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Reaction mechanisms: OCR A‑Level Chemistry B questions

Every OCR A-Level Chemistry B exam question on CD Reaction mechanisms (specification points CD(k)–(l)), 2016–2025, with its mark scheme and examiner’s report.

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2,049 questions

  1. Q27

    June 2024 · Paper 1

    The whole paper ↗
    June 2024 Paper 1, question 27: Ethanal, CH3CHO, reacts with cyanide in a two-step mechanism. What is correct about this mechanism? A In step 1 the nitrogen on the cyanide ion attacks the carb
  2. Q34(e)

    June 2024 · Paper 1

    The whole paper ↗
    June 2024 Paper 1, question 34(e): The mechanism for the dehydration of a cyclic alcohol using concentrated sulfuric acid takes place in two steps. Step 1: H O+ O H H + H+ Step 2: H H H O+ H H+ +
  3. Q4(a)

    June 2023 · Paper 2

    The whole paper ↗
    June 2023 Paper 2, question 4(a): Name the type of reaction by which 3-oxybutanoic acid is converted to 3-hydroxybutanoic acid. [1]
  4. Q4(g)(i)

    June 2023 · Paper 2

    The whole paper ↗
    June 2023 Paper 2, question 4(g)(i): Complete the mechanism for this reaction. Show curly arrows, charges, lone pairs and the product. O C H3C CH3 [3]
  5. Q35(e)(iii)

    June 2022 · Paper 1

    The whole paper ↗
    June 2022 Paper 1, question 35(e)(iii): The reaction of benzaldehyde with hydrogen cyanide can be written as follows: C6H5CHO + HCN C6H5CH(OH)CN Write out the two-step mechanism for this reaction. Use
  6. Q4(d)

    June 2022 · Paper 2

    The whole paper ↗
    June 2022 Paper 2, question 4(d): Chymotrypsin catalyses the hydrolysis of proteins in the small intestine. The active site of chymotrypsin consists of the amino acids serine, histidine and aspa
  7. Q34(a)(i)

    November 2021 · Paper 1

    The whole paper ↗
    November 2021 Paper 1, question 34(a)(i): Name the type of reaction that occurs in reaction 1. [1]
  8. Q3(e)(i)

    November 2021 · Paper 2

    The whole paper ↗
    November 2021 Paper 2, question 3(e)(i): Draw the mechanism for the attack of a cyanide ion on benzaldehyde, followed by attack by H+ to give compound C. [2]
  9. Q1(c)

    November 2021 · Paper 3

    The whole paper ↗
    November 2021 Paper 3, question 1(c): Alcohols can also undergo substitution reactions. The following sequence shows an incomplete mechanism for the reaction between (CH3)3COH and concentrated hydro
  10. Q4(e)(i)

    November 2020 · Paper 2

    The whole paper ↗
    November 2020 Paper 2, question 4(e)(i): Draw ‘curly arrows’ on Fig. 4.2 to complete the mechanism. H COOH COOH Step 1 Step 2 COOH H COOH C C HOOC C C C C + H H H HOOC H +H+ H+ H maleic acid fumaric ac
  11. Q4(e)(iii)

    November 2020 · Paper 2

    The whole paper ↗
    November 2020 Paper 2, question 4(e)(iii): The student then reads that if 2H+ ions are used for the isomerisation, then there isn’t any 2H found in the fumaric acid formed. Does this support the student’
  12. Q2(b)

    June 2019 · Paper 3

    The whole paper ↗
    June 2019 Paper 3, question 2(b): The reactant 4-aminophenol can be made from phenol in the two-step synthesis shown below. OH OH OH dil. H2SO4 NaBH4 NaNO3 NO2 NH2 Name the type of reaction for
  13. Q2(d)

    June 2019 · Paper 3

    The whole paper ↗
    June 2019 Paper 3, question 2(d): The mechanism for the reaction for the formation of paracetamol is shown in Fig. 2.3. Ethanoic anhydride Intermediate O O – C C H O H3C O CH3 + N C O HO C O H C
  14. Q31(f)

    June 2018 · Paper 1

    The whole paper ↗
    June 2018 Paper 1, question 31(f): The carbonyl compound from (e) can be reacted further to produce other raw materials. For example, it reacts with HCN. The formula of a carbonyl compound is sho
  15. Q34(d)

    June 2017 · Paper 1

    The whole paper ↗
    June 2017 Paper 1, question 34(d): Another dye is used as an acid-base indicator. It is red in acidic conditions and yellow in neutral or alkaline conditions. The equation for the reaction produc
  16. Q2(b)(iii)

