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Calculating enthalpy changes from experiments: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 6.1.3 Calculating enthalpy changes from experiments, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. Q1(a)

    June 2025 · AS Unit 2

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  2. Q5(b)

    June 2025 · AS Unit 3

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  3. Q19(b)

    June 2025 · Unit 4

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  4. Q16(b)(i)

    October 2024 · AS Unit 2

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  5. The start of question 2

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  6. The start of question 2

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  7. Q2(a)(iii)

    October 2024 · AS Unit 3

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  8. Q20(b)

    October 2024 · Unit 4

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  9. The start of question 17

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  10. Q17(c)

    June 2024 · AS Unit 2

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  11. Q4(b)

    June 2024 · AS Unit 3

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  13. Q4(d)(ii)

    June 2024 · AS Unit 3

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  15. Q6(a)

    June 2024 (R) · AS Unit 2

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  16. Q22(b)

    January 2024 · AS Unit 2

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  17. Q4(c)(i)

    January 2024 · AS Unit 3

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  18. Q4(c)(ii)

    January 2024 · AS Unit 3

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  19. Q4(c)(iii)

    January 2024 · AS Unit 3

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  20. Q19(a)(i)

    October 2023 · AS Unit 1

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All 60 questions on Calculating enthalpy changes from experiments, as a list
  1. June 2025, AS Unit 2, Q1(a) (1 mark): What is the expression for the enthalpy change of neutralisation of sodium hydroxide and ethanoic acid, in J mol–1? [Assume: the specific heat capacity of the m
  2. June 2025, AS Unit 3, Q5(b) (4 marks): The student carried out the reaction. The starting temperature recorded was 19.4°C. The maximum temperature recorded was 55.2°C. Calculate the value for the ent
  3. June 2025, Unit 4, Q19(b) (4 marks): Hydrated copper(II) sulfate is soluble in water. A student carried out an experiment to determine its enthalpy change of solution. 100 g of distilled water was
  4. October 2024, AS Unit 2, Q16(b)(i) (4 marks): In the first experiment, the student determined the enthalpy change when dissolving anhydrous magnesium sulfate. MgSO4(s) + (aq) → MgSO4(aq) 100.0 g of distille
  5. October 2024, AS Unit 3, Q2(a)(i) (3 marks): Draw two lines of best-fit to determine the maximum temperature change at the point of neutralisation. (3) Volume of hydrochloric acid at neutralisation cm3 Max
  6. October 2024, AS Unit 3, Q2(a)(ii) (2 marks): Calculate the concentration of the sodium hydroxide solution, using an answer from (a)(i) and information from the procedure. (2)
  7. October 2024, AS Unit 3, Q2(a)(iii) (4 marks): Calculate the enthalpy change of neutralisation, in kJ mol−1. (4) Assume the value of the specific heat capacity of the solution is 4.18 J g−1 °C−1 and the dens
  8. October 2024, Unit 4, Q20(b) (3 marks): Magnesium chloride, MgCl2(s), is used in the manufacture of tofu from soya milk. An experiment was carried out to determine the enthalpy change of solution, Δso
  9. June 2024, AS Unit 2, Q17(a) (3 marks): Find the end‑point volume and the maximum temperature by adding appropriate lines of best fit to the graph. (3) End‑point volume = Maximum temperature =
  10. June 2024, AS Unit 2, Q17(c) (5 marks): The reaction that occurs is shown. CH3COOH(aq) + NH3(aq) → CH3COONH4(aq) Calculate the enthalpy change of neutralisation for this reaction, in kJ mol‒1. Give yo
  11. June 2024, AS Unit 3, Q4(b) (1 mark): State the purpose of measuring the temperature every 30 seconds for 2½ minutes in Step 2. (1)
  12. June 2024, AS Unit 3, Q4(d)(i) (2 marks): Determine the maximum temperature change, ∆T , for this reaction, using the graph. You must show your working on the graph. (2)
  13. June 2024, AS Unit 3, Q4(d)(ii) (2 marks): Explain why the temperature decreases over time after 5 minutes. (2)
