Atomic structure and isotopes: OCR A‑Level Chemistry A questions
Every OCR A-Level Chemistry A exam question on 2.1.1 Atomic structure and isotopes, 2016–2025, with its mark scheme and examiner’s report.
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Q1(a)(i)
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Q1(a)(ii)
The whole paper ↗![June 2025 Paper 3, question 1(a)(ii): Explain why there are peaks with m/z values of 158, 160 and 162 and predict their relative abundances. Explanation Relative abundances [3]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h43203-jun25-01-aii-qp.webp?v=3)
Q21(a)
The whole paper ↗![June 2025 AS Paper 1, question 21(a): This part of the question is about sulfur. Complete the table below. Species Protons Neutrons Electrons 34S 16 16 18 [2]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h03201-jun25-21-a-qp.webp?v=3)
Q21(b)
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![June 2024 AS Paper 1, question 2: Which row shows the atomic structure of 25Mg2+? 2 Protons Neutrons Electrons A 10 12 13 B 10 15 12 C 12 13 10 D 12 13 14 Your answer [1]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h03201-jun24-02-qp.webp?v=3)
Q21(a)
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Q1(a)(i)
The whole paper ↗![June 2023 AS Paper 2, question 1(a)(i): Calculate the relative atomic mass of titanium in the sample. Give your answer to 2 decimal places. relative atomic mass = [2]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h03202-jun23-01-ai-qp.webp?v=3)
Q1(a)(iii)
The whole paper ↗![June 2023 AS Paper 2, question 1(a)(iii): Complete the table to show the number of protons, neutrons and electrons in a 48Ti2+ ion. Protons Neutrons Electrons 48Ti2+ ion [1]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h03202-jun23-01-aiii-qp.webp?v=3)
Q1(b)(i)
The whole paper ↗![June 2022 Paper 3, question 1(b)(i): What are the percentage compositions of copper and zinc in the brass sample? Cu = % Zn = % [1]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h43203-jun22-01-bi-qp.webp?v=3)
Q1(b)(ii)
The whole paper ↗![June 2022 Paper 3, question 1(b)(ii): Calculate the relative atomic mass of zinc in the sample of brass. Give your answer to 2 decimal places. relative atomic mass = [2]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h43203-jun22-01-bii-qp.webp?v=3)
Q22(a)
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Q22(b)
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Q21(b)
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Q21(c)
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Q16(a)
The whole paper ↗![November 2020 Paper 1, question 16(a): Relative atomic mass is defined as ‘the weighted mean mass compared with 1/12th mass of carbon-12’. Explain what is meant by the term weighted mean mass. [1]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h43201-nov20-16-a-qp.webp?v=3)
Q21(b)
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Q21(c)(i)
The whole paper ↗![November 2020 AS Paper 1, question 21(c)(i): Calculate the relative atomic mass of chlorine. Give your answer to 2 decimal places. relative atomic mass = [2]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h03201-nov20-21-ci-qp.webp?v=3)
Q21(c)(ii)
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Q16(b)
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All 35 questions on Atomic structure and isotopes, as a list
- June 2025, Paper 1, Q1 (1 mark): The table shows the number of protons and neutrons in four different atoms. Atom Number of protons Number of neutrons W 17 18 X 18 18 Y 19 18 Z 18 19 Which two
- June 2025, Paper 3, Q1(a)(i) (2 marks): Complete the table to show the number of protons, neutrons and electrons in the particles that cause the peaks at m/z 79 and 81. Number of Number of Number of m
- June 2025, Paper 3, Q1(a)(ii) (3 marks): Explain why there are peaks with m/z values of 158, 160 and 162 and predict their relative abundances. Explanation Relative abundances [3]
- June 2025, AS Paper 1, Q21(a) (2 marks): This part of the question is about sulfur. Complete the table below. Species Protons Neutrons Electrons 34S 16 16 18 [2]
- June 2025, AS Paper 1, Q21(b) (2 marks): The mass spectrum of a sample of magnesium is shown below. 75.45% Relative abundance 15.21% 9.34% 24 25 26 m / z Calculate the relative atomic mass of magnesium
- June 2024, AS Paper 1, Q2 (1 mark): Which row shows the atomic structure of 25Mg2+? 2 Protons Neutrons Electrons A 10 12 13 B 10 15 12 C 12 13 10 D 12 13 14 Your answer [1]
- June 2024, AS Paper 1, Q21(a) (2 marks): A sample of iron is isolated from a meteorite and analysed by mass spectrometry. The mass spectrum shows peaks with the relative abundances below. 54Fe 56Fe 57F
- June 2023, AS Paper 2, Q1(a)(i) (2 marks): Calculate the relative atomic mass of titanium in the sample. Give your answer to 2 decimal places. relative atomic mass = [2]