    June 2017 · Paper 2

    The whole paper ↗
    June 2017 Paper 2, question 2(b)(iii): Name the type of reaction that occurs in step 2 and name the functional group that has been formed. Type of reaction Functional group formed [1]
  17. Q3(a)(v)

    June 2017 · Paper 2

    The whole paper ↗
    June 2017 Paper 2, question 3(a)(v): Explain why the reaction in which the linear form changes to the ring form is not condensation. [1]
  18. Q3(a)(vi)

    June 2017 · Paper 2

    The whole paper ↗
    June 2017 Paper 2, question 3(a)(vi): Complete the equation that shows the reaction when the linear form changes to the ring form. –CHO + HO– → [1]
All 18 questions on Reaction mechanisms, as a list
  1. June 2024, Paper 1, Q27 (1 mark): Ethanal, CH3CHO, reacts with cyanide in a two-step mechanism. What is correct about this mechanism? A In step 1 the nitrogen on the cyanide ion attacks the carb
  2. June 2024, Paper 1, Q34(e) (2 marks): The mechanism for the dehydration of a cyclic alcohol using concentrated sulfuric acid takes place in two steps. Step 1: H O+ O H H + H+ Step 2: H H H O+ H H+ +
  3. June 2023, Paper 2, Q4(a) (1 mark): Name the type of reaction by which 3-oxybutanoic acid is converted to 3-hydroxybutanoic acid. [1]
  4. June 2023, Paper 2, Q4(g)(i) (3 marks): Complete the mechanism for this reaction. Show curly arrows, charges, lone pairs and the product. O C H3C CH3 [3]
  5. June 2022, Paper 1, Q35(e)(iii) (3 marks): The reaction of benzaldehyde with hydrogen cyanide can be written as follows: C6H5CHO + HCN C6H5CH(OH)CN Write out the two-step mechanism for this reaction. Use
  6. June 2022, Paper 2, Q4(d) (3 marks): Chymotrypsin catalyses the hydrolysis of proteins in the small intestine. The active site of chymotrypsin consists of the amino acids serine, histidine and aspa
  7. November 2021, Paper 1, Q34(a)(i) (1 mark): Name the type of reaction that occurs in reaction 1. [1]
  8. November 2021, Paper 2, Q3(e)(i) (2 marks): Draw the mechanism for the attack of a cyanide ion on benzaldehyde, followed by attack by H+ to give compound C. [2]
  9. November 2021, Paper 3, Q1(c) (2 marks): Alcohols can also undergo substitution reactions. The following sequence shows an incomplete mechanism for the reaction between (CH3)3COH and concentrated hydro
  10. November 2020, Paper 2, Q4(e)(i) (2 marks): Draw ‘curly arrows’ on Fig. 4.2 to complete the mechanism. H COOH COOH Step 1 Step 2 COOH H COOH C C HOOC C C C C + H H H HOOC H +H+ H+ H maleic acid fumaric ac
  11. November 2020, Paper 2, Q4(e)(iii) (2 marks): The student then reads that if 2H+ ions are used for the isomerisation, then there isn’t any 2H found in the fumaric acid formed. Does this support the student’
  12. June 2019, Paper 3, Q2(b) (2 marks): The reactant 4-aminophenol can be made from phenol in the two-step synthesis shown below. OH OH OH dil. H2SO4 NaBH4 NaNO3 NO2 NH2 Name the type of reaction for
  13. June 2019, Paper 3, Q2(d) (1 mark): The mechanism for the reaction for the formation of paracetamol is shown in Fig. 2.3. Ethanoic anhydride Intermediate O O – C C H O H3C O CH3 + N C O HO C O H C
  14. June 2018, Paper 1, Q31(f) (4 marks): The carbonyl compound from (e) can be reacted further to produce other raw materials. For example, it reacts with HCN. The formula of a carbonyl compound is sho
  15. June 2017, Paper 1, Q34(d) (3 marks): Another dye is used as an acid-base indicator. It is red in acidic conditions and yellow in neutral or alkaline conditions. The equation for the reaction produc
  16. June 2017, Paper 2, Q2(b)(iii) (1 mark): Name the type of reaction that occurs in step 2 and name the functional group that has been formed. Type of reaction Functional group formed [1]
  17. June 2017, Paper 2, Q3(a)(v) (1 mark): Explain why the reaction in which the linear form changes to the ring form is not condensation. [1]
  18. June 2017, Paper 2, Q3(a)(vi) (1 mark): Complete the equation that shows the reaction when the linear form changes to the ring form. –CHO + HO– → [1]

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