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Oxidation states of vanadium: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 17.2.1 Oxidation states of vanadium, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. Q5

    June 2025 · Unit 5

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  2. Q4

    January 2025 · Unit 5

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  3. Q1

    June 2024 · Unit 5

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  4. The start of question 3

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  5. Q3(a)(ii)

    January 2024 · Unit 6

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  6. Q3(a)(iv)

    January 2024 · Unit 6

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  7. Q18(a)

    January 2023 · Unit 5

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  8. Q18(b)

    January 2023 · Unit 5

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  10. The start of question 19

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  11. The start of question 19

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  12. Q19(c)(ii)

    October 2022 · Unit 5

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  13. Q3

    June 2022 · Unit 5

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  14. Q1(a)(i)

    June 2021 · Unit 6

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  15. Q1(a)(ii)

    June 2021 · Unit 6

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  16. Q1(a)(iii)

    June 2021 · Unit 6

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  17. Q1(a)(iv)

    June 2021 · Unit 6

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  18. Q24(b)(i)

    October 2020 · Unit 5

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  19. Q24(b)(ii)

    October 2020 · Unit 5

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All 20 questions on Oxidation states of vanadium, as a list
  1. June 2025, Unit 5, Q5 (1 mark): 2+ ions? 5 What is the colour of an aqueous solution of V A blue B green C purple D yellow Use this space for any rough working. Anything you write in this spac
  2. January 2025, Unit 5, Q4 (1 mark): What is the colour of the VO2+ ion in aqueous solution? A blue B green C violet D yellow
  3. June 2024, Unit 5, Q1 (1 mark): What colour is vanadium(III) in aqueous solution? A blue B green C purple D yellow
  4. January 2024, Unit 6, Q3(a)(i) (1 mark): Suggest why only an approximate volume of sulfuric acid was used. (1)
  5. January 2024, Unit 6, Q3(a)(ii) (1 mark): The cotton wool helps to prevent the reoxidation of the vanadium and to allow the escape of hydrogen gas. State why hydrogen gas was produced. You may include a
  6. January 2024, Unit 6, Q3(a)(iv) (3 marks): The student concluded that zinc had reduced the vanadium(V) to the vanadium(II) oxidation state. Explain the sequence of colours that the student would have see
  7. January 2023, Unit 5, Q18(a) (1 mark): State the oxidation number of vanadium in Na3VO4 . (1)
  8. January 2023, Unit 5, Q18(b) (3 marks): In aqueous solution, vanadium(II) exists as [V(H2O)6]2+ but vanadium(V) exists as [VO2(H2O)4]+. Explain why vanadium(V) does not exist as [V(H2O)6]5+. (3)
  9. January 2023, Unit 5, Q18(e) (6 marks): Vanadium(V) ions, VO2 oxidation states. Compare and contrast the use of iron and tin in this reduction process. Include equations and Ecell values for any react
  10. October 2022, Unit 5, Q19(b)(i) (4 marks): Justify the use of sodium thiosulfate for this reaction by writing the relevant equations and calculating their Ecell values. Use the standard electrode potenti
  11. October 2022, Unit 5, Q19(b)(ii) (2 marks): Explain why nickel, Ni, is not a suitable reagent to convert VO2+ into V3+, with no other vanadium species being formed. (2)
  12. October 2022, Unit 5, Q19(c)(ii) (2 marks): Suggest why the VO2+ ions formed do not affect the titration. (2)
  13. June 2022, Unit 5, Q3 (1 mark): Excess aqueous sodium thiosulfate is added to an aqueous solution of ammonium vanadate(V). What colour is the mixture when the reaction is complete? Refer to pa
  14. June 2021, Unit 6, Q1(a)(i) (1 mark): When excess dilute sulfuric acid is added to an aqueous solution of NH4VO3 , − ion is converted into the VO2 + ion. the VO3 Write the ionic equation for the con
  15. June 2021, Unit 6, Q1(a)(ii) (1 mark): State the colour of an acidified solution of ammonium vanadate(V). (1)
  16. June 2021, Unit 6, Q1(a)(iii) (2 marks): A student added zinc metal to an acidified solution of ammonium vanadate(V). The zinc reduced the vanadium in a series of reactions. The student suggested that
  17. June 2021, Unit 6, Q1(a)(iv) (2 marks): When the mixture obtained at the end of the sequence in (a)(iii) is filtered, the filtrate changes colour from violet to green on standing. No further changes
  18. October 2020, Unit 5, Q24(b)(i) (2 marks): Complete the table to show the colours of the ions that each of these oxidation states has in aqueous solution. (2) Colour of the ions in Oxidation state of van
  19. October 2020, Unit 5, Q24(b)(ii) (1 mark): Two vanadium species exist in equilibrium in an aqueous solution. −(aq) + H2O(l) ⇌ VO2 VO3 +(aq) + 2OH−(aq) Deduce whether or not this is a redox reaction. Just
  20. October 2020, Unit 5, Q24(b)(iii) (5 marks): Predict the oxidising agent that could convert vanadium(II) ions to vanadium(III) ions and then vanadium(IV) ions, but not to vanadium(V) ions, under standard c

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