Experimental methods for measuring rates: Edexcel International A Level Chemistry questions
Edexcel International A Level Chemistry past-paper questions on 11.1.2 Experimental methods for measuring rates, 2019–2025, with mark schemes and examiner’s reports where available.
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Calculations
- Your answer
Q18(a)(i)
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Q18(a)(ii)
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Q18(c)(ii)
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Q4(a)(i)
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Q1(a)
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Your answerQ3(a)(i)
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Q16(a)(i)
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Q16(a)(ii)
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Q16(b)(iii)
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Q16(b)(iv)
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Q1(a)
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Your answerQ1(b)
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Your answerQ15(c)(i)
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Q1(b)
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Your answerQ17(a)(i)
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Q2(a)(i)
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Q2(a)(ii)
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- Your answer
Q4(a)
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All 37 questions on Experimental methods for measuring rates, as a list
- June 2025, Unit 4, Q9 (1 mark): In an experiment to determine the rate of reaction between bromine and methanoic acid, which method would not be suitable? Br2(aq) + HCOOH(aq) → 2H+(aq) + 2Br−(
- June 2025, Unit 4, Q18(a)(i) (1 mark): The reaction in the sample stops immediately on removal from the reaction mixture. Suggest why this occurs. (1)
- June 2025, Unit 4, Q18(a)(ii) (1 mark): State why it is not necessary to calculate the concentration of hydrogen peroxide solution when trying to deduce the order of reaction with respect to hydrogen
- January 2025, Unit 4, Q18(c)(ii) (2 marks): The temperature of the reaction was changed to 75°C. Draw a line on the graph to show the possible results if this was the only change. Justify any similarities
- January 2025, Unit 6, Q4(a)(i) (1 mark): Give the name of the most suitable technique to monitor the concentration of In2– during the reaction. (1)
- June 2024, Unit 4, Q1(a) (1 mark): Which continuous monitoring method could be used to obtain kinetics data for this reaction? (1) A colorimetry B mass change C titration with sodium thiosulfate
- June 2024, Unit 6, Q3(a)(i) (2 marks): Explain why Step 3 effectively stops the reaction between potassium manganate(VII) and ethanedioate ions. (2)
- January 2024, Unit 4, Q16(a)(i) (1 mark): State the final colour of the mixture containing the starch‑iodine complex. (1)
- January 2024, Unit 4, Q16(a)(ii) (2 marks): Under appropriate conditions, the reciprocal of time can be used as an approximate measure of the initial rate of the reaction. Explain why the concentration of
- January 2024, Unit 4, Q16(b)(iii) (1 mark): All four mixtures contained 8.50 × 10–5 mol of sodium thiosulfate. Calculate the amount of iodine that had reacted with the sodium thiosulfate when the colour c
- January 2024, Unit 4, Q16(b)(iv) (2 marks): Calculate the rate of reaction, in mol dm–3 s–1, with respect to hydrogen peroxide using the answer from (b)(iii), the stoichiometry of Reaction 1 and data from
- October 2023, Unit 4, Q1(a) (1 mark): (CH3)2C (1) A colorimetry B measurement of change in volume C measurement of change in mass D quenching with ice‑cold water followed by titrating with acid
- October 2023, Unit 4, Q1(b) (1 mark): HCOOCH3(aq) + NaOH(aq) → HCOONa(aq) + CH3OH(aq) (1) A colorimetry B measurement of change in volume C measurement of change in mass D quenching with ice‑cold wa
- October 2023, Unit 4, Q15(c)(i) (1 mark): Give the reason why colorimetry can be used to monitor the rate of the reaction. (1)
- January 2023, Unit 4, Q1(b) (1 mark): Which two methods can be used for continuous monitoring of the progress of this reaction? (1) A colorimetry and titration B colorimetry and volume change C mass
- January 2023, Unit 4, Q17(a)(i) (3 marks): The rate of this reaction may be obtained by adding a fixed volume of sodium thiosulfate solution and a few drops of starch solution to the reaction mixture. Ex
- January 2023, Unit 6, Q2(a)(i) (1 mark): Give the expected colour change at the end‑point. (1)
- January 2023, Unit 6, Q2(a)(ii) (2 marks): Explain the effect on the volume of hydrochloric acid required if the titration was not carried out immediately after Step 4. (2)
- October 2022, Unit 4, Q1 (1 mark): Which continuous monitoring method could be used to obtain rate data for the reaction shown? C4H9Cl(l) + H2O(l) → C4H9OH(aq) + H+(aq) + Cl−(aq) A electrical con
- October 2022, Unit 6, Q4(a) (1 mark): Name the apparatus which is most suitable to remove the samples from the reaction mixture. (1)
- October 2022, Unit 6, Q4(b)(i) (1 mark): Give a reason why Vfinal – Vt is plotted on the y‑axis of the graph, rather than the concentration of sodium hydroxide solution for each titre. (1)
- October 2022, Unit 6, Q4(c) (2 marks): The student suggested placing ice in the conical flask before carrying out each titration. Explain whether or not this suggestion would improve the validity of
- June 2022, Unit 4, Q11(a) (1 mark): Which method would be most suitable for following this reaction? (1) A colorimetry B timing how long the solution takes to go cloudy C quenching and titrating w
- January 2022, Unit 6, Q3(a) (1 mark): Give one reason why the contents of beaker P are poured back into beaker Q in Step 3. (1)
- January 2022, Unit 6, Q3(b)(i) (2 marks): Explain why phenol is added to the reaction mixture. (2)
- January 2022, Unit 6, Q3(b)(ii) (1 mark): Give the colour of the reaction mixture before it turns colourless. (1)
- January 2022, Unit 6, Q3(b)(iii) (1 mark): Give the reason why the temperature is measured in Step 4. (1)
- January 2022, Unit 6, Q3(c)(i) (1 mark): Complete the table by calculating the remaining values of 1/t. (1)
- January 2022, Unit 6, Q3(c)(iii) (1 mark): State why the volume of KBr is proportional to the concentration of bromide ions in the reaction mixture. (1)
- October 2020, Unit 4, Q1 (1 mark): Bromine oxidises methanoic acid to carbon dioxide. The equation for the reaction is HCOOH(aq) + Br2(aq) → 2H+(aq) + 2Br −(aq) + CO2(g) Which of the following me
- October 2020, Unit 6, Q3(b) (2 marks): Explain the purpose of the phenol in this experiment. (2)
- October 2020, Unit 6, Q3(c) (1 mark): Suggest a way of making the disappearance of the methyl red colour easier to see. (1)
- October 2020, Unit 6, Q3(d)(i) (1 mark): State why the total volume of the mixture is kept constant. (1)
- October 2020, Unit 6, Q3(d)(iv) (1 mark): Reciprocal time (1/t) is used as a measure of rate in this experiment. Suggest the assumption on which this depends. Refer in your answer to the shape of a typi
- October 2020, Unit 6, Q3(d)(v) (2 marks): Another student accidentally measured 8.5 cm3 of potassium bromate(V) rather than 8.0 cm3 in Run 4. Explain whether or not this portion of potassium bromate(V)
- October 2020, Unit 6, Q3(e)(i) (1 mark): Give a reason why the potassium bromate(V) solution is first measured into a separate boiling tube rather than directly into the reaction mixture. (1)
- October 2020, Unit 6, Q3(f) (2 marks): State the changes that you would make to the procedure to obtain the data needed to determine the overall rate equation for the reaction between bromide and bro
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