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Polyesters and polyamides: OCR A‑Level Chemistry A questions

Every OCR A-Level Chemistry A exam question on 6.2.3 Polyesters and polyamides, 2016–2025, with its mark scheme and examiner’s report.

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1,820 questions

  1. Q7

    June 2025 · Paper 2

    The whole paper ↗
    June 2025 Paper 2, question 7: What are the organic products of the acid hydrolysis of CH3CH2CONHCH3? CH3CH2COO– + CH3NH3 + A + B CH3CH2COOH + CH3NH3 C CH3CH2COOH + CH3NH2 CH3CH2COO– + CH3NH2
  2. Q18(a)

    June 2025 · Paper 2

    The whole paper ↗
    June 2025 Paper 2, question 18(a): 1-Chlorobut-2-ene and 3-hydroxybutanoic acid can both form polymers. Draw two repeat units of each of the polymers formed. State the type of polymerisation reac
  3. Q18(b)(ii)

    June 2025 · Paper 2

    The whole paper ↗
    June 2025 Paper 2, question 18(b)(ii): The polymer formed from 3-hydroxybutanoic acid can be hydrolysed. This makes the polymer biodegradable. Suggest what feature in the structure of this polymer al
  4. Q12

    June 2024 · Paper 2

    The whole paper ↗
    June 2024 Paper 2, question 12: 1,6-Diaminohexane, H2N(CH2)6NH2, reacts with hexanedioyl dichloride, Cl OC(CH2)4COCl to form a polyamide and one other product. What is the other product formed
  5. Q20(c)

    June 2024 · Paper 2

    The whole paper ↗
    June 2024 Paper 2, question 20(c): The repeat unit of a polyester is shown below. O O O O Draw the structures of monomers required to form this polyester. [2]
  6. Q20(d)

    June 2024 · Paper 2

    The whole paper ↗
    June 2024 Paper 2, question 20(d): The compound below contains an ester and an amide group. O N O H O Draw the structures of the organic products formed by the complete alkaline hydrolysis of thi
  7. Q22(a)

    June 2024 · Paper 2

    The whole paper ↗
    June 2024 Paper 2, question 22(a): A polymer is formed from 500 molecules of this α-amino acid. Determine the molar mass of this polymer. Give your answer to the nearest whole number. molar mass
  8. Q22(b)

    June 2024 · Paper 2

    The whole paper ↗
    June 2024 Paper 2, question 22(b): The amino acid below can form addition and condensation polymers. H H O C C H CH C H2N OH Draw 2 repeat units of these polymers. Display the sections linking th
  9. Q20(b)(i)

    June 2023 · Paper 2

    The whole paper ↗
    June 2023 Paper 2, question 20(b)(i): A student predicts that PAS could polymerise to form a polymer containing both ester and amide linkages. Draw a section of this polymer. The section should cont
  10. Q21(c)(ii)

    June 2023 · Paper 2

    The whole paper ↗
    June 2023 Paper 2, question 21(c)(ii): A student hydrolyses compound E with dilute hydrochloric acid, HCl (aq). Draw the structures of the organic products formed by this hydrolysis. [4]
  11. Q19(c)(ii)

    June 2022 · Paper 2

    The whole paper ↗
    June 2022 Paper 2, question 19(c)(ii): Butanedicarboxylic acid and 1,4-dihydroxy-2-methylbenzene react to form a condensation polymer. Draw one repeat unit of this condensation polymer. [2]
  12. Q19(c)(iii)

    June 2022 · Paper 2

    The whole paper ↗
    June 2022 Paper 2, question 19(c)(iii): Three repeat units of a condensation polymer are shown below. O O O O O O O O O O O O Draw the structure of the monomer required to form this polymer. [1]
  13. Q19(d)(i)

    June 2022 · Paper 2

    The whole paper ↗
    June 2022 Paper 2, question 19(d)(i): Draw one repeat unit of this polymer. [1]
  14. Q19(d)(ii)

    June 2022 · Paper 2

    The whole paper ↗
    June 2022 Paper 2, question 19(d)(ii): What is the relative molecular mass, Mr, of the polymer? Mr = [2]
  15. Q17(c)

    November 2021 · Paper 2

    The whole paper ↗
    November 2021 Paper 2, question 17(c): A polymer can be made from the monomers: • 1,4-diaminobutane • benzene-1,4-diacyl dichloride. Draw the structures of these monomers and one repeat unit of the p
  16. Q18(b)(i)

    November 2020 · Paper 2

    The whole paper ↗
    November 2020 Paper 2, question 18(b)(i): Draw one repeat unit of polymer E. The functional groups should be clearly displayed. [2]
  17. Q18(b)(ii)

    November 2020 · Paper 2

    The whole paper ↗
    November 2020 Paper 2, question 18(b)(ii): Governments are encouraging the development of biodegradable polymers to reduce dependency on persistent plastic waste derived from fossil fuels. Polymer E is a
  18. Q21(b)(ii)

    November 2020 · Paper 2

    The whole paper ↗
    November 2020 Paper 2, question 21(b)(ii): A sample of aspartame is hydrolysed with aqueous acid. Draw the structures of the three organic products of the complete acid hydrolysis of aspartame. [4]
  19. Q9

    June 2019 · Paper 2

    The whole paper ↗
    June 2019 Paper 2, question 9: The repeat unit of a polymer is shown below. H H H H O O C C O C C C C H H O H H Which monomers could form this polymer? O OH HO A OH HO O O OH HO OH B HO O O O
  20. Q18(d)

