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Ionisation energies as evidence for shells and sub-shells: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 2.2.2 Ionisation energies as evidence for shells and sub-shells, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. The start of question 21

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  2. The start of question 21

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  3. Q21(c)(ii)

    June 2025 · AS Unit 1

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  4. Q21(c)(iii)

    June 2025 · AS Unit 1

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  6. Q20(a)(ii)

    October 2024 · AS Unit 1

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  7. Q20(b)

    October 2024 · AS Unit 1

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  8. The start of question 16

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  9. Q16(b)(ii)

    June 2024 · AS Unit 1

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  10. Q1(a)

    January 2024 · AS Unit 1

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  11. Q1(b)

    January 2024 · AS Unit 1

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  12. Q1(c)

    January 2024 · AS Unit 1

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  13. Q1(d)

    January 2024 · AS Unit 1

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  15. The start of question 18

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  17. The start of question 11

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  18. Q11(b)

    October 2022 · AS Unit 1

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  19. Q11(c)

    October 2022 · AS Unit 1

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  20. Q14(a)(ii)

    October 2022 · AS Unit 1

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All 33 questions on Ionisation energies as evidence for shells and sub-shells, as a list
  1. June 2025, AS Unit 1, Q21(b)(i) (2 marks): The following data show the first seven ionisation energies for an element in Period 3. Deduce, with a reason, the identity of the element. (2) Ionisation numbe
  2. June 2025, AS Unit 1, Q21(c)(i) (3 marks): Plot the following first ionisation energies of the elements in Period 2 on the grid below. (3) Element Li Be B C N O F Ne 1st ionisation energy / kJ mol–1 520
  3. June 2025, AS Unit 1, Q21(c)(ii) (2 marks): Explain the difference in first ionisation energies between beryllium and boron. (2)
  4. June 2025, AS Unit 1, Q21(c)(iii) (2 marks): Explain the difference in first ionisation energies between carbon and nitrogen. (2)
  5. January 2025, AS Unit 1, Q9 (1 mark): The first four ionisation energies of the elements gallium (Ga), indium (In), germanium (Ge) and tin (Sn) are shown. Which values are the first four ionisation
  6. October 2024, AS Unit 1, Q20(a)(ii) (3 marks): Explain which one of the elements from lithium to nitrogen deviates from this general trend. (3)
  7. October 2024, AS Unit 1, Q20(b) (1 mark): Identify the Period 3 element that has the following successive ionisation energies. Ionisation energy / kJ mol–1 First Second Third Fourth Fifth Sixth Seventh
  8. June 2024, AS Unit 1, Q16(b)(i) (3 marks): Explain the trend in the first ionisation energies of Al, Si and P. (3)
  9. June 2024, AS Unit 1, Q16(b)(ii) (2 marks): Explain why sulfur does not follow this trend. (2)
  10. January 2024, AS Unit 1, Q1(a) (1 mark): Which element has atoms with a full outer shell of electrons? A element P B element Q C element R D element S
  11. January 2024, AS Unit 1, Q1(b) (1 mark): Which element could be X in a gaseous covalent compound with the formula HX? A element P B element Q C element R D element S
  12. January 2024, AS Unit 1, Q1(c) (1 mark): Which element could be Y in an ionic compound with the formula YF2? A element P B element Q C element R D element S
  13. January 2024, AS Unit 1, Q1(d) (1 mark): Which element has atoms with the largest atomic radius? A element P B element Q C element R D element S
  14. October 2023, AS Unit 1, Q6 (1 mark): The electronic configurations of the atoms of four elements are shown. What is the electronic configuration of the atom of element which has the lowest first io
  15. October 2023, AS Unit 1, Q18(a)(ii) (3 marks): Predict a value for the first ionisation energy of oxygen. Justify your answer. (3)
  16. October 2023, AS Unit 1, Q18(b)(ii) (2 marks): Explain the large difference between the first and second ionisation energies of lithium. (2)
  17. October 2022, AS Unit 1, Q11(a) (1 mark): Which element has only one p orbital containing a pair of electrons? (1) A element U B element V C element W D element X
  18. October 2022, AS Unit 1, Q11(b) (1 mark): Which element is the least reactive? (1) A element S B element X C element Y D element Z
  19. October 2022, AS Unit 1, Q11(c) (1 mark): Which element has the greatest second ionisation energy? (1) A element S B element T C element X D element Y
  20. October 2022, AS Unit 1, Q14(a)(ii) (1 mark): State how the graph confirms that barium is in Group 2 in the Periodic Table. (1)
  21. January 2022, AS Unit 1, Q23(a)(iii) (2 marks): Explain why the first ionisation energy of oxygen is lower than that of nitrogen. (2)
  22. January 2022, AS Unit 1, Q23(b) (2 marks): All the successive ionisation energies of nitrogen are shown in the table. Ionisation number 1 2 3 4 5 6 7 Ionisation energy 1402 2856 4578 7475 9445 53 267 64
  23. October 2021, AS Unit 1, Q14(a) (2 marks): The first four ionisation energies of aluminium are shown. Energy / kJ mol−1 Ionisation number 1 578 2 1820 3 2750 4 11 600 Explain how this information shows t
  24. October 2021, AS Unit 1, Q14(b)(ii) (2 marks): Explain why the first ionisation energy of aluminium is less than the first ionisation energy of magnesium. (2)
  25. June 2021, AS Unit 1, Q5 (1 mark): The graph shows log (ionisation energy) against ionisation number for the successive ionisations of an element. 6 5 4 log (ionisation 3 energy) 2 1 0 0 2 4 6 8
  26. January 2021, AS Unit 1, Q18(c) (3 marks): Explain why the first ionisation energy of sulfur is less than the first ionisation energies of both phosphorus and chlorine. (3) . .
  27. October 2020, AS Unit 1, Q18(c) (3 marks): Describe what can be deduced about the electronic structure of sodium from its successive ionisation energies. (3)
  28. October 2020, AS Unit 1, Q18(d)(iii) (1 mark): Suggest why the fourth ionisation energies of neon and sodium are similar in magnitude even though the elements are in different periods of the Periodic Table.
  29. January 2020, AS Unit 1, Q5 (1 mark): The first five ionisation energies of an element, in kJ mol–1, are 578 1 817 2 745 11 578 14 831 This element could be A sodium B magnesium C aluminium D silico
  30. January 2019, AS Unit 1, Q5 (1 mark): The first six ionisation energies of an element, in kJ mol−1, are shown. 578 1817 2745 11 578 14 831 18 378 Which group of the Periodic Table includes this elem
  31. January 2019, AS Unit 1, Q22(a)(i) (1 mark): Complete the table. (1)
  32. January 2019, AS Unit 1, Q22(a)(ii) (3 marks): Plot a graph of log (ionisation energy) against ionisation number. (3)
  33. January 2019, AS Unit 1, Q22(a)(iv) (3 marks): Explain what can be deduced from the graph about the electronic structure of nitrogen. (3)

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