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The electrochemical series and disproportionation: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 16.1.5 The electrochemical series and disproportionation, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. Q14(a)(i)

    June 2024 · Unit 5

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  2. Q14(a)(ii)

    June 2024 · Unit 5

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  4. Q16(a)(ii)

    January 2024 · Unit 5

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  10. Q18(a)(i)

    June 2021 · Unit 5

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  12. Q19(c)(i)

    January 2021 · Unit 5

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All 13 questions on The electrochemical series and disproportionation, as a list
  1. June 2024, Unit 5, Q14(a)(i) (1 mark): Name the type of the forward reaction that is shown in the right‑hand electrode systems in the Data Booklet. (1)
  2. June 2024, Unit 5, Q14(a)(ii) (1 mark): Name the series formed when the right‑hand electrode systems are placed in order, most negative first. (1)
  3. January 2024, Unit 5, Q4 (1 mark): Which sequence shows the ions in order of increasing strength as a reducing agent? Refer to your Data Booklet. A V2+ < Fe2+ < Cr2+ B Cr2+ < Fe2+ < V2+ C Cr2+ <
  4. January 2024, Unit 5, Q16(a)(ii) (2 marks): Write an equation for the reaction of H3MnO4 in acidic solution to give ions containing manganese(VI) and manganese(IV). Use the Latimer diagram to obtain the f
  5. January 2024, Unit 5, Q16(a)(iii) (2 marks): Deduce whether or not this disproportionation reaction is thermodynamically feasible by calculating E for the reaction. (2)
  6. October 2023, Unit 5, Q8 (1 mark): Standard electrode potentials can also be given an alternative name. The electrochemical series lists standard electrode potentials in order. Which of these is
  7. June 2023, Unit 5, Q2 (1 mark): Some standard electrode potentials are shown. Right-hand electrode system E / V Mg2+ + 2e–  Mg –2.37 –2.33 Ce3+ + 3e–  Ce Mn2+ + 2e–  Mn –1.19 Mn3+ + e–  Mn
  8. January 2023, Unit 5, Q20(c) (1 mark): Potassium manganate(VI), K2MnO4 , is a green solid. In acidic solution, the manganate(VI) ions disproportionate to form manganate(VII) ions and manganese(IV) ox
  9. October 2021, Unit 5, Q3 (1 mark): Some standard electrode potentials are shown. Electrode system E d / V Bk3+ + e–  Bk2+ –2.80 Cu2+ + e–  Cu+ +0.15 +1.67 Bk4+ + e–  Bk3+ Au+ + e– +1.69  Au A
  10. June 2021, Unit 5, Q18(a)(i) (2 marks): Write the ionic equation for the disproportionation of manganate(VI) ions, MnO4 2−, in acidic conditions, using relevant half-equations from the table. State sy
  11. June 2021, Unit 5, Q18(a)(ii) (2 marks): Calculate O conditions, stating whether or not the reaction is thermodynamically feasible. (2)
  12. January 2021, Unit 5, Q19(c)(i) (1 mark): Write the ionic equation for this disproportionation reaction. State symbols are not required. (1)
  13. January 2021, Unit 5, Q19(c)(ii) (2 marks): Show that the reaction in (c)(i) is thermodynamically feasible. Use the standard electrode potentials of the relevant half-cells from the Data Booklet. (2)

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