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Making and hydrolysing esters: OCR A‑Level Chemistry A questions

OCR A-Level Chemistry A past-paper questions on 6.1.3.2 Making and hydrolysing esters, 2016–2025, with mark schemes and examiner’s reports where available.

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  2. The start of question 21

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  3. Q17(d)

    June 2024 · Paper 2

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  4. Q20(b)(i)

    June 2024 · Paper 2

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  7. Q14

    June 2023 · Paper 2

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  10. Q10

    June 2022 · Paper 2

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  12. Q6(b)(ii)

    June 2022 · Paper 3

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  13. Q6

    November 2021 · Paper 2

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  14. Q20(a)(iii)

    November 2021 · Paper 2

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  16. Q9

    November 2020 · Paper 2

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  20. Q18(a)(iii)

    June 2019 · Paper 2

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All 26 questions on Making and hydrolysing esters, as a list
  1. June 2025, Paper 2, Q9 (1 mark): Which reagents could a student use to prepare the ester shown? O CH3CH2 C O O A OH CH3CH2 C + HO CH3CH2 OH + HOOC B C CH3CH2CH2 OH + HOOC O D CH3CH2 C Cl + HO Y
  2. June 2025, Paper 2, Q21(e) (7 marks): Complete the flowchart for the reactions of pyruvic acid. excess NH3 Acyl chloride Compound P reagent(s) O NaOH(aq) O OH Pyruvic acid CH3OH / H2SO4 reagent(s) O
  3. June 2024, Paper 2, Q17(d) (2 marks): Esterification reaction of (CH3)3COH Reagent(s) and/or catalyst organic product [2]
  4. June 2024, Paper 2, Q20(b)(i) (1 mark): What is the systematic name for this ester? [1]
  5. June 2024, Paper 2, Q20(d) (4 marks): The compound below contains an ester and an amide group. O N O H O Draw the structures of the organic products formed by the complete alkaline hydrolysis of thi
  6. June 2024, Paper 2, Q23(b)(ii) (1 mark): Another student suggests that adding aqueous sodium hydroxide would be more effective in removing the sulfuric acid catalyst than Na2CO3(aq). Comment on whether
  7. June 2023, Paper 2, Q14 (1 mark): Which compound(s) is/are hydrolysed by HCl (aq) to produce butanoic acid? 1 CH3CH2CH2COOCH3 2 CH3CH2CH2CH2CN 3 CH3CH2CH2CH2Cl A 1, 2 and 3 B Only 1 and 2 C Only
  8. June 2023, Paper 3, Q5(b)(ii) (3 marks): In this reaction, 1 mol of aspirin reacts with 3 mol of hot NaOH(aq). Complete the equation for the reaction of aspirin with an excess of hot NaOH(aq). Show str
  9. June 2023, Paper 3, Q6(e) (6 marks): This question is about nitric acid, hydrochloric acid and sulfuric acid. (e)* Three reactions involving sulfuric acid are shown below. Reaction 1 Dilute sulfuri
  10. June 2022, Paper 2, Q10 (1 mark): Butyl propanoate is hydrolysed by aqueous sodium hydroxide. Which compound is one of the products of this hydrolysis? A C3H7ONa B C3H5O2Na C C4H9ONa D C4H7O2Na
  11. June 2022, Paper 2, Q19(b) (4 marks): The structure of 2-hydroxybutanoic acid is shown below. H CH3CH2 C COOH OH 2-hydroxybutanoic acid Fill in the flowchart for reactions involving 2-hydroxybutanoi
  12. June 2022, Paper 3, Q6(b)(ii) (2 marks): A ‘vitamin C ester’ tablet contains an ester with the molecular formula C22H38O7. This ester can be prepared by reacting vitamin C with a long chain carboxylic
  13. November 2021, Paper 2, Q6 (1 mark): CH3CH2COOCH3 is heated with aqueous sodium hydroxide to produce two organic products. What are the two organic products? A CH3CH2COOH and CH3OH B CH3CH2COONa an
  14. November 2021, Paper 2, Q20(a)(iii) (3 marks): Two molecules of salicylic acid can react together in the presence of an acid catalyst to form compound B. Compound B has three rings and a molecular formula of
  15. November 2020, Paper 2, Q3 (1 mark): Which of these reagent(s) will not react with HOCH2CH2CH2COOH? A NaCN in ethanol B C2H5OH in the presence of an acid catalyst C (CH3CO)2O D concentrated H2SO4 Y
  16. November 2020, Paper 2, Q9 (1 mark): What is the structural formula of ethyl 3-methylbutanoate? A CH3CH2COOCH2CH2CH(CH3)2 B CH3CH2COOCH(CH3)CH2CH3 C CH3CH2CH(CH3)COOCH2CH3 D (CH3)2CHCH2COOCH2CH3 Yo
  17. November 2020, Paper 2, Q14 (1 mark): Which of the following reactions produce propan-1-ol? 1 The alkaline hydrolysis of 1-chloropropane. 2 The acid hydrolysis of propyl methanoate. 3 The acid hydro
  18. June 2019, Paper 2, Q18(a)(i) (1 mark): What is the systematic name of ester A? [1]
  19. June 2019, Paper 2, Q18(a)(ii) (5 marks): In the boxes, draw the organic products for the reactions of the functional groups in ester A shown below. Each reaction forms two organic products. + H+(aq) O
  20. June 2019, Paper 2, Q18(a)(iii) (1 mark): Name the type of reactions of ester A shown in (ii). [1]
  21. June 2018, Paper 2, Q16(c) (3 marks): The flowchart below shows some reactions of compound C. In the boxes, draw the organic products of these reactions. excess CH3OH/H2SO4 Steam COOH HOOC H3PO4 com
  22. June 2018, Paper 3, Q5(b)(ii) (1 mark): Write the equation for the equilibrium reaction that takes place. [1]
  23. June 2018, Paper 3, Q5(b)(iii) (1 mark): Draw the skeletal formula of the ester present in the equilibrium mixture. [1]
  24. June 2017, Paper 2, Q21 (6 marks): 21* Compound L is an organic compound containing carbon, hydrogen and oxygen only. The 1H NMR spectrum of compound L is shown below. The numbers by the peaks ar
  25. June 2017, Paper 3, Q4(b)(ii) (3 marks): Compound A is heated with a few drops of concentrated sulfuric acid as a catalyst. A cyclic ‘dimer’ of compound A forms. Equation Type of reaction [3]
  26. June 2017, Paper 3, Q5(a)(ii) (2 marks): Thiols react with carboxylic acids to form thioesters. Write an equation for the reaction of butane-1-thiol with ethanoic acid. Use structures for all organic c

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