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Ligands and complex ion shapes: OCR A‑Level Chemistry A questions

OCR A-Level Chemistry A past-paper questions on 5.3.1.2 Ligands and complex ion shapes, 2016–2025, with mark schemes and examiner’s reports where available.

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  1. Q15

    June 2025 · Paper 1

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  2. Q21(b)(i)

    June 2025 · Paper 1

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  4. Q4(b)(ii)

    June 2025 · Paper 3

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  5. Q22(b)(ii)

    June 2024 · Paper 1

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  6. Q3(a)(i)

    June 2024 · Paper 3

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  7. Q22(c)

    June 2023 · Paper 1

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  8. Q22(a)(i)

    June 2022 · Paper 1

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  9. Q17(b)(i)

    November 2021 · Paper 1

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  11. Q18(a)(iii)

    June 2019 · Paper 1

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  12. Q2

    June 2017 · Paper 1

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  13. Q4(c)(i)

    June 2017 · Paper 3

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All 13 questions on Ligands and complex ion shapes, as a list
  1. June 2025, Paper 1, Q15 (1 mark): Chromium forms the complex ions [Cr(NH3)6]3+ and [Cr(OH)6]3–. Which statement(s) about the complexes is / are correct? 1 Chromium is in the same oxidation state
  2. June 2025, Paper 1, Q21(b)(i) (1 mark): What is meant by a monodentate ligand? [1]
  3. June 2025, Paper 1, Q21(b)(ii) (4 marks): An iron(II) complex contains two different ligands: C5H5N, and Cl –. The complex has a molar mass of 442.8 g mol–1 and the following percentage composition by m
  4. June 2025, Paper 3, Q4(b)(ii) (3 marks): Complex A can be prepared by reacting an aqueous solution of nickel(II) sulfate with amino acid B and potassium hydroxide. Aqueous nickel(II) sulfate contains t
  5. June 2024, Paper 1, Q22(b)(ii) (2 marks): Cobalt (III) forms an octahedral complex ion D, which contains both ammonia and chloride ligands. Complex ion D has a molar mass of 197.9 g mol–1. Determine the
  6. June 2024, Paper 3, Q3(a)(i) (2 marks): Explain what is meant by the term bidentate ligand. [2]
  7. June 2023, Paper 1, Q22(c) (2 marks): The ethanedioate ion, C2O4 A complex ion of cobalt(III) contains two ethanedioate ligands and two water ligands. Determine the charge of this complex ion and th
  8. June 2022, Paper 1, Q22(a)(i) (1 mark): Explain why ethane-1,2-diamine can act as a bidentate ligand. [1]
  9. November 2021, Paper 1, Q17(b)(i) (1 mark): What is meant by a bidentate ligand? [1]
  10. November 2020, Paper 3, Q2 (6 marks): 2* Transition metal ions can bond to ligands to form complex ions with different shapes. Explain what is meant by the terms ligand, coordination number and liga
  11. June 2019, Paper 1, Q18(a)(iii) (2 marks): Draw a 3-D diagram for the shape of the complex ion that forms in Experiment 2, Step 2. Include the charge of the ion. [2]
  12. June 2017, Paper 1, Q2 (1 mark): What is the bonding between the ligands and the metal ion in [Fe(H2O)6]2+? 2 A Metallic B Ionic C Hydrogen D Dative covalent Your answer [1]
  13. June 2017, Paper 3, Q4(c)(i) (1 mark): Draw the structure of the ligand in chromium(III) picolinate. [1]

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