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Types of reaction and bond breaking: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 4.A.3 Types of reaction and bond breaking, 2019–2025, with mark schemes and examiner’s reports where available.

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  2. The start of question 19

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  5. The start of question 10

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  6. Q21(a)

    October 2021 · Unit 5

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  10. Q17

    June 2019 · AS Unit 1

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  11. Q13

    January 2019 · AS Unit 1

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All 11 questions on Types of reaction and bond breaking, as a list
  1. October 2024, AS Unit 1, Q14 (1 mark): Polymerisation of alkenes occurs via a free radical mechanism. This reaction is started by the addition of small amounts of another compound. The structure of o
  2. January 2024, AS Unit 1, Q19(b)(ii) (2 marks): Using your answer to (b)(i), state what is meant by the terms homolytic and free radical. (2) homolytic free radical
  3. October 2022, AS Unit 1, Q7(b) (1 mark): One of the steps of the reaction is shown. C8H17• + Br2 → C8H17Br + Br• What is the name of this step and the type of bond breaking that takes place in the brom
  4. June 2022, AS Unit 1, Q14 (1 mark): Heterolytic fission produces A free radicals only B ions only C free radicals and positive ions only D free radicals and negative ions only Use this space for a
  5. January 2022, AS Unit 1, Q10(b) (1 mark): The ultraviolet radiation is needed for (1) A homolytic breaking of a Br–Br bond B heterolytic breaking of a Br–Br bond C homolytic breaking of a C–H bond D het
  6. October 2021, Unit 5, Q21(a) (1 mark): The equation shows the reaction between a free radical T• and curcumin (shown by a simplified structure). O O X X TH + H T O O curcumin Complete the left‑hand s
  7. October 2020, AS Unit 1, Q22(b)(i) (1 mark): State the essential condition necessary for this process. (1)
  8. October 2020, AS Unit 1, Q22(b)(ii) (2 marks): Write an equation for this fission in molecule X. Include curly half-arrows. (2)
  9. January 2020, AS Unit 1, Q21(f)(i) (1 mark): Classify the type of reaction occurring in Reaction 1. (1)
  10. June 2019, AS Unit 1, Q17 (1 mark): What type of bond breaking occurs in this process? H2O o H+ + OH− A electrophilic B heterolytic C homolytic D ionic Use this space for any rough working. Anythi
  11. January 2019, AS Unit 1, Q13 (1 mark): An electrophile A accepts a pair of electrons B always has a negative charge C always has a positive charge D donates a pair of electrons

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