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Kc and Kp expressions and calculations: OCR A‑Level Chemistry A questions

OCR A-Level Chemistry A past-paper questions on 5.1.2.2 Kc and Kp expressions and calculations, 2016–2025, with mark schemes and examiner’s reports where available.

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  1. Q17(c)(i)

    June 2025 · Paper 1

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  3. The start of question 18

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  4. The start of question 19

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  5. Q6(d)

    June 2023 · Paper 3

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  8. Q1(b)

    November 2021 · Paper 3

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  9. Q9

    November 2020 · Paper 1

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  10. The start of question 17

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  11. Q20(b)

    November 2020 · Paper 1

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  13. Q18(a)

    June 2018 · Paper 1

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  15. Q5(b)(iv)

    June 2018 · Paper 3

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  17. Q18(b)(i)

    June 2017 · Paper 1

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  18. Q18(b)(ii)

    June 2017 · Paper 1

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  19. Q20(b)(i)

    June 2017 · Paper 1

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All 21 questions on Kc and Kp expressions and calculations, as a list
  1. June 2025, Paper 1, Q17(c)(i) (1 mark): Explain why Kp for Equilibrium 17.3 has no units. [1]
  2. June 2025, Paper 1, Q17(c)(ii) (3 marks): An equal number of moles of steam and carbon monoxide are left at 700 K in a sealed container until equilibrium is reached. At equilibrium, both H2 and CO2 have
  3. June 2024, Paper 1, Q18(a)(i) (5 marks): 2.25 moles of SO3 is heated to 550 °C in the presence of a catalyst and the resulting mixture allowed to reach equilibrium. The equilibrium mixture contains 0.9
  4. June 2023, Paper 1, Q19(a)(i) (5 marks): A sealed flask containing 6.00 moles of NO2(g) is heated to a constant temperature and allowed to reach equilibrium. The equilibrium mixture contains 5.40 mol o
  5. June 2023, Paper 3, Q6(d) (5 marks): In the UK, most sulfuric acid, H2SO4, is manufactured by the Contact process. One stage in the Contact process involves the equilibrium between sulfur dioxide,
  6. June 2022, Paper 1, Q20(a) (6 marks): This question is about equilibria involving hydrogen. (a)* Hydrogen is used industrially to manufacture ammonia. The equilibrium is shown below. 2NH3(g) ∆H = –9
  7. November 2021, Paper 1, Q20(c)(i) (4 marks): Calculate Kp, in MPa–1, for Equilibrium 20.1. Give your answer to 3 significant figures. Kp = MPa–1 [4]
  8. November 2021, Paper 3, Q1(b) (2 marks): Pure PCl5 is placed in a sealed container which is heated to 200 ºC. An equilibrium is set up: PCl5(g) PCl3(g) + Cl2(g) Under these conditions: Kc = 8.00 × 10–3
  9. November 2020, Paper 1, Q9 (1 mark): The reversible reaction of nitrogen and hydrogen to form ammonia is shown below. N2(g) + 3H2(g) 2NH3(g) In the equilibrium mixture, the partial pressure of N2 i
  10. November 2020, Paper 1, Q17(d) (3 marks): At 298 K, the free energy change, ∆G, for the production of methanol in equilibrium 1 is −2.48 × 104 J mol−1. ∆G is linked to Kp by the relationship: ∆G = −RT l
  11. November 2020, Paper 1, Q20(b) (4 marks): The student carries out a second experiment to determine the value of Kc for this reaction. The student mixes 9.6 g of CH3OH with 12.0 g of CH3COOH and adds the
  12. June 2019, Paper 1, Q19(b)(ii) (5 marks): Determine the value of Kp for Equilibrium 1 at 1000 K. Show all your working. Give your answer to 3 significant figures. Kp = [5]
  13. June 2018, Paper 1, Q18(a) (2 marks): Write an expression for Kc for this equilibrium and state the units. Kc = Units = [2]
  14. June 2018, Paper 1, Q18(b) (4 marks): A chemist mixes together nitrogen and oxygen and pressurises the gases so that their total gas volume is 4.0 dm3. • The mixture is allowed to reach equilibrium
  15. June 2018, Paper 3, Q5(b)(iv) (1 mark): Kc is the equilibrium constant in terms of equilibrium concentrations. Why can expression 5.1 be used to calculate Kc for this equilibrium? [1]
  16. June 2018, Paper 3, Q5(b)(v) (3 marks): Calculate the value of Kc for this reaction. Show your working. Kc = [3]
  17. June 2017, Paper 1, Q18(b)(i) (1 mark): Why is equilibrium 18.1 a heterogeneous equilibrium? [1]
  18. June 2017, Paper 1, Q18(b)(ii) (1 mark): Write the expression for Kp for equilibrium 18.1. [1]
  19. June 2017, Paper 1, Q20(b)(i) (2 marks): Write the expression for Kc and the units of Kc for this equilibrium. [2]
  20. June 2017, Paper 1, Q20(b)(ii) (4 marks): Determine the amount, in mol, of SO3 in the equilibrium mixture at this temperature. Give your final answer to an appropriate number of significant figures. Sho
  21. June 2017, Paper 3, Q3(c)(ii) (3 marks): Peroxyethanoic acid can be prepared by reacting hydrogen peroxide with ethanoic acid. This is a heterogeneous equilibrium. CH3COOOH(aq) + H2O(l) Kc = 0.37 dm3 m

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