  14. June 2024, AS Unit 3, Q4(e)(ii) (1 mark): State why the number of moles of sodium hydroxide and not the number of moles of sulfuric acid is used in the calculation for this experiment. (1)
  15. June 2024 (R), AS Unit 2, Q6(a) (1 mark): Which is the correct expression to calculate the enthalpy change of neutralisation for this reaction, in J mol–1 ? (1) A Δ T 4.2 50 3 5.0 10 B Δ T 4.2 25 3 2.5
  16. January 2024, AS Unit 2, Q22(b) (4 marks): The student carried out an experiment to determine the enthalpy change of reaction, ΔrH2 , in kJ mol–1, for Reaction 2. Reaction 2 MgO(s) + 2HCl(aq) → MgCl2(aq)
  17. January 2024, AS Unit 3, Q4(c)(i) (1 mark): Calculate the energy transferred to the water. (1)
  18. January 2024, AS Unit 3, Q4(c)(ii) (1 mark): Calculate the amount of ethanol burnt in moles. (1)
  19. January 2024, AS Unit 3, Q4(c)(iii) (1 mark): Calculate the enthalpy change of combustion of ethanol in kJ mol–1, using your answers to (c)(i) and (c)(ii). Give your answer to an appropriate number of signi
  20. October 2023, AS Unit 1, Q19(a)(i) (2 marks): Calculate the mean energy density of this E10 fuel in MJ kg–1. Give your answer to an appropriate number of significant figures. (2)
  21. October 2023, AS Unit 1, Q19(a)(iii) (1 mark): Calculate the energy released when 1500 cm3 of the E10 fuel is burned in excess oxygen, using your answers from (a)(i) and (a)(ii). [If you did not calculate a
  22. October 2023, AS Unit 2, Q18(b)(i) (2 marks): Use the graph shown to determine the maximum temperature change, ΔT, in this experiment. You must show your working on the graph. (2) ΔT 28 26 Temperature / °C
  23. October 2023, AS Unit 2, Q18(b)(ii) (3 marks): Calculate the enthalpy change of neutralisation using your answers to (a) and (b)(i). Give a sign and units with your answer. Assume: no energy is used to heat
  24. June 2023, AS Unit 2, Q20(a)(iii) (2 marks): When petrol is used to power a car, the energy available is less than the theoretical maximum. When one kilogram of petrol powers a car, the energy used to move
  25. January 2023, AS Unit 2, Q1(b) (1 mark): The student repeats the experiment but burns 0.30 g of methanol and uses 75.0 cm3 of water in the copper calorimeter. What is the expected temperature change in
  26. January 2023, AS Unit 3, Q2(b)(i) (1 mark): The student’s results are shown. Quantity Value Final water temperature / °C 29.1 Initial water temperature / °C 21.8 Temperature change / °C Mass of burner + e
  27. January 2023, AS Unit 3, Q2(b)(ii) (3 marks): Calculate the enthalpy change of combustion of ethanol in kJ mol–1, using the student’s results. Give your answer to an appropriate number of significant figure
  28. October 2022, AS Unit 2, Q20(a) (4 marks): In the first experiment, the student determines the enthalpy change when hydrated copper(II) sulfate dissolves in water. CuSO4·5H2O(s) + aq → CuSO4(aq) 10.68 g
  29. June 2022, AS Unit 2, Q18(a)(iv) (3 marks): Calculate the heat energy released during the complete combustion of 1 dm3 of 2,2,4-trimethylpentane. [Density of 2,2,4-trimethylpentane = 0.692 g cm−3] (3)
  30. June 2022, AS Unit 2, Q18(b)(i) (4 marks): Calculate the enthalpy change of combustion of ethanol. Give your answer to an appropriate number of significant figures, and include a sign and units. [Specifi
  31. June 2022, AS Unit 3, Q1(b)(ii) (1 mark): Calculate the energy transferred in the reaction, in joules. Assume that the specific heat capacity of the solution is 4.2 J g–1°C–1. (1)
  32. June 2022, AS Unit 3, Q1(b)(iii) (1 mark): State a second assumption, other than the specific heat capacity of the solution, that you have made in your calculation in (b)(ii). (1)
  33. June 2022, AS Unit 3, Q1(b)(iv) (2 marks): Calculate the enthalpy change of the reaction, using your answers to (b)(i) and (b)(ii). (2)
  34. January 2022, AS Unit 2, Q3 (1 mark): 5.20 g of sodium hydrogencarbonate is added to an excess of acid. The temperature increases and the energy change is calculated to be 1030 J. What is the enthal
  35. January 2022, AS Unit 2, Q21(a)(i) (1 mark): Complete the table. (1)
  36. January 2022, AS Unit 2, Q21(a)(ii) (4 marks): Calculate the enthalpy change of combustion, ΔcH, of 2‑methylpropan‑2‑ol. Give a sign and units in your answer. [Specific heat capacity of water = 4.18 J g−1 °C
  37. January 2022, AS Unit 3, Q1(b)(i) (2 marks): Give two reasons why the student stirred the solution in Steps 3 and 4. (2)
