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Transition metals: electron configurations and oxidation numbers: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 17.1.1 Transition metals: electron configurations and oxidation numbers, 2019–2025, with mark schemes and examiner’s reports where available.

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  5. Q21(a)(i)

    January 2025 · Unit 5

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  16. Q20(a)(i)

    January 2023 · Unit 5

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  17. Q20(a)(ii)

    January 2023 · Unit 5

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  20. Q19(a)

    October 2022 · Unit 5

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All 29 questions on Transition metals: electron configurations and oxidation numbers, as a list
  1. June 2025, Unit 5, Q4 (1 mark): 2+ ion? 4 What is the electronic configuration of a Zn 10 A [Ar] 3d 10 4s 2 B [Ar] 3d 9 4s 1 C [Ar] 3d 8 4s 2 D [Ar] 3d
  2. June 2025 (A), Unit 5, Q7(b) (1 mark): Which complex contains a metal in the +1 oxidation state? (1) A [CuCl2]– B [CrCl4]– C [Pt(NH3)2Cl2] D [Ni(CO)4]
  3. January 2025, Unit 5, Q3 (1 mark): The first five ionisation energies of four elements are shown. Which are the ionisation energies of a transition metal? A 419 3051 4412 5877 7975 B 578 1817 274
  4. January 2025, Unit 5, Q6 (1 mark): Which of these pairs of elements are both transition metals? A gold and scandium B gold and titanium C scandium and zinc D titanium and zinc
  5. January 2025, Unit 5, Q21(a)(i) (1 mark): The electronic configuration for Fe is shown. (1) Fe [Ar] 3d 4s Complete the electronic configuration for the Fe2+ ion in iron(II) sulfate. Fe2+ [Ar] 3d 4s
  6. January 2025, Unit 5, Q21(a)(ii) (3 marks): An aqueous solution of iron(II) sulfate is pale green in colour. When left exposed to the air the solution turns brown. Explain why this colour change occurs. I
  7. October 2024, Unit 5, Q1 (1 mark): What is the electronic configuration of the chromium atom? A [Ar] 3d4 4s2 B [Ar] 3d5 4s1 C [Ar] 3d6 D [Ar] 3d1 4s2 4p3
  8. January 2024, Unit 5, Q3 (1 mark): Which successive ionisation energies (in kJ mol–1) are most likely to be those of a transition element? A 578 1817 2745 11 578 14 831 B 759 1561 2958 5290 7236
  9. January 2024, Unit 5, Q5(a) (1 mark): What are the electronic structures of the three copper species? (1) Cu+ Cu2+ Cu [Ar] 3d9 4s2 [Ar] 3d9 4s1 [Ar] 3d9 A [Ar] 3d9 4s2 [Ar] 3d8 4s2 [Ar] 3d7 4s2 B [A
  10. January 2024, Unit 5, Q5(b) (1 mark): Which rows show the substances with their correct oxidation states? (1) Cu(0) Cu(I) Cu(II) A S U P B S R Q C T S P D T U Q
  11. October 2023, Unit 5, Q1 (1 mark): Which of these is a d-block element but is not a transition element? A cobalt B copper C nickel D zinc
  12. October 2023, Unit 5, Q2 (1 mark): In which of these pairs does the transition metal have the same oxidation number? A CrO2Cl2 and [Cr(NH3)4Cl2]+ B [Cu(NH3)2]+ and [CuCl4]2− C Mn2O3 and MnO2 D VO
  13. June 2023, Unit 5, Q6 (1 mark): Which electronic configuration is correct? A Ti2+ [Ar]4s2 B Cr [Ar]3d44s2 C Fe3+ [Ar]3d34s2 D Cu [Ar]3d104s1
  14. June 2023, Unit 5, Q21(a) (3 marks): Mercury forms compounds in either the +1 or +2 oxidation states. Explain why mercury is classified as a d-block element but is not a transition element. (3)
  15. January 2023, Unit 5, Q1 (1 mark): In which species does the transition metal have the lowest oxidation number? A [Cu(NH3)2]+ B [Fe(CN)6]3– C MnSO4 D Ni(CO)4
  16. January 2023, Unit 5, Q20(a)(i) (1 mark): Complete the electronic configurations for a manganese atom and a manganese(II) ion, using the electron-in-boxes notation. (1) Mn atom: [Ar] 3d 4s Mn2+ ion: [Ar
  17. January 2023, Unit 5, Q20(a)(ii) (3 marks): The standard electrode potentials, E , for the half-cells involving the oxidation states +3 and +2 for manganese and iron are shown. Mn3+(aq) + e–  Mn2+(aq) E
  18. October 2022, Unit 5, Q5 (1 mark): The element zinc is not classified as a transition metal. This is because A the 3d subshell of a zinc atom is full B zinc only forms one stable ion C the only s
  19. October 2022, Unit 5, Q6 (1 mark): What is the electronic configuration of the Fe2+ ion? A [Ar] ↑ ↑ ↑ ↑ ↑ ↑ B [Ar] ↑↓ ↑ ↑ ↑ ↑ C [Ar] ↑ ↑ ↑ ↑ ↑↓ D [Ar] ↑↓ ↑↓ ↑ ↑ 3d 4s
  20. October 2022, Unit 5, Q19(a) (3 marks): Explain the highest stable oxidation state formed by vanadium, by referring to its electronic configuration. (3)
  21. January 2022, Unit 5, Q9 (1 mark): The formulae of four ions are shown. Formula of ion 2− CrO4 AlO2 − [Fe(CN)6]4− [CrCl2(H2O)4]+ How many of these ions contain a metal with an oxidation number of
  22. October 2021, Unit 5, Q20(a) (1 mark): Titanium(III) chloride is used as a catalyst in the production of poly(propene). State the property of transition metals, such as titanium, that makes their com
  23. June 2021, Unit 5, Q3 (1 mark): What is the electronic configuration of a chromium atom? 3d 4s ↑ ↑ ↑ ↑ ↑ ↑ A (Ar) ↑ ↑ ↑ ↑ ⇅ B (Ar) ⇅ ⇅ ↑ ↑ C (Ar) ⇅ ↑ ↑ ⇅ D (Ar)
  24. June 2021, Unit 5, Q21(a) (2 marks): Explain, in terms of electronic structure, why iron(III) compounds are more stable than iron(II) compounds. (2)
  25. June 2021, Unit 5, Q21(b)(ii) (3 marks): Explain how stable iron(III) ions can be formed from iron(II) ions in aqueous solution. Refer to the relevant energy changes of these ions only. (3)
  26. January 2021, Unit 5, Q5 (1 mark): Which of these has the greatest number of unpaired electrons in each of its atoms? A chromium B iron C manganese D vanadium
  27. January 2021, Unit 5, Q6 (1 mark): Nickel is classified as a transition metal. This is because nickel A is a d block element B has partially filled d orbitals C forms stable ions with partially f
  28. October 2020, Unit 5, Q16 (1 mark): The electronic configuration of the atoms of an element is 1s22s22p63s23p63d54s1. What is the maximum oxidation number shown in compounds of this element? A +1
  29. October 2020, Unit 5, Q25(b)(i) (1 mark): The Lanthanides The lanthanides form a series in the Periodic Table comprising the elements from lanthanum, La (Z = 57) to lutetium, Lu (Z = 71). They have impo

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