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Disproportionation and chlorine in water: OCR A‑Level Chemistry A questions

OCR A-Level Chemistry A past-paper questions on 3.1.3.3 Disproportionation and chlorine in water, 2016–2025, with mark schemes and examiner’s reports where available.

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  1. Q22(a)

    June 2025 · AS Paper 1

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  2. Q22(b)(ii)

    June 2025 · AS Paper 1

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  3. Q6

    June 2024 · Paper 1

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  4. Q20(a)(i)

    June 2024 · Paper 1

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  5. Q8

    June 2024 · AS Paper 1

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  6. Q9

    June 2024 · AS Paper 1

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  7. Q3(b)

    June 2023 · AS Paper 2

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  9. Q24(a)(i)

    June 2022 · AS Paper 1

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  10. Q24(a)(ii)

    June 2022 · AS Paper 1

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  11. Q23(a)

    November 2021 · AS Paper 1

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  12. Q21(b)

    November 2020 · Paper 1

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  13. Q3(d)(ii)

    November 2020 · AS Paper 2

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  14. Q1(a)(v)

    June 2018 · Paper 3

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  15. Q3(b)(i)

    June 2018 · AS Paper 2

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  16. Q3(b)(ii)

    June 2018 · AS Paper 2

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  18. Q23(b)

    June 2016 · AS Paper 1

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All 18 questions on Disproportionation and chlorine in water, as a list
  1. June 2025, AS Paper 1, Q22(a) (3 marks): An aqueous solution of bromine reacts with cold aqueous sodium hydroxide in a disproportionation reaction. The equation is shown below. Br2(aq) + 2NaOH(aq) NaBr
  2. June 2025, AS Paper 1, Q22(b)(ii) (1 mark): Chlorine is used in water treatment. State one disadvantage of treating water with chlorine. [1]
  3. June 2024, Paper 1, Q6 (1 mark): Which equation does not represent a disproportionation reaction? A Cl 2 + H2O HCl O + HCl B Cl 2 + 2NaOH NaCl O + NaCl + H2O C 4KCl O3 KCl + 3KCl O4 D 4HCl + Mn
  4. June 2024, Paper 1, Q20(a)(i) (1 mark): Chlorine is used to treat water in large-scale water treatment plants. Suggest why chlorine is added to water in large-scale water treatment plants. [1]
  5. June 2024, AS Paper 1, Q8 (1 mark): In the UK, water companies typically treat drinking water with chlorine gas at a concentration of 0.500 mg dm–3 or less. Which statement about UK drinking water
  6. June 2024, AS Paper 1, Q9 (1 mark): Which reaction does not show disproportionation of chlorine? A MnO2 + 4HCl MnCl 2 + Cl 2 + 2H2O B Cl 2 + H2O HCl + HCl O C 2Cl O2 + 2NaOH NaCl O2 + NaCl O3 + H2
  7. June 2023, AS Paper 2, Q3(b) (3 marks): Chlorine reacts with calcium hydroxide to form Ca(OCl )2, which is the active ingredient in bleaching powder. 2Cl 2 + 2Ca(OH)2 CaCl 2 + Ca(OCl )2 + 2H2O This is
  8. June 2022, Paper 3, Q2(a)(ii) (3 marks): Calcium hypochlorite, Ca(Cl O)2, is heated. The Ca(Cl O)2 decomposes to form CaCl 2 and Ca(Cl O3)2. This is a disproportionation reaction. Write an equation for
  9. June 2022, AS Paper 1, Q24(a)(i) (1 mark): What is meant by the term disproportionation? [1]
  10. June 2022, AS Paper 1, Q24(a)(ii) (3 marks): Construct the equation for the reaction of chlorine with dilute sodium hydroxide. Use your equation to explain that disproportionation has taken place. Equation
  11. November 2021, AS Paper 1, Q23(a) (1 mark): Chlorine is used to kill bacteria in drinking water. State one risk in using chlorine in drinking water. [1]
  12. November 2020, Paper 1, Q21(b) (1 mark): Chlorine is used in water treatment. State one benefit and one risk of using chlorine in water treatment. Benefit Risk [1]
  13. November 2020, AS Paper 2, Q3(d)(ii) (3 marks): This reaction is an example of disproportionation. Use oxidation numbers to explain why. Include the meaning of the term disproportionation. [3]
  14. June 2018, Paper 3, Q1(a)(v) (1 mark): An element which reacts with water to form an acidic solution. [1]
  15. June 2018, AS Paper 2, Q3(b)(i) (3 marks): Iodine reacts with water as shown below. I2 + H2O HI + HIO Using oxidation numbers, explain why this reaction is a disproportionation. [3]
  16. June 2018, AS Paper 2, Q3(b)(ii) (1 mark): Chlorine is used to purify water on a large scale. State one disadvantage of using chlorine for the purification of drinking water. [1]
  17. June 2017, Paper 1, Q17(c)(i) (3 marks): State what is meant by disproportionation and use oxidation numbers to show that disproportionation has taken place. [3]
  18. June 2016, AS Paper 1, Q23(b) (1 mark): Chlorine is used in water treatment. State one benefit and one risk of chlorine in water treatment. Benefit Risk [1]

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