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Hazard, risk and working safely: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 4.A.1 Hazard, risk and working safely, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. Q14(a)

    June 2025 · AS Unit 1

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  2. Q14(b)

    June 2025 · AS Unit 1

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  5. Q14

    January 2025 · AS Unit 1

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  7. Q4(d)(i)

    October 2024 · AS Unit 3

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  8. Q4(d)(ii)

    October 2024 · AS Unit 3

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  9. Q4(d)(iii)

    October 2024 · AS Unit 3

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  10. Q4(d)(iv)

    October 2024 · AS Unit 3

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  11. Q4(a)

    October 2024 · Unit 6

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  12. Q3(a)(ii)

    June 2024 · AS Unit 3

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  13. Q19(a)

    June 2024 · Unit 5

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  16. Q17

    October 2023 · AS Unit 1

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  17. Q3(a)(i)

    October 2023 · AS Unit 3

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  18. Q3(a)(ii)

    October 2023 · AS Unit 3

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  19. Q15

    January 2023 · AS Unit 1

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  20. Q17(e)(i)

    October 2022 · AS Unit 1

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All 36 questions on Hazard, risk and working safely, as a list
  1. June 2025, AS Unit 1, Q14(a) (1 mark): Hairdressers use solutions of hydrogen peroxide that have these hazards: • can cause serious eye damage • is harmful if swallowed • is an oxidising agent Which
  2. June 2025, AS Unit 1, Q14(b) (1 mark): When hydrogen peroxide is used in an experiment to measure rate of decomposition, how could the risk be reduced? (I) using an alternative method that involves l
  3. June 2025, Unit 6, Q4(a) (1 mark): State the main safety precaution, other than wearing safety spectacles and a laboratory coat, that should be taken when weighing the phenol in Step 1. (1)
  4. June 2025, Unit 6, Q4(b) (1 mark): Give one reason why Step 2 must be performed in a fume cupboard. (1)
  5. January 2025, AS Unit 1, Q14 (1 mark): Which hazard warning symbol would be found on a bottle of hexane? A B C D
  6. January 2025, Unit 6, Q2(d) (3 marks): The hazard symbols present on the reagent bottle containing phenylamine are shown. State three precautions, other than wearing safety glasses and a laboratory c
  7. October 2024, AS Unit 3, Q4(d)(i) (1 mark): Draw the hazard symbol that should be displayed on the bottle of hydrogen peroxide. (1)
  8. October 2024, AS Unit 3, Q4(d)(ii) (1 mark): State one safety precaution that should be taken when using the hydrogen peroxide, other than wearing a lab coat and safety spectacles. (1)
  9. October 2024, AS Unit 3, Q4(d)(iii) (1 mark): The risk of harm to students needs to be reduced before they carry out this experiment in class. Suggest another control measure to reduce the risk for students
  10. October 2024, AS Unit 3, Q4(d)(iv) (1 mark): Give a reason why, during the experiment, the measuring cylinders should be placed in a tray. (1)
  11. October 2024, Unit 6, Q4(a) (2 marks): Phenylamine, used in Reaction 1, is labelled with the following hazard symbols. State the meaning of each symbol. (2)
  12. June 2024, AS Unit 3, Q3(a)(ii) (2 marks): The 3‑way tap can be used to prevent more chlorine gas from entering the equilibrium system. Identify Q and state why it is necessary. (2)
  13. June 2024, Unit 5, Q19(a) (1 mark): Identify the hazard symbol(s) that should be displayed on a box of liquitabs, using ticks (). (1)
  14. June 2024, Unit 6, Q5(a)(ii) (1 mark): Containers of ammonia gas have the following hazard warning signs. State these two hazards associated with ammonia. (1)