  38. October 2021, AS Unit 2, Q19(a)(i) (1 mark): Calculate the number of moles of ethanol in 1.19 g. [ Molar mass of ethanol = 46.0 g mol−1 ] (1)
  39. October 2021, AS Unit 2, Q19(a)(ii) (2 marks): Calculate the heat energy required to raise the temperature of 100 g of water from 21.6 °C to 63.9 °C. [Specific heat capacity of water = 4.18 J g−1°C−1 ] (2)
  40. October 2021, AS Unit 2, Q19(a)(iii) (3 marks): Use your answers to (a) (i) and (ii) to calculate a value for the enthalpy change of combustion of ethanol. Give your answer to an appropriate number of signifi
  41. October 2021, Unit 6, Q3(b) (3 marks): The temperature rise was 12.5 °C. Calculate the enthalpy change for the formation of this solution of lithium chloride. Include a sign and units in your answer.
  42. June 2021, AS Unit 2, Q19(b) (3 marks): A student carried out an experiment to determine the enthalpy change of the reaction. A sample of 0.50 g of magnesium powder was added to 25 cm3 of 0.20 mol dm−
  43. June 2021, AS Unit 2, Q19(d) (4 marks): Calculate the standard molar enthalpy change for the reaction, using your answers to (b) and (c)(ii). Include a sign and units in your answer. [Specific heat ca
  44. January 2021, AS Unit 2, Q11 (1 mark): The table shows the amount of energy released per gram when some alkanes are burned in excess oxygen under standard conditions. Energy released Alkane / kJ g−1
  45. January 2021, AS Unit 2, Q21(b) (5 marks): Sodium ethanoate is a component of reusable hand warmers. In use, a supersaturated solution of sodium ethanoate recrystallises to form solid hydrated sodium eth
  46. January 2021, AS Unit 3, Q3(c)(i) (2 marks): Calculate the enthalpy change, ΔH1 , for the reaction between MCO3 and hydrochloric acid in kJ mol−1. Include a sign with your answer. (2)
  47. October 2020, AS Unit 2, Q15(b)(i) (3 marks): Student A used a calorimetric method, reacting a 50.0 cm3 sample of the solution with excess powdered zinc. AgNO3(aq) + ½Zn(s) → ½Zn(NO3)2(aq) + Ag(s) ΔrH = –36
  48. October 2020, AS Unit 3, Q4(a)(i) (1 mark): Give a reason why an excess of sodium hydroxide was used. (1)
  49. October 2020, AS Unit 3, Q4(a)(ii) (1 mark): The diagram shows part of the thermometer when the temperature had reached its maximum. 30 20 Record the temperature in the table of results and then complete t
  50. October 2020, AS Unit 3, Q4(b) (4 marks): Calculate the enthalpy change of neutralisation of hydrochloric acid. Include a sign and units in your answer. [Assume: the density of both solutions and the mi
  51. January 2020, AS Unit 2, Q2 (1 mark): When 50 cm3 of hydrochloric acid of concentration 2.0 mol dm−3 is added to 50 cm3 of sodium hydroxide solution of concentration 2.0 mol dm−3, the temperature in
  52. January 2020, AS Unit 2, Q15(a)(i) (2 marks): State why different volumes of water are used in the two experiments. Justify your answer. (2)
  53. January 2020, AS Unit 2, Q15(a)(ii) (3 marks): Calculate the enthalpy change of solution, ǻsolnH, in kJ mol−1, for the anhydrous salt, CuSO4 . ⎡ Assume: heat capacity of the solution = 4.2 J g−1 °C−1 ⎣⎢ dens
  54. January 2020, AS Unit 3, Q2(a)(i) (2 marks): Calculate the number of moles of magnesium in the 10 cm length of ribbon used in this experiment. [Ar value: Mg = 24.3] (2)
  55. January 2020, AS Unit 3, Q2(a)(ii) (4 marks): Calculate the enthalpy change for this reaction including a sign and units. Give your answer to an appropriate number of significant figures. Data: Specific hea
  56. June 2019, AS Unit 2, Q12 (1 mark): In an experiment, 50.0 cm3 of 1.0 mol dm−3 HCl(aq) reacts with 50.0 cm3 of 1.0 mol dm−3 NaOH(aq). The energy released = 2500 J. The specific heat capacity of th
  57. June 2019, AS Unit 3, Q3(a)(i) (1 mark): Give a reason, other than preventing heat loss, for placing the polystyrene cup in a glass beaker. (1)
  58. June 2019, AS Unit 3, Q3(b)(i) (3 marks): Plot a labelled graph of mass of metal on the horizontal axis against temperature change on the vertical axis. (3)
  59. June 2019, AS Unit 3, Q3(b)(ii) (2 marks): Determine the mass of metal M that reacts exactly with 50.0 cm3 of 1.35 mol dm−3 copper(II) sulfate by drawing appropriate best-fit straight lines. You must sho
  60. June 2019, AS Unit 3, Q3(b)(iii) (3 marks): The equation for the reaction of M with copper(II) sulfate is M(s) + CuSO4(aq) → MSO4(aq) + Cu(s) Use the equation and your answer to (b)(ii) to calculate the r

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