- June 2023, AS Paper 2, Q1(a)(iii) (1 mark): Complete the table to show the number of protons, neutrons and electrons in a 48Ti2+ ion. Protons Neutrons Electrons 48Ti2+ ion [1]
- June 2022, Paper 3, Q1(b)(i) (1 mark): What are the percentage compositions of copper and zinc in the brass sample? Cu = % Zn = % [1]
- June 2022, Paper 3, Q1(b)(ii) (2 marks): Calculate the relative atomic mass of zinc in the sample of brass. Give your answer to 2 decimal places. relative atomic mass = [2]
- June 2022, AS Paper 1, Q22(a) (2 marks): The relative atomic mass of a sample of osmium can be determined from its mass spectrum, shown below. 43.89% 27.23% relative abundance 16.75% (%) 12.13% 185 186
- June 2022, AS Paper 1, Q22(b) (2 marks): Complete the table for an atom and an ion of two different elements. Mass Element Protons Neutrons Electron configuration Charge number 28 34 0 1s22s22p63s23p6
- November 2021, AS Paper 1, Q21(b) (1 mark): Selenium, Se, has the atomic number 34. 76Se and 82Se are two isotopes of selenium. Complete the table to show the numbers of protons, neutrons and electrons in
- November 2021, AS Paper 1, Q21(c) (2 marks): The relative atomic mass of an element can be determined from its mass spectrum. The table shows the results of a mass spectrum of a sample of sulfur, S. Isotop
- November 2020, Paper 1, Q16(a) (1 mark): Relative atomic mass is defined as ‘the weighted mean mass compared with 1/12th mass of carbon-12’. Explain what is meant by the term weighted mean mass. [1]
- November 2020, AS Paper 1, Q21(b) (2 marks): Most elements contain atoms of different isotopes. State any differences and similarities between the atomic structures of isotopes of the same element. Differe
- November 2020, AS Paper 1, Q21(c)(i) (2 marks): Calculate the relative atomic mass of chlorine. Give your answer to 2 decimal places. relative atomic mass = [2]
- November 2020, AS Paper 1, Q21(c)(ii) (2 marks): The mass spectrum of chlorine, Cl 2, also contains three molecular ion, M+, peaks. One of the M+ peaks has an m /z value of 72. Suggest why an M+ peak at m /z =
- June 2019, Paper 1, Q16(b) (2 marks): A sample of magnesium, Ar = 24.305, is found to consist of three isotopes. The accurate relative isotopic masses and % abundances of two of the isotopes are sho
- June 2019, Paper 3, Q1(b) (1 mark): Explain why a small proportion of molecules in water have a relative molecular mass of 20. [1]
- June 2019, AS Paper 1, Q21(a) (1 mark): Most elements contain different isotopes. State two differences between isotopes of the same element. [1]
- June 2019, AS Paper 1, Q21(b) (2 marks): Complete the table for an atom and an ion of two different elements. Mass Element Protons Neutrons Electrons Charge number 26 28 0 80 36 2− [2]
- June 2019, AS Paper 2, Q1(a)(i) (2 marks): Explain what is meant by the term relative atomic mass of an element. [2]
- June 2019, AS Paper 2, Q1(a)(ii) (2 marks): A sample of strontium has a relative atomic mass of 87.73. The sample consists of: • 82.9% Sr-88 • 6.9% Sr-87 • one other isotope. Determine the other isotope o
- June 2018, Paper 1, Q1 (1 mark): A sample of boron contains the isotopes 10B and 11B. 1 The relative atomic mass of the boron sample is 10.8. What is the percentage of 11B atoms in the sample o
- June 2018, AS Paper 1, Q21(a)(i) (1 mark): Complete the table to show the atomic structure of 30Si. Protons Neutrons Electrons 30Si [1]
- June 2018, AS Paper 1, Q21(a)(ii) (2 marks): A sample of silicon is analysed by mass spectrometry. The mass spectrum shows peaks with the relative abundances below. 28Si • 92.23% 29Si • 4.68% 30Si • 3.09%
- June 2017, Paper 1, Q1 (1 mark): Which atom is not an isotope of iodine? Number of neutrons Mass number A 72 125 B 74 127 C 75 128 D 77 129 Your answer [1]
- June 2017, AS Paper 1, Q1 (1 mark): Which ion has a different number of electrons from the other three ions? Ga3+ A Cl − B S2− C Ca2+ D Your answer [1]
- June 2017, AS Paper 1, Q22(a)(i) (2 marks): The species causing the peaks in the mass spectrum are 1+ ions of magnesium. Complete the table to show the number of protons, neutrons and electrons in each 1+
- June 2017, AS Paper 1, Q22(a)(ii) (2 marks): Calculate the relative atomic mass of the magnesium in the sample. Give your answer to two decimal places. relative atomic mass = [2]
- June 2016, AS Paper 1, Q1 (1 mark): Which row shows the atomic structure of 37Cl–? 1 protons neutrons electrons A 17 18 20 B 17 20 18 C 18 19 17 D 20 17 21 Your answer [1]
- June 2016, AS Paper 1, Q21(a) (2 marks): Copper and nickel each exist as a mixture of isotopes. State the similarities and differences between the atomic structure of isotopes of the same element. Simi
- June 2016, AS Paper 1, Q21(b)(i) (2 marks): Calculate the relative atomic mass of the copper used to make the coins. Give your answer to two decimal places. relative atomic mass = [2]
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