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Optical activity and racemic mixtures: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 15.A.2 Optical activity and racemic mixtures, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. The start of question 19

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  2. The start of question 18

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  3. The start of question 10

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  4. The start of question 14

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  6. The start of question 18

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  7. Q17(b)(ii)

    June 2022 · Unit 4

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    The start of question 17

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  8. Q4(b)(ii)

    June 2022 · Unit 6

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  9. The start of question 19

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  10. Q17(a)(ii)

    January 2021 · Unit 4

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All 10 questions on Optical activity and racemic mixtures, as a list
  1. June 2025 (A), Unit 5, Q19(a)(v) (3 marks): Alanine exists as two optical isomers. Explain how this type of isomerism occurs, stating how the isomers may be distinguished. (3)
  2. January 2024, Unit 4, Q18(b)(ii) (3 marks): Explain why the 2‑hydroxypropanoic acid, CH3CH(OH)COOH, produced is not optically active. (3)
  3. January 2024, Unit 5, Q10(c) (1 mark): Which of the esters could rotate the plane of plane‑polarised monochromatic light? (1) A Q only B Q and R C Q, R and S D R and S
  4. October 2023, Unit 4, Q14(b) (2 marks): Explain why the product of the reaction is not optically active even though it contains a chiral carbon atom. (2)
  5. June 2023, Unit 4, Q5 (1 mark): Which pair of compounds can form a racemic mixture when mixed? CH2OH CH2OH A H H C2H5 CH2OH HO H3C CH2OH CH2OH B H H C2H5 C2H5 HO HO CH3 CH3 C H HO C2H4OH CH2OH
  6. January 2023, Unit 4, Q18(a) (6 marks): Explain why lactic acid formed in muscles is optically active while lactic acid obtained using the laboratory synthesis is not. You should define any terms you
  7. June 2022, Unit 4, Q17(b)(ii) (1 mark): Describe how you could distinguish between pure samples of the two optical isomers. (1)
  8. June 2022, Unit 6, Q4(b)(ii) (2 marks): The limonene extracted from orange peel is D‑limonene. State how the presence of a single optical isomer could be confirmed, naming the apparatus used. No exper
  9. June 2021, Unit 4, Q19(a)(ii) (3 marks): A student predicted that the product of Step 1 would rotate the plane of plane-polarised light. Comment on this prediction. (3)
  10. January 2021, Unit 4, Q17(a)(ii) (1 mark): A laboratory sample of lactic acid does not rotate the plane of plane-polarised monochromatic light. Give a reason for this observation. (1)

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