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The rate-determining step: OCR A‑Level Chemistry A questions

OCR A-Level Chemistry A past-paper questions on 5.1.1.4 The rate-determining step, 2016–2025, with mark schemes and examiner’s reports where available.

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  1. Q9

    June 2025 · Paper 1

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  3. Q20(b)

    June 2024 · Paper 1

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  4. Q16(b)

    June 2022 · Paper 1

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  5. Q21(a)(ii)

    November 2021 · Paper 1

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  6. Q4(c)(i)

    November 2021 · Paper 3

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  7. The start of question 17

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All 7 questions on The rate-determining step, as a list
  1. June 2025, Paper 1, Q9 (1 mark): Hydrogen reacts with iodine monochloride, ICl , as shown in the equation: H2 + 2ICl 2HCl + I2 The mechanism for the reaction is: H2 + ICl HCl + HI slow step HI
  2. June 2025, Paper 3, Q3(b) (6 marks): This question is about equilibrium and rates. (b)* A reaction takes place when aqueous solutions of propanone, CH3COCH3(aq), and bromine, Br2(aq), are mixed in
  3. June 2024, Paper 1, Q20(b) (2 marks): Fluorine, F2, reacts with nitrogen dioxide, NO2, to form nitryl fluoride, NO2F, as shown in Reaction 20.1 below. F2 + 2NO2 2NO2F Reaction 20.1 The mechanism for
  4. June 2022, Paper 1, Q16(b) (2 marks): Carbon monoxide also reacts with nitrogen dioxide as shown in Reaction 16.2. CO(g) + NO2(g) NO(g) + CO2(g) Reaction 16.2 The rate equation for Reaction 16.2 is
  5. November 2021, Paper 1, Q21(a)(ii) (2 marks): Predict a possible two-step mechanism for Reaction 21.1. The first step is the rate-determining step. Step 1 Step 2 [2]
  6. November 2021, Paper 3, Q4(c)(i) (2 marks): Write equations to suggest a two-step mechanism for the reaction. Slow Fast [2]
  7. June 2018, Paper 1, Q17(a) (6 marks): This question is about reaction rates. Aqueous iron(III) ions, Fe3+(aq), react with aqueous iodide ions, I–(aq), as shown below. 2Fe3+(aq) + 2I–(aq) 2Fe2+(aq) +

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