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Identification of functional groups by test-tube reactions: AQA A‑Level Chemistry questions

AQA A-Level Chemistry past-paper questions on 3.3.6.1 Identification of functional groups by test-tube reactions, 2008–2025, with mark schemes and examiner’s reports where available.

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  1. The start of question 05

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  2. Q01.1

    June 2024 · AS Paper 2

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  6. Q01.1

    June 2023 · AS Paper 2

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  7. Q01.2

    June 2023 · AS Paper 2

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  9. Q06.6

    November 2021 · Paper 3

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  11. The start of question 03

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  13. The start of question 06

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  15. The start of question 13

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  17. Q01.1

    June 2019 · AS Paper 2

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  18. Q01.2

    June 2019 · AS Paper 2

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All 46 questions on Identification of functional groups by test-tube reactions, as a list
  1. June 2024, Paper 2, Q05.2 (3 marks): Three unlabelled bottles are known to contain either propan-1-ol, propanal, or propanone. A sample of each liquid is warmed with a few drops of Fehling’s soluti
  2. June 2024, AS Paper 2, Q01.1 (3 marks): Table 1 shows the results of chemical tests on three organic compounds. Complete the empty boxes in the table. Table 1 Chemical test Add bromine water orange to
  3. June 2023, Paper 2, Q06.1 (1 mark): Identify the missing reagent needed in Test 1. [1 mark]
  4. June 2023, Paper 2, Q06.2 (2 marks): In addition to the missing reagent in Test 1, there is a mistake in the method for two of the other tests. State the two mistakes. Suggest how each of the mista
  5. June 2023, Paper 2, Q06.3 (8 marks): The missing reagent is added and the mistakes are corrected. Identify the liquid(s), J, K, L and M, that would react in each test. State the expected observatio
  6. June 2023, AS Paper 2, Q01.1 (3 marks): and 01.2, give a reagent (or combination of reagents) that could be added separately to each compound in a single reaction to distinguish between them. State wh
  7. June 2023, AS Paper 2, Q01.2 (3 marks): Cyclohexane and cyclohexene [3 marks] Reagent(s) Observation with cyclohexane Observation with cyclohexene
  8. June 2022, AS Paper 2, Q02 (6 marks): A student has samples of these four compounds but does not know which is which: • butanoic acid • 2-methylpropanal • 2-methylpropanoic acid • 2-methylpropan-1-o
  9. November 2021, Paper 3, Q06.6 (3 marks): State a simple chemical test that distinguishes the propanoic acid from the propan-1-ol. Give one observation for the test with each substance. [3 marks] Test P
  10. November 2021, AS Paper 2, Q07.4 (1 mark): Figure 3 shows the infrared spectrum of a functional group isomer of prop-2-en-1-ol. Figure 3 This isomer reacts with acidified potassium dichromate(VI) to form
  11. November 2020, Paper 2, Q03.2 (2 marks): Identify the isomer(s) that would react with Tollens’ reagent. State the expected observation when Tollens’ reagent reacts. [2 marks] Isomer(s) Expected observa
  12. November 2020, Paper 3, Q24 (1 mark): Which compound decolourises bromine water in the absence of sunlight? [1 mark] A CH3CH2CH2Br B C D CH3CH2CHCH2
  13. November 2020, AS Paper 2, Q06.2 (2 marks): State what you would observe if bromine water was added to poly(chloroethene). Explain this observation. [2 marks] Observation Explanation
  14. June 2019, Paper 2, Q06.1 (3 marks): Give a reagent and observations for a test-tube reaction to distinguish between 2-methylbutan-1-ol and 2-methylbutan-2-ol. [3 marks] Reagent Observation with 2-
  15. June 2019, Paper 2, Q13.2 (2 marks): A student attempted to reduce a sample of 2-methylbutanal but added insufficient NaBH4 The student confirmed that the reduction was incomplete by using a chemic
  16. June 2019, Paper 3, Q23 (1 mark): Three reagents are added separately to four organic compounds. Which row shows the correct observations? [1 mark] Sodium hydrogen carbonate Acidified potassium
  17. June 2019, AS Paper 2, Q01.1 (3 marks): and 01.2, give a reagent (or combination of reagents) that could be added separately to each compound to distinguish between them. State what is observed in eac
  18. June 2019, AS Paper 2, Q01.2 (3 marks): Compounds A and C [3 marks] Reagent Observation with A Observation with C
