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Ionisation energies, orbitals and the factors affecting them: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 2.2.1 Ionisation energies, orbitals and the factors affecting them, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. Q21(a)

    June 2025 · AS Unit 1

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  5. Q18(b)(i)

    October 2023 · AS Unit 1

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  9. Q14(a)(i)

    October 2022 · AS Unit 1

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  11. Q23(a)(i)

    January 2022 · AS Unit 1

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  17. Q21(b)(i)

    June 2021 · Unit 5

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  18. Q18(b)

    January 2021 · AS Unit 1

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All 27 questions on Ionisation energies, orbitals and the factors affecting them, as a list
  1. June 2025, AS Unit 1, Q21(a) (3 marks): Write the equation for the third ionisation energy of calcium. Include state symbols. (3)
  2. June 2024, AS Unit 1, Q10 (1 mark): Which equation represents the second ionisation energy of magnesium? A Mg(g) → Mg2+(g) + 2e– B Mg+(g) → Mg2+(g) + e– C Mg+(s) → Mg2+(s) + e– D Mg(g) → Mg+(g) +
  3. October 2023, AS Unit 1, Q18(a)(i) (2 marks): Explain the general trend in first ionisation energy across Period 2. (2)
  4. October 2023, AS Unit 1, Q18(a)(ii) (3 marks): Predict a value for the first ionisation energy of oxygen. Justify your answer. (3)
  5. October 2023, AS Unit 1, Q18(b)(i) (2 marks): Write the equation for the second ionisation energy of lithium. Include state symbols. (2)
  6. October 2023, AS Unit 1, Q18(b)(ii) (2 marks): Explain the large difference between the first and second ionisation energies of lithium. (2)
  7. January 2023, AS Unit 1, Q8 (1 mark): Which is the equation for the second ionisation of element J? A J(g) → J2+(g) + 2e– B J+(g) → J2+(g) + e– C J+(g) → J3+(g) + 2e– D J2+(g) → J3+(g) + e–
  8. January 2023, AS Unit 1, Q9 (1 mark): Which is a reason why fluorine has a higher first ionisation energy than oxygen? A a fluorine atom has fewer unpaired electrons B a fluorine atom has fewer shel
  9. October 2022, AS Unit 1, Q14(a)(i) (1 mark): Write an equation, including state symbols, for the third ionisation energy of barium. (1)
  10. June 2022, AS Unit 1, Q7 (1 mark): Which equation represents the first ionisation energy of iodine? A I2(s) → 2I+(g) + 2e− B I2(g) → 2I+(g) + 2e− C ½I2(s) → I+(g) + e− D I(g) → I+(g) + e− Use thi
  11. January 2022, AS Unit 1, Q23(a)(i) (1 mark): Give an equation that represents the first ionisation energy of lithium. Include state symbols. (1)
  12. January 2022, AS Unit 1, Q23(a)(ii) (2 marks): Explain why there is a general increase in the first ionisation energy across the period. (2)
  13. January 2022, AS Unit 1, Q23(a)(iii) (2 marks): Explain why the first ionisation energy of oxygen is lower than that of nitrogen. (2)
  14. October 2021, AS Unit 1, Q2 (1 mark): Which equation represents the second ionisation energy of chlorine? A Cl−(g) + e− → Cl2−(g) B Cl(g) + 2e− → Cl2−(g) C 2Cl(g) → 2Cl+(g) + 2e− D Cl+(g) → Cl2+(g)
  15. June 2021, AS Unit 1, Q4 (1 mark): Which equation represents the second ionisation energy of magnesium? A Mg(g) → Mg2+(g) + 2e− B Mg+(g) → Mg2+(g) + e− C Mg(s) → Mg2+(s) + 2e− D Mg+(s) → Mg2+(s)
  16. June 2021, AS Unit 2, Q8 (1 mark): Several factors may affect ionisation energies: I) the number of protons increases II) the outer electron is further from the nucleus III) the amount of shieldi
  17. June 2021, Unit 5, Q21(b)(i) (1 mark): Write the equation for the third ionisation energy of iron. Include state symbols. (1)
  18. January 2021, AS Unit 1, Q18(b) (2 marks): Write an equation for the first ionisation energy of sulfur. Include state symbols. (2)
  19. January 2021, AS Unit 1, Q18(c) (3 marks): Explain why the first ionisation energy of sulfur is less than the first ionisation energies of both phosphorus and chlorine. (3) . .
  20. October 2020, AS Unit 1, Q14 (1 mark): Which equation represents the third ionisation energy for element J? A J2+(g) → J3+(g) + e– B J3+(g) → J4+(g) + e– C J(g) → J3+(g) + e– D J(g) → J3+(g) + 3e–
  21. October 2020, AS Unit 1, Q18(d)(i) (3 marks): The log of the fourth ionisation energy for six elements is shown in the table. log10 (fourth ionisation energy / kJ mol–1) Element O 3.87 F 3.92 Ne 3.97 Na Mg
  22. October 2020, AS Unit 1, Q18(d)(ii) (1 mark): Use your graph to estimate the fourth ionisation energy for sodium, in kJ mol–1. (1)
  23. January 2020, AS Unit 1, Q18(b) (2 marks): Write an equation for the first ionisation energy of chlorine. Include state symbols. (2)
  24. January 2020, AS Unit 1, Q18(c) (3 marks): Explain the difference in the first ionisation energies of chlorine and bromine. (3)
  25. June 2019, AS Unit 1, Q9 (1 mark): Which sketch graph shows the trend in first ionisation energy values going down Group 1 in the Periodic Table? First ionisation A energy Atomic number First ion
  26. June 2019, AS Unit 1, Q13 (1 mark): Which is the equation for the second ionisation energy of an element, A? A A(g) o A2+(g) + 2e− B A+(g) o A2+(g) + e− C A2+(g) o A3+(g) + e− D A2+(g) o A4+(g) +
  27. January 2019, AS Unit 1, Q22(a)(v) (3 marks): Explain why the first ionisation energy of oxygen is lower than that of nitrogen. (3)

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