainty for the rise in temperature of ±0.5 °C was adequate for this experiment. Explain
  105. June 2016, AS Paper 2, Q02.5 (3 marks): The enthalpy of combustion of ethanol is −1371 kJ mol−1. The density of ethanol is 0.789 g cm−3. Calculate the heat energy released in kJ when 0.500 dm3 of etha
  106. June 2016, AS Paper 2, Q22 (1 mark): Some enthalpy data is given in Table 3. Table 3 Bond C−H O−H H−H C≡O Bond enthalpy / kJ mol−1 413 463 436 To be calculated Use the information in Table 3 and th
  107. Specimen, Paper 1, Q04.1 (3 marks): H–H bond enthalpy = kJ mo
  108. Specimen, Paper 1, Q04.2: 9
  109. Specimen, Paper 1, Q04.3 (1 mark): Suggest one environmental advantage of manufacturing methanol fuel by this reaction. [1 mark] 0 4 . 3
  110. Specimen, Paper 1, Q09.1 (4 marks): 9 A 5.00 g sample of potassium chloride was added to 50.0 g of water initially at 20.0 °C. The mixture was stirred and as the potassium chloride dissolved, the
  111. Specimen, Paper 1, Q09.2 (4 marks): Enthalpy of solution = kJ mo 5
  112. Specimen, Paper 3, Q09 (1 mark): 6

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