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Periodicity: trends in ionisation energy and melting temperature: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 2.3.2 Periodicity: trends in ionisation energy and melting temperature, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. Q21(b)(ii)

    June 2025 · AS Unit 1

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  5. Q20(a)(i)

    October 2024 · AS Unit 1

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  6. Q20(c)(i)

    October 2024 · AS Unit 1

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  13. Q22(b)(ii)

    January 2022 · AS Unit 1

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  16. Q14(b)(i)

    October 2021 · AS Unit 1

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  18. Q22(a)(ii)

    June 2021 · AS Unit 1

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  19. Q22(a)(iii)

    June 2021 · AS Unit 1

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All 30 questions on Periodicity: trends in ionisation energy and melting temperature, as a list
  1. June 2025, AS Unit 1, Q21(b)(ii) (1 mark): State the general trend in first ionisation energies across Period 3. (1)
  2. June 2025, AS Unit 1, Q21(c)(i) (3 marks): Plot the following first ionisation energies of the elements in Period 2 on the grid below. (3) Element Li Be B C N O F Ne 1st ionisation energy / kJ mol–1 520
  3. October 2024, AS Unit 1, Q10(a) (1 mark): Which statement is not correct for these Period 3 elements? (1) A atoms of Cl(g) have the highest first ionisation energy B ions of Cl–(g) and S2–(g) have the s
  4. October 2024, AS Unit 1, Q10(b) (1 mark): The melting temperatures of these elements are shown in the table. Element Na Mg Al Si P S Cl Melting temperature / K 371 922 933 1683 317 392 172 Which of the
  5. October 2024, AS Unit 1, Q20(a)(i) (2 marks): Explain the general trend in first ionisation energies for the Period 2 elements. (2)
  6. October 2024, AS Unit 1, Q20(c)(i) (2 marks): The diagram shows the melting temperatures of the elements in Period 2 from lithium to nitrogen. Complete the diagram by putting crosses to show the approximate
  7. October 2024, AS Unit 1, Q20(c)(ii) (3 marks): Explain why the melting temperature of carbon is high, with reference to its structure and bonding. (3)
  8. June 2024, AS Unit 1, Q16(b)(i) (3 marks): Explain the trend in the first ionisation energies of Al, Si and P. (3)
  9. October 2023, AS Unit 1, Q18(a)(i) (2 marks): Explain the general trend in first ionisation energy across Period 2. (2)
  10. January 2023, AS Unit 1, Q9 (1 mark): Which is a reason why fluorine has a higher first ionisation energy than oxygen? A a fluorine atom has fewer unpaired electrons B a fluorine atom has fewer shel
  11. June 2022, AS Unit 1, Q1 (1 mark): Elements in their most stable state exist as A atoms in giant structures only B atoms in molecules and atoms in giant structures only C isolated atoms and atoms
  12. January 2022, AS Unit 1, Q22(a)(ii) (3 marks): Melting temperature depends on the strength of metallic bonding. Explain why the metallic bonding in magnesium is much stronger than that in sodium. (3)
  13. January 2022, AS Unit 1, Q22(b)(ii) (3 marks): Explain why the melting temperature of silicon is much higher than that of phosphorus, by referring to their structures. (3)
  14. January 2022, AS Unit 1, Q23(a)(ii) (2 marks): Explain why there is a general increase in the first ionisation energy across the period. (2)
  15. October 2021, AS Unit 1, Q8 (1 mark): In which series are the elements in order of increasing melting temperature? A I2 < Br2 < Cl2 < F2 B Li < Be < B < C C Li < Na < K < Rb D Si < P < S < Cl
  16. October 2021, AS Unit 1, Q14(b)(i) (2 marks): Explain the general increase in the first ionisation energy from sodium to argon. (2)
  17. June 2021, AS Unit 1, Q22(a)(i) (2 marks): Plot a graph of atomic radius against atomic number. (2)
  18. June 2021, AS Unit 1, Q22(a)(ii) (1 mark): Use the graph to estimate the atomic radius of silicon, Si. (1)
  19. June 2021, AS Unit 1, Q22(a)(iii) (3 marks): Suggest an explanation for the decrease in atomic radius as atomic number increases across a period. (3)
  20. June 2021, AS Unit 1, Q22(b) (6 marks): The melting temperatures of sodium, sodium chloride and chlorine are given in the table. Complete the table to show the type of structure, the type of bond or f
  21. January 2021, AS Unit 1, Q7 (1 mark): The Period 2 element with the highest melting temperature is A aluminium B boron C carbon D silicon
  22. October 2020, AS Unit 1, Q18(d)(i) (3 marks): The log of the fourth ionisation energy for six elements is shown in the table. log10 (fourth ionisation energy / kJ mol–1) Element O 3.87 F 3.92 Ne 3.97 Na Mg
  23. October 2020, AS Unit 1, Q18(d)(ii) (1 mark): Use your graph to estimate the fourth ionisation energy for sodium, in kJ mol–1. (1)
  24. January 2020, AS Unit 1, Q19(a)(i) (2 marks): The student incorrectly plotted two values: one for a metal and one for a non-metal. Identify these elements, by name or formula. (2)
  25. January 2020, AS Unit 1, Q19(a)(ii) (3 marks): Explain, with reference to structure and bonding, why silicon has a very high melting temperature. (3)
  26. June 2019, AS Unit 1, Q14 (1 mark): The bar chart shows the melting temperatures of the first twenty elements. 4000 3500 3000 2500 Melting 2000 temperature / K 1500 1000 500 0 1 2 3 4 5 6 7 8 9 10
  27. January 2019, AS Unit 1, Q6 (1 mark): The diagram shows the first ionisation energy for the elements from sodium to silicon. 1100 1000 900 First 800 ionisation 700 energy / kJ mol−1 600 500 400 3001
  28. January 2019, AS Unit 1, Q22(a)(i) (1 mark): Complete the table. (1)
  29. January 2019, AS Unit 1, Q22(a)(ii) (3 marks): Plot a graph of log (ionisation energy) against ionisation number. (3)
  30. January 2019, AS Unit 1, Q22(a)(iii) (1 mark): Give a reason why the logarithm of the ionisation energy, rather than just the ionisation energy, is used to plot this graph. (1)

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