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Homogeneous catalysts and autocatalysis: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 17.3.2 Homogeneous catalysts and autocatalysis, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. Q9

    June 2025 (A) · Unit 5

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  2. Q4(a)

    October 2024 · Unit 5

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  3. Q4(b)

    October 2024 · Unit 5

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  4. Q14

    October 2024 · Unit 5

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  5. Q3(a)(iv)

    October 2024 · Unit 6

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  6. The start of question 3

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  7. Q3(b)(ii)

    June 2024 · Unit 6

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  8. Q3(b)(iii)

    June 2024 · Unit 6

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  9. Q6

    October 2023 · Unit 5

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  10. Q19(b)(i)

    October 2023 · Unit 5

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  11. Q19(b)(ii)

    October 2023 · Unit 5

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  12. Q7

    January 2023 · Unit 5

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  13. Q20(d)

    January 2023 · Unit 5

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  14. Q9

    October 2022 · Unit 5

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  15. The start of question 1

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  16. Q1(b)

    June 2022 · Unit 5

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  17. Q9

    October 2021 · Unit 5

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  18. Q10

    October 2021 · Unit 5

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  19. Q21(e)(i)

    June 2021 · Unit 5

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  20. Q21(e)(ii)

    June 2021 · Unit 5

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All 23 questions on Homogeneous catalysts and autocatalysis, as a list
  1. June 2025 (A), Unit 5, Q9 (1 mark): 2– , is mixed with 9 An acidified solution, containing tartrate ions, C4H4O6 hydrogen peroxide solution. When pink cobalt(II) chloride solution is added to the
  2. October 2024, Unit 5, Q4(a) (1 mark): What is the best explanation for the high activation energy of this reaction? (1) A the peroxodisulfate ion is a weak oxidising agent B the iodide ion is a weak
  3. October 2024, Unit 5, Q4(b) (1 mark): Which property of iron(II) ions enables them to function as a catalyst for this reaction? (1) A iron(II) ions can be easily reduced to metallic iron B iron(II)
  4. October 2024, Unit 5, Q14 (1 mark): The formation of carbon dioxide from the reaction between manganate(VII) ions and ethanedioate ions is autocatalysed by manganese(II) ions. The equation for thi
  5. October 2024, Unit 6, Q3(a)(iv) (3 marks): Suggest why, in Step 2, the temperature of the mixture at the start should be 60°C but no further warming is needed after a small quantity of the potassium mang
  6. June 2024, Unit 6, Q3(b)(i) (3 marks): Plot a graph of volume of sodium thiosulfate against time. (3)
  7. June 2024, Unit 6, Q3(b)(ii) (1 mark): Describe how the rate of reaction changes during the reaction. (1)
  8. June 2024, Unit 6, Q3(b)(iii) (3 marks): Explain why the rate of reaction changes in this way. (3)
  9. October 2023, Unit 5, Q6 (1 mark): Acidified manganate(VII) ions react with ethanedioate ions. 2− → 2Mn2+ + 8H2O + 10CO2 2MnO4 − + 16H+ + 5C2O4 The rate of this reaction increases then decreases.
  10. October 2023, Unit 5, Q19(b)(i) (1 mark): Give a reason why the activation energy for this reaction is high in the absence of a catalyst. (1)
  11. October 2023, Unit 5, Q19(b)(ii) (2 marks): Write the ionic equations for the reactions that occur when the catalyst of Fe2+ ions is added. State symbols are not required. (2)
  12. January 2023, Unit 5, Q7 (1 mark): Persulfate ions react slowly with iodide ions at room temperature unless a catalyst of Fe2+ or Fe3+ is added to the reaction mixture. 2–(aq) + 2I–(aq) → 2SO4 2–
  13. January 2023, Unit 5, Q20(d) (3 marks): Manganate(VII) ions react with ethanedioate ions in acidic solution. 2MnO4 –(aq) + 16H+(aq) + 5C2O4 2–(aq) → 2Mn2+(aq) + 8H2O(l) + 10CO2(g) Two experiments were
  14. October 2022, Unit 5, Q9 (1 mark): The sequence shown is the mechanism for a reaction in aqueous solution. Step 1 Ag+ + Ce4+ → Ag2+ + Ce3+ Step 2 Ti+ + Ag2+ → Ti2+ + Ag+ Step 3 Ti2+ + Ce4+ → Ti3+
  15. June 2022, Unit 5, Q1(a) (1 mark): Some standard electrode potentials are shown. Right-hand electrode system E / V Cu2+ + e−  Cu+ +0.15 I2 + 2e−  2I− +0.54 Fe3+ + e−  Fe2+ +0.77 Cl2 + 2e−  2C
  16. June 2022, Unit 5, Q1(b) (1 mark): Which term best describes the type of catalyst for the reaction in (a)? (1) A autocatalyst B biocatalyst C heterogeneous D homogeneous
  17. October 2021, Unit 5, Q9 (1 mark): The reaction of ethanedioate ions, C2O 4 2– , with manganate(VII) ions, MnO 4 – , in acidic solution involves autocatalysis. 2– → 2Mn2+ + 10CO2 + 8H2O 2MnO 4 –
  18. October 2021, Unit 5, Q10 (1 mark): Iodide ions, I–, are oxidised by peroxodisulfate(VI) ions, S2O 8 2– . 2I–(aq) + S2O 8 2–(aq) → I2(aq) + 2SO 4 2–(aq) Which of the following statements is true o
  19. June 2021, Unit 5, Q21(e)(i) (1 mark): State why the catalyst is described as ‘homogeneous’. (1)
  20. June 2021, Unit 5, Q21(e)(ii) (2 marks): Write two equations to show how iron(II) ions catalyse this oxidation. State symbols are not required. (2)
  21. June 2021, Unit 5, Q21(e)(iii) (1 mark): Suggest how iron(II) ions lower the activation energy of this reaction. (1)
  22. January 2021, Unit 5, Q9 (1 mark): Iodide ions are oxidised by peroxodisulfate ions in aqueous solution. 2I− + S2O2− → I2 + 2SO2− 8 4 This reaction is catalysed by adding Fe2+ ions to the solutio
  23. October 2020, Unit 5, Q24(c) (6 marks): Transition metals, their compounds and their ions can act as heterogeneous and homogeneous catalysts. Compare and contrast these two types of catalytic behaviou

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