  19. June 2018, Paper 2, Q03.3 (2 marks): Describe how you would carry out a simple test-tube reaction to confirm that the sample of propanal obtained by distillation does not contain any propanoic acid
  20. June 2018, Paper 3, Q03.2 (2 marks): Describe a test-tube reaction, on the product, to show that the cyclohexanol had been dehydrated. State what you would observe. [2 marks]
  21. June 2018, AS Paper 2, Q07.1 (6 marks): Four compounds, all colourless liquids, are • butan-2-ol • butanal • butanone • 2-methylpropan-2-ol Two of these compounds can be identified using different tes
  22. June 2017, Paper 2, Q07.1 (6 marks): You are provided with samples of each of the four compounds. Describe how you could distinguish between all four compounds using the minimum number of tests on
  23. June 2016, AS Paper 2, Q03.7 (2 marks): Oleic acid (C18H34O2) is a straight-chain fatty acid obtained from plant oils. Isooctane can be made from oleic acid. The skeletal formula of oleic acid is show
  24. June 2016, AS Paper 2, Q09 (1 mark): Which of the following compounds would form an orange-red precipitate when heated with Fehling’s solution? [1 mark] A CH3CH2CN B CH3CH2COOH C CH3CHO D CH3COCH3
  25. Specimen, Paper 3, Q01.5 (5 marks): 5
  26. June 2016, CHEM4 (old spec), Q4(c) (3 marks): Compound Q is an alternative product that could be formed when X reacts with benzene. Describe how you could distinguish between P and Q by a test-tube reaction
  27. June 2016, CHEM2 (old spec), Q4(b) (3 marks): Compounds A and B are both straight-chain compounds. A can be oxidised to form P. B can be oxidised to form Q. P and Q are isomers with molecular formula C4H8O
  28. June 2015, CHEM4 (old spec), Q10(a) (3 marks): A simple test-tube reaction can be used to distinguish between isomers P and S. Identify a reagent (or combination of reagents) you could use. State what you wo
  29. June 2015, CHEM4 (old spec), Q10(b) (2 marks): A simple test-tube reaction can be used to distinguish between isomer Q and all the other isomers. Identify a reagent (or combination of reagents) you could use
  30. June 2015, CHEM2 (old spec), Q2(a) (3 marks): Butan-2-ol and 2-methylpropan-2-ol [3 marks] Reagent Observation with butan-2-ol Observation with 2-methylpropan-2-ol
  31. June 2015, CHEM2 (old spec), Q2(b) (3 marks): Propane and propene [3 marks] Reagent Observation with propane Observation with propene
  32. June 2014, CHEM4 (old spec), Q8(b) (5 marks): State how you could distinguish between compounds J and K by a simple test-tube reaction. State how you could distinguish between J and K by giving the number o
  33. June 2014, CHEM2 (old spec), Q7(b) (3 marks): A chemical test can be used to distinguish between separate samples of Isomer 1 and Isomer 2. Identify a suitable reagent for the test. State what you would obs
  34. June 2013, CHEM2 (old spec), Q2(c) (3 marks): Cyclohexane and cyclohexene Reagent Observation with cyclohexane Observation with cyclohexene
  35. June 2013, CHEM2 (old spec), Q2(d) (3 marks): Butanal and butanone Reagent Observation with butanal Observation with butanone
  36. January 2013, CHEM4 (old spec), Q6(a) (3 marks): Reagent Observation with R Observation with S
  37. January 2013, CHEM4 (old spec), Q6(b) (3 marks): Reagent Observation with T Observation with U
  38. January 2013, CHEM4 (old spec), Q6(c) (3 marks): Reagent Observation with V Observation with W
  39. January 2013, CHEM2 (old spec), Q10(d) (3 marks): State how you could test a sample of water to show that it contains chloride ions. In your answer, give a reagent, one observation and the simplest ionic equati
  40. June 2012, CHEM4 (old spec), Q7(a) (8 marks): A chemist discovered four unlabelled bottles of liquid, each of which contained a different pure organic compound. The compounds were known to be propan-1-ol, p
  41. January 2012, CHEM2 (old spec), Q6(b) (2 marks): A simple chemical test, using either Fehling’s solution or Tollens’ reagent, can be used to distinguish between compound 1 and compound 3. Choose one of these t
  42. January 2012, CHEM2 (old spec), Q10(b) (3 marks): A simple chemical test can be used to distinguish between cyclohexane (A) and cyclohexene (D). Give a reagent for this test and state what you would observe wit
  43. June 2011, CHEM4 (old spec), Q7(a)(i) (3 marks):
  44. June 2011, CHEM4 (old spec), Q7(a)(ii) (3 marks):
  45. June 2011, CHEM4 (old spec), Q7(a)(iii) (3 marks):
  46. June 2008, CHM4 (2008 spec), Q7(a) (9 marks): 7 (a) Describe, by giving reagents and stating observations, how you could distinguish between the compounds in the following pairs. Use one simple test-tube re

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