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Ligand substitution and haemoglobin: OCR A‑Level Chemistry A questions

OCR A-Level Chemistry A past-paper questions on 5.3.1.4 Ligand substitution and haemoglobin, 2016–2025, with mark schemes and examiner’s reports where available.

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  1. The start of question 22

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  2. The start of question 22

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  3. Q22(b)(ii)

    June 2023 · Paper 1

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    The start of question 22

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  4. Q4(c)(i)

    June 2023 · Paper 3

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  5. The start of question 22

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  6. The start of question 17

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  8. Q17(b)

    June 2019 · Paper 1

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  9. Q18(a)(i)

    June 2019 · Paper 1

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  10. The start of question 21

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  11. Q2(c)(i)

    June 2018 · Paper 3

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  13. The start of question 4

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  14. The start of question 23

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  15. The start of question 23

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All 15 questions on Ligand substitution and haemoglobin, as a list
  1. June 2024, Paper 1, Q22(b)(i) (3 marks): Suggest the formulae of A, B and C. Complex ion A: Solid B: Complex ion C: [3]
  2. June 2024, Paper 1, Q22(c) (5 marks): Red blood cells contain haemoglobin which transports oxygen around the body. For efficient transportation of oxygen, healthy human blood must be maintained at a
  3. June 2023, Paper 1, Q22(b)(ii) (2 marks): Describe ligand substitution reactions using either copper or chromium ions as examples. Include equations. [2]
  4. June 2023, Paper 3, Q4(c)(i) (1 mark): The student adds an excess of aqueous ammonia to their aqueous solution of Tutton’s salt. A deep blue solution forms. The complex ion responsible for the deep b
  5. June 2022, Paper 1, Q22(c) (6 marks): This question is about reactions of transition metal compounds. (c)* This question is about copper and copper compounds. Experiment 1 Hydrochloric acid, HCl (aq
  6. November 2021, Paper 1, Q17(b)(ii) (6 marks): This question is about d-block elements. (ii)* Determine the formulae of A and B. Write the ionic equation for the ligand substitution and show 3D structures fo
  7. November 2020, Paper 3, Q2 (6 marks): 2* Transition metal ions can bond to ligands to form complex ions with different shapes. Explain what is meant by the terms ligand, coordination number and liga
  8. June 2019, Paper 1, Q17(b) (3 marks): Red blood cells contain haemoglobin. Explain using ligand substitutions: • how haemoglobin transports oxygen around the body • why carbon monoxide is toxic. [3]
  9. June 2019, Paper 1, Q18(a)(i) (1 mark): What is the formula of the complex ion in the purple solution that forms in Experiment 1? [1]
  10. June 2018, Paper 1, Q21(d) (6 marks): This question is about some reactions of d block elements and their ions. Table 21.1 shows standard electrode potentials which will be needed within this questi
  11. June 2018, Paper 3, Q2(c)(i) (1 mark): Write the equilibrium equation for the reaction that takes place when the colour of the solution changes. [1]
  12. June 2018, Paper 3, Q2(c)(ii) (2 marks): Explain the observations and predict whether the formation of the blue colour is exothermic or endothermic. [2]
  13. June 2018, Paper 3, Q4(a)(ii) (2 marks): Cis-platin is prepared in a ligand substitution reaction which takes place in multiple steps. The equation for the final step forming cis-platin is shown below.
  14. June 2017, Paper 1, Q23(a)(i) (5 marks): In the boxes, write down the formulae of the species responsible for the observations. yellow solution Reaction 1 HCl(aq) NH3(aq) [Cu(H2O)6]2+ pale blue solutio
  15. June 2017, Paper 1, Q23(a)(ii) (2 marks): Name the type of reaction for Reaction 1 and Reaction 2. Reaction 1 Reaction 2 [2]

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