    June 2019 · Paper 2

    The whole paper ↗
    June 2019 Paper 2, question 18(d): A polyester is formed from 200 molecules of 4-hydroxybenzoic acid. What is the relative molecular mass, Mr, of the polyester? Mr = g mol−1 [2]
All 27 questions on Polyesters and polyamides, as a list
  1. June 2025, Paper 2, Q7 (1 mark): What are the organic products of the acid hydrolysis of CH3CH2CONHCH3? CH3CH2COO– + CH3NH3 + A + B CH3CH2COOH + CH3NH3 C CH3CH2COOH + CH3NH2 CH3CH2COO– + CH3NH2
  2. June 2025, Paper 2, Q18(a) (4 marks): 1-Chlorobut-2-ene and 3-hydroxybutanoic acid can both form polymers. Draw two repeat units of each of the polymers formed. State the type of polymerisation reac
  3. June 2025, Paper 2, Q18(b)(ii) (1 mark): The polymer formed from 3-hydroxybutanoic acid can be hydrolysed. This makes the polymer biodegradable. Suggest what feature in the structure of this polymer al
  4. June 2024, Paper 2, Q12 (1 mark): 1,6-Diaminohexane, H2N(CH2)6NH2, reacts with hexanedioyl dichloride, Cl OC(CH2)4COCl to form a polyamide and one other product. What is the other product formed
  5. June 2024, Paper 2, Q20(c) (2 marks): The repeat unit of a polyester is shown below. O O O O Draw the structures of monomers required to form this polyester. [2]
  6. June 2024, Paper 2, Q20(d) (4 marks): The compound below contains an ester and an amide group. O N O H O Draw the structures of the organic products formed by the complete alkaline hydrolysis of thi
  7. June 2024, Paper 2, Q22(a) (3 marks): A polymer is formed from 500 molecules of this α-amino acid. Determine the molar mass of this polymer. Give your answer to the nearest whole number. molar mass
  8. June 2024, Paper 2, Q22(b) (3 marks): The amino acid below can form addition and condensation polymers. H H O C C H CH C H2N OH Draw 2 repeat units of these polymers. Display the sections linking th
  9. June 2023, Paper 2, Q20(b)(i) (3 marks): A student predicts that PAS could polymerise to form a polymer containing both ester and amide linkages. Draw a section of this polymer. The section should cont
  10. June 2023, Paper 2, Q21(c)(ii) (4 marks): A student hydrolyses compound E with dilute hydrochloric acid, HCl (aq). Draw the structures of the organic products formed by this hydrolysis. [4]
  11. June 2022, Paper 2, Q19(c)(ii) (2 marks): Butanedicarboxylic acid and 1,4-dihydroxy-2-methylbenzene react to form a condensation polymer. Draw one repeat unit of this condensation polymer. [2]
  12. June 2022, Paper 2, Q19(c)(iii) (1 mark): Three repeat units of a condensation polymer are shown below. O O O O O O O O O O O O Draw the structure of the monomer required to form this polymer. [1]
  13. June 2022, Paper 2, Q19(d)(i) (1 mark): Draw one repeat unit of this polymer. [1]
  14. June 2022, Paper 2, Q19(d)(ii) (2 marks): What is the relative molecular mass, Mr, of the polymer? Mr = [2]
  15. November 2021, Paper 2, Q17(c) (4 marks): A polymer can be made from the monomers: • 1,4-diaminobutane • benzene-1,4-diacyl dichloride. Draw the structures of these monomers and one repeat unit of the p
  16. November 2020, Paper 2, Q18(b)(i) (2 marks): Draw one repeat unit of polymer E. The functional groups should be clearly displayed. [2]
  17. November 2020, Paper 2, Q18(b)(ii) (1 mark): Governments are encouraging the development of biodegradable polymers to reduce dependency on persistent plastic waste derived from fossil fuels. Polymer E is a
  18. November 2020, Paper 2, Q21(b)(ii) (4 marks): A sample of aspartame is hydrolysed with aqueous acid. Draw the structures of the three organic products of the complete acid hydrolysis of aspartame. [4]
  19. June 2019, Paper 2, Q9 (1 mark): The repeat unit of a polymer is shown below. H H H H O O C C O C C C C H H O H H Which monomers could form this polymer? O OH HO A OH HO O O OH HO OH B HO O O O
  20. June 2019, Paper 2, Q18(d) (2 marks): A polyester is formed from 200 molecules of 4-hydroxybenzoic acid. What is the relative molecular mass, Mr, of the polyester? Mr = g mol−1 [2]
  21. June 2019, Paper 2, Q19(b)(i) (3 marks): Draw two repeat units of these polymers. Two repeat units of polymer formed from D Two repeat units of polymer formed from E [3]
  22. June 2019, Paper 2, Q19(b)(ii) (1 mark): State the type of polymer formed from compounds D and E. From compound D From compound E [1]
  23. June 2018, Paper 2, Q17(c) (3 marks): α-Amino acids can react to form proteins. A short section of a protein chain is shown below. HO H O CH2 CH N C N C CH CH2 H O CH2 C O H2N A student hydrolyses t
  24. June 2018, Paper 2, Q21(b) (4 marks): Compound H is used in the synthesis of polymer I, as shown in the flowchart below. Complete the flowchart by drawing the structure of the acyl chloride and two
  25. June 2017, Paper 2, Q18(a)(iv) (3 marks): Compound I is the monomer for the biodegradable polymer J. Draw two repeat units of polymer J and suggest a reason why it is biodegradable. [3]
  26. June 2017, Paper 2, Q18(b)(i) (2 marks): Draw the structures of two monomers that can be used to form Nylon 6,6. [2]
  27. June 2017, Paper 2, Q18(b)(ii) (1 mark): A sample of Nylon 6,6 has a relative molecular mass of 21500. Estimate the number of repeat units in the sample. Give your answer as a whole number. number of r

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