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London forces, dipole-dipole forces and hydrogen bonds: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 7.1.1 London forces, dipole-dipole forces and hydrogen bonds, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. The start of question 23

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  2. The start of question 15

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  4. Q19(a)(ii)

    October 2024 · AS Unit 2

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  10. Q4

    October 2023 · AS Unit 2

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  13. Q20(b)

    June 2023 · AS Unit 2

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  14. Q22(c)(iii)

    June 2023 · AS Unit 2

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  15. The start of question 24

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  16. Q4

    January 2023 · AS Unit 2

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  17. Q5

    January 2023 · AS Unit 2

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  18. Q12

    October 2022 · AS Unit 2

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  19. Q7

    January 2022 · AS Unit 2

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  20. The start of question 24

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All 26 questions on London forces, dipole-dipole forces and hydrogen bonds, as a list
  1. June 2025, AS Unit 1, Q23(b)(v) (2 marks): Ethene and poly(ethene) have different melting temperatures. Molecule Melting temperature (K) ethene 104.1 poly(ethene) 400 Explain why their melting temperatur
  2. June 2025, Unit 4, Q15(b) (3 marks): Butanoic acid is very soluble in water. This is due to strong intermolecular forces between butanoic acid molecules and water molecules. Complete the diagram by
  3. June 2025, Unit 5, Q17(a)(iii) (2 marks): Trimethylamine is a gas at room temperature but readily dissolves in water. Draw a diagram of the intermolecular force that leads to trimethylamine being solubl
  4. October 2024, AS Unit 2, Q19(a)(ii) (1 mark): State why the London forces in hydrogen iodide are stronger than those in hydrogen chloride and hydrogen bromide. (1)
  5. October 2024, Unit 5, Q15(a) (2 marks): Butylamine is miscible with water. Draw a labelled diagram to show one of the intermolecular interactions between a butylamine molecule and a molecule of water.
  6. January 2024, AS Unit 2, Q1 (1 mark): Which compound has intermolecular hydrogen bonding? A HF B H2Te C AsH3 D SnH4
  7. January 2024, AS Unit 2, Q2 (1 mark): In which process are intermolecular hydrogen bonds broken? A H2(g) → 2H(g) B H2O(l) → H2O(g) C H2(l) → H2(g) D H2(g) + ½O2(g) → H2O(g)
  8. January 2024, AS Unit 2, Q3 (1 mark): A compound contains • molecules with non-polar bonds • permanent dipole-permanent dipole forces between its molecules. What could be the formula of this compoun
  9. January 2024, AS Unit 2, Q4 (1 mark): Which alkane has the strongest London forces in the liquid phase? A (CH3)4C B CH3CH2CH2CH2CH3 C (C2H5)4C D CH3(CH2)7CH3
  10. October 2023, AS Unit 2, Q4 (1 mark): Which row in the table shows the forces between the molecules in the liquid state? Permanent dipole‑dipole Molecule London forces Hydrogen bonding interaction A
  11. June 2023, AS Unit 2, Q5 (1 mark): The boiling temperature of hexane is 69 °C and that of cyclohexane is 81 °C. The main reason that cyclohexane has a higher boiling temperature is that cyclohexa
  12. June 2023, AS Unit 2, Q7 (1 mark): Hydrogen bonds are formed when methanol dissolves in water. Which structure best represents a hydrogen bond between methanol and water? H H O : A H C H O H H H
  13. June 2023, AS Unit 2, Q20(b) (6 marks): Two alternatives to hydrocarbon fuels are hydrogen and ammonia. Hydrogen burns to form water as the only product but hydrogen is extremely hard to liquefy. Ammo
  14. June 2023, AS Unit 2, Q22(c)(iii) (2 marks): Commercial disinfectants are often made more viscous by adding propane‑1,2,3‑triol to the aqueous solution. Suggest how propane-1,2,3-triol makes disinfectants
  15. June 2023, Unit 5, Q24(a)(ii) (3 marks): Explain why PAM is able to absorb large amounts of water. Include a diagram in your answer. (3)
  16. January 2023, AS Unit 2, Q4 (1 mark): Which compound has London forces as the only intermolecular force? A HF B OF2 C PF3 D CF4 Use this space for any rough working. Anything you write in this space
  17. January 2023, AS Unit 2, Q5 (1 mark): Which compound has intermolecular hydrogen bonding? A (CH3)3N B (CH3)3CF C (CH3)3COH D (CH3)3CCHO
  18. October 2022, AS Unit 2, Q12 (1 mark): Which compound does not form hydrogen bonds between its molecules? A HCl B H2O C HF D NH3
  19. January 2022, AS Unit 2, Q7 (1 mark): Which intermolecular forces exist between the molecules of the compound shown? HO O A hydrogen bonding and London forces only B hydrogen bonding and permanent d
  20. January 2022, AS Unit 2, Q24(a) (3 marks): Urea has a melting temperature of 133 °C. Explain why this value is higher than expected for a relatively small molecule. (3)
  21. October 2021, AS Unit 2, Q22(d)(i) (1 mark): Give a possible reason why ethanol is able to absorb water. (1)
  22. October 2021, Unit 4, Q11 (1 mark): Ethanal and propane have the same molar mass but ethanal has a much higher boiling temperature. Ethanal is fully miscible in water but propane is almost insolub
  23. June 2021, AS Unit 2, Q20(a) (6 marks): Some data for three small molecules are shown. Boiling temperature Molecule Mr / °C Fluorine 38.0 −188 Hydrogen chloride 36.5 −85 Methanol 32.0 65 Explain the l
  24. June 2021, Unit 5, Q11 (1 mark): Hydrogen bonds are formed when methylamine dissolves in water. Which structure best represents a hydrogen bond between methylamine and water? H H O A H C N H H
  25. January 2021, AS Unit 2, Q3 (1 mark): Which of these pure compounds has hydrogen bonding in the liquid state? A 1,1,1-trichloroethane, CH3CCl3 B trimethylamine, (CH3)3N C hydrogen fluoride, HF D hyd
  26. June 2019, AS Unit 2, Q16(b) (1 mark): Which diagram best represents a hydrogen bond between two water molecules? (1) 180° O H H H A O H 180° O H H H B O H H 104.5° C O O H H H 104.5° H O H D H O H

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