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Ligands and complex ions: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 17.1.2 Ligands and complex ions, 2019–2025, with mark schemes and examiner’s reports where available.

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  2. Q6

    June 2025 (A) · Unit 5

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  3. Q16(a)(ii)

    June 2025 (A) · Unit 5

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  4. Q1

    January 2025 · Unit 5

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  5. Q1(a)(ii)

    January 2025 · Unit 6

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  6. Q18(b)(ii)

    October 2024 · Unit 5

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  8. The start of question 17

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  9. Q17(b)(ii)

    January 2024 · Unit 5

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  10. The start of question 19

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  11. Q2(b)

    January 2023 · Unit 5

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  12. Q1(a)(i)

    October 2022 · Unit 6

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  13. Q1(a)

    January 2022 · Unit 5

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  14. Q1(a)

    January 2022 · Unit 6

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  15. Q18(b)

    October 2021 · Unit 5

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  16. Q20(b)(i)

    October 2021 · Unit 5

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  17. Q4

    June 2021 · Unit 5

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  18. Q7(b)

    January 2021 · Unit 5

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  19. Q19(b)(i)

    January 2021 · Unit 5

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  20. Q17

    October 2020 · Unit 5

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All 20 questions on Ligands and complex ions, as a list
  1. June 2025, Unit 5, Q6 (1 mark): Which is incorrect for H2O, OH − and NH3? A all can act as bidentate ligands B all can act as electron pair donors C all can form dative covalent bonds D all ca
  2. June 2025 (A), Unit 5, Q6 (1 mark): Excess aqueous silver nitrate is added to a solution containing 0.100 mol of chromium(III) chloride, CrCl3•6H2O. A precipitate, AgCl, appears immediately, which
  3. June 2025 (A), Unit 5, Q16(a)(ii) (2 marks): Describe the bonding between the manganese(II) ion and the ligands. (2)
  4. January 2025, Unit 5, Q1 (1 mark): Which species cannot act as a ligand in the formation of a complex ion? A C2H6 B CO C OH– D C4H9NH2
  5. January 2025, Unit 6, Q1(a)(ii) (1 mark): State the formula of the complex ion. (1)
  6. October 2024, Unit 5, Q18(b)(ii) (3 marks): 12.8 cm3 of 0.05 mol dm−3 iron(III) chloride solution reacted with 8.0 cm3 of 0.08 mol dm−3 ammonium thiocyanate to form a complex ion. Deduce the formula of th
  7. October 2024, Unit 5, Q18(d)(iii) (3 marks): Explain how the H N H bond angles would be expected to change in ethane-1,2-diamine when the complex ion is formed. (3)
  8. January 2024, Unit 5, Q17(a)(ii) (5 marks): You are provided with three equimolar solutions of the three isomers. Suggest how you would quantitatively determine the relative numbers of free chloride ions
  9. January 2024, Unit 5, Q17(b)(ii) (1 mark): Describe how guanine and adenine can bind to the platinum ion. (1)
  10. October 2023, Unit 5, Q19(c)(i) (2 marks): Explain how water acts as a monodentate ligand. (2)
  11. January 2023, Unit 5, Q2(b) (1 mark): What is the overall charge on this complex ion? (1) A 0 B +1 C +2 D +3 Use this space for any rough working. Anything you write in this space will gain no credi
  12. October 2022, Unit 6, Q1(a)(i) (1 mark): Note the A pink solution The formula of the complex (1) appearance ion formed is
  13. January 2022, Unit 5, Q1(a) (1 mark): The bonding within the complex [Cu(NH3)4(H2O)2]2+ is (1) A covalent, dative covalent and ionic B covalent and dative covalent only C covalent only D dative cova
  14. January 2022, Unit 6, Q1(a) (1 mark): Give the formula of a complex ion of chromium present in solution A. (1)
  15. October 2021, Unit 5, Q18(b) (1 mark): Give the formula of complex ion B. (1)
  16. October 2021, Unit 5, Q20(b)(i) (2 marks): THF acts as a monodentate ligand in complex Y. State the meaning of the terms monodentate and ligand. (2)
  17. June 2021, Unit 5, Q4 (1 mark): A ligand must be an A electron-pair donor B electron-pair donor and negatively charged C electron-pair acceptor D electron-pair acceptor and negatively charged
  18. January 2021, Unit 5, Q7(b) (1 mark): What is the bonding between the ligands and the central atom in these complexes? (1) A the bonding in both complexes is ionic B the bonding in both complexes is
  19. January 2021, Unit 5, Q19(b)(i) (1 mark): Name this type of chemical species. (1)
  20. October 2020, Unit 5, Q17 (1 mark): Which of the following species will not act as a ligand in the formation of a complex ion? A CH3NH2 B CN− C NH3 D NH4 +

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