  15. June 2024, Unit 6, Q5(a)(iii) (1 mark): Give a precaution to reduce the risk when carrying out Steps 3 and 4. It is assumed that safety goggles and a laboratory coat are used. (1)
  16. October 2023, AS Unit 1, Q17 (1 mark): A technician is asked to store four reagent bottles safely. The only information about each substance is the hazard label on the bottle. W X Y Z Based on the ha
  17. October 2023, AS Unit 3, Q3(a)(i) (1 mark): Complete the table by identifying the hazards. (1)
  18. October 2023, AS Unit 3, Q3(a)(ii) (2 marks): For each compound, state one way in which the risk due to the hazard shown could be reduced when carrying out this preparation. (2) Cyclohexanol Cyclohexene
  19. January 2023, AS Unit 1, Q15 (1 mark): Prop‑2-en‑1‑ol is flammable, toxic and an environmental hazard. Which hazard symbols should be shown on its container? A B C D Use this space for any rough work
  20. October 2022, AS Unit 1, Q17(e)(i) (2 marks): Suggest one advantage and one disadvantage of using liquid carbon dioxide rather than hexane to dissolve the limonene. Assume that the carbon dioxide does not e
  21. October 2022, AS Unit 3, Q3(d) (1 mark): The metal nitrate is toxic. Draw the hazard symbol that should be displayed on the bottle. (1)
  22. June 2022, AS Unit 1, Q13 (1 mark): When carrying out chemical experiments, the hazards and risks must be considered. For a given chemical A the hazard is fixed but the risk varies B the hazard va
  23. January 2022, AS Unit 2, Q23(a)(i) (1 mark): State why the thermal decomposition of magnesium ethanedioate should be carried out in a fume cupboard. (1)
  24. January 2022, AS Unit 3, Q4(b)(i) (2 marks): Identify the main hazard related to chlorine gas, giving the best way of minimising the risk when using this gas. (2)
  25. January 2022, Unit 6, Q4(a) (2 marks): This question is about the preparation of phenylamine by the reduction of nitrobenzene. NH2 NO2 + 6[H] → + 2H2O phenylamine nitrobenzene Outline procedure Step
  26. October 2021, AS Unit 3, Q2(d)(i) (2 marks): Complete the table to identify the hazards indicated by the symbols. (2)
  27. October 2021, AS Unit 3, Q2(d)(ii) (1 mark): State one precaution, other than wearing safety spectacles and a laboratory coat, that should be taken when using pure geraniol to reduce the risk associated wi
  28. June 2021, AS Unit 2, Q22(e)(iii) (1 mark): Suggest a precaution that should be taken when opening a bottle of trichloromethane. (1)
  29. June 2021, AS Unit 2, Q22(e)(iv) (1 mark): Trichloromethane can be used as an anaesthetic. Suggest whether an old bottle of trichloromethane can still be used for medical treatment, giving a reason for y
  30. June 2021, AS Unit 3, Q3(c) (1 mark): Solid samples of soluble barium compounds such as barium oxide are toxic by inhalation due to the presence of barium ions. Give a safety precaution that should
  31. June 2021, AS Unit 3, Q3(d) (1 mark): Barium also forms a peroxide. A bottle of barium peroxide has the hazard symbol Give the meaning of this symbol. (1)
  32. January 2021, AS Unit 1, Q13 (1 mark): A substance is labelled with the hazard symbol shown. What is the meaning of this symbol? A gloves must be worn B corrosive C do not store with flammable substa
  33. January 2021, AS Unit 3, Q4(a)(i) (2 marks): The concentrated hydrochloric acid used in Step 1 was labelled Suggest two safety precautions, other than wearing safety spectacles and a laboratory coat, to mi
  34. October 2020, AS Unit 1, Q19(d)(i) (2 marks): Some of the symbols shown are used for ammonium dichromate(VI). Identify the symbols for ammonium dichromate(VI) by placing a tick () in the box under each rel
  35. October 2020, AS Unit 1, Q19(d)(ii) (1 mark): Suggest why ammonium dichromate(VI) is not stored in the same cupboard as alkanes. (1)
  36. January 2020, AS Unit 1, Q21(c)(ii) (2 marks): One hazard symbol for 1,2-dichloroethane is shown. By identifying this hazard, give one way of minimising the risk when working with 1,2-dichloroethane in a lab

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