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Redox titrations and calculations: OCR A‑Level Chemistry A questions

OCR A-Level Chemistry A past-paper questions on 5.2.3.2 Redox titrations and calculations, 2016–2025, with mark schemes and examiner’s reports where available.

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  1. Q21(d)(i)

    June 2025 · Paper 1

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  2. Q21(d)(ii)

    June 2025 · Paper 1

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  3. Q21(b)

    June 2024 · Paper 1

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  5. Q3(b)(ii)

    June 2024 · Paper 3

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  6. Q3(b)(iii)

    June 2024 · Paper 3

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  7. Q3(b)(iv)

    June 2024 · Paper 3

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  8. Q21(a)(i)

    June 2023 · Paper 1

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  9. Q21(a)(ii)

    June 2023 · Paper 1

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  10. Q21(a)(iii)

    June 2023 · Paper 1

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  11. Q21(b)

    June 2023 · Paper 1

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  12. Q4

    June 2022 · Paper 1

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  13. Q6(d)

    June 2022 · Paper 3

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  14. Q18(c)

    November 2021 · Paper 1

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  15. Q18(d)

    November 2021 · Paper 1

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  16. Q18(e)(i)

    November 2021 · Paper 1

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  17. Q18(e)(ii)

    November 2021 · Paper 1

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  18. Q18(f)

    November 2021 · Paper 1

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  19. Q22(c)

    November 2020 · Paper 1

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  20. Q18(c)(i)

    June 2019 · Paper 1

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All 27 questions on Redox titrations and calculations, as a list
  1. June 2025, Paper 1, Q21(d)(i) (5 marks): Calculate the percentage by mass of CuSO4•5H2O in Mixture A. Give your answer to 3 significant figures. Percentage of CuSO4•5H2O in Mixture A = % [5]
  2. June 2025, Paper 1, Q21(d)(ii) (1 mark): The student repeats their method, but after carrying out Step 1 they leave the solution exposed to the air for a few days. Some of the iron(II) sulfate is oxidi
  3. June 2024, Paper 1, Q21(b) (4 marks): Potassium iodate tablets prevent the uptake of radioactive iodine in the human body following a nuclear accident. The mass of potassium iodate(V), KIO3, in a ta
  4. June 2024, Paper 3, Q3(b)(i) (2 marks): In the titration, both iron(II) ions and ethanedioate, C2O4 Construct half-equations for the oxidation of iron(II) and ethanedioate ions. Oxidation of iron(II)
  5. June 2024, Paper 3, Q3(b)(ii) (3 marks): The student prepares a 250.0 cm3 solution of iron(II) ethanedioate by dissolving 1.295 g of FeC2O4•xH2O, in dilute sulfuric acid. The student titrates 25.0 cm3
  6. June 2024, Paper 3, Q3(b)(iii) (1 mark): The uncertainty in each burette reading is ±0.05 cm3. Calculate the percentage uncertainty for the titre in Titration 1. percentage uncertainty = % [1]
  7. June 2024, Paper 3, Q3(b)(iv) (6 marks): This question is about compounds and ions of iron(II) and iron(III) that contain ethanedioate ions, 2–. C2O4 (iv)* In the titration, 5 mol of iron(II) ethanedio
  8. June 2023, Paper 1, Q21(a)(i) (1 mark): State the colour change seen at the end point of the titration. from to [1]
  9. June 2023, Paper 1, Q21(a)(ii) (2 marks): The student’s titration results are shown in the table below. The trial titre has been omitted. 1 2 3 Final volume / cm3 12.65 25.60 38.35 Initial volume / cm3
  10. June 2023, Paper 1, Q21(a)(iii) (3 marks): Determine the concentration, in mol dm–3, of iron(II) ions in the river water. concentration = mol dm–3 [3]
  11. June 2023, Paper 1, Q21(b) (4 marks): The student modifies the experiment in (a) to determine the combined concentration of iron(II) and iron(III) ions in the river water. The student’s method is sh
  12. June 2022, Paper 1, Q4 (1 mark): Hydrogen peroxide, H2O2, can be oxidised by manganate(VII) ions under acid conditions as shown below. –(aq) + 5H2O2(aq) + 6H+(aq) 2Mn2+(aq) + 5O2(g) + 8H2O(l) 2
  13. June 2022, Paper 3, Q6(d) (4 marks): The label on a carton of orange juice lists the mass of vitamin C, in mg, in a typical serving of 150 cm3. The student carries out an investigation to check the
  14. November 2021, Paper 1, Q18(c) (1 mark): Suggest a suitable indicator for this titration and state the colour change at the end point in Step 4. Indicator: Colour from to [1]
  15. November 2021, Paper 1, Q18(d) (4 marks): Determine the percentage, by mass, of copper in the copper ore. Give your answer to an appropriate number of significant figures. percentage = % [4]
  16. November 2021, Paper 1, Q18(e)(i) (1 mark): The potassium iodide was not in excess, in Step 3. [1]
  17. November 2021, Paper 1, Q18(e)(ii) (1 mark): The burette readings were read from the top of the meniscus, in Step 4. [1]
  18. November 2021, Paper 1, Q18(f) (2 marks): The student then modifies the method in order to obtain a more accurate value for the percentage by mass of copper in the ore. The student decides to use 25.00
  19. November 2020, Paper 1, Q22(c) (5 marks): Sodium sulfite(IV), Na2SO3, is used as a preservative in some foods. Food safety legislation allows a maximum of 850 mg Na2SO3 per kg of burger meat. A chemist
  20. June 2019, Paper 1, Q18(c)(i) (1 mark): Explain why the student used 0.00200 mol dm−3 potassium manganate(VII) solution for this titration, rather than the more usual concentration of 0.0200 mol dm−3
  21. June 2019, Paper 1, Q18(c)(ii) (5 marks): Use the student’s results to determine the mass, in mg, of iron(II) gluconate in one tablet. Give your answer to 3 significant figures. mass of iron(II) glucona
  22. June 2018, Paper 1, Q20(d)(i) (2 marks): Complete Table 20.1 and calculate the mean titre that the student should use for analysing the results. mean titre = cm3 [2]
  23. June 2018, Paper 1, Q20(d)(ii) (1 mark): The uncertainty in each burette reading is ±0.05 cm3. Calculate the percentage uncertainty in the titre obtained from titration 1. Give your answer to two decim
  24. June 2018, Paper 1, Q20(d)(iii) (2 marks): Describe and explain how the student should determine the end point of this titration accurately. [2]
  25. June 2018, Paper 1, Q20(d)(iv) (5 marks): Determine the relative formula mass and formula of the Group 1 iodate(V), B. Show your working. relative formula mass of B = formula of B = [5]
  26. June 2018, Paper 3, Q3(b)(i) (1 mark): This titration is self-indicating and the student does not need to add an indicator. What colour change would the student observe at the end point? Colour chang
  27. June 2018, Paper 3, Q3(b)(ii) (6 marks): Calculate the percentage, by mass, of ethanedioic acid in the rhubarb leaves. Give your answer to an appropriate number of significant figures. percentage of et

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