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Grignard reagents and lengthening carbon chains: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 20.1.2 Grignard reagents and lengthening carbon chains, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. Q18(e)

    June 2025 (A) · Unit 5

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  2. Q18(f)

    June 2025 (A) · Unit 5

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  3. Q19

    January 2025 · Unit 5

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  5. Q12(a)

    June 2024 · Unit 5

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  6. Q12(b)

    June 2024 · Unit 5

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  8. The start of question 20

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  10. Q12(a)

    January 2023 · Unit 5

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  11. Q12(b)

    January 2023 · Unit 5

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  12. Q9(a)

    June 2022 · Unit 5

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  13. Q9(c)

    June 2022 · Unit 5

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  14. Q9(d)

    June 2022 · Unit 5

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  16. Q16

    October 2021 · Unit 5

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  18. Q11

    October 2020 · Unit 5

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All 18 questions on Grignard reagents and lengthening carbon chains, as a list
  1. June 2025 (A), Unit 5, Q18(e) (1 mark): Name the type of reagent used in Step 5. (1)
  2. June 2025 (A), Unit 5, Q18(f) (1 mark): Draw a possible structure of K that could be formed in Step 5. (1)
  3. January 2025, Unit 5, Q19 (6 marks): Grignard reagents are used to increase the length of the carbon chain in organic molecules. An outline synthesis of propanoic acid from ethanoic acid is shown.
  4. October 2024, Unit 5, Q19(c) (7 marks): Raspberry ketone can also be synthesised in the laboratory using a Grignard reagent via a multi-step process. The overall reaction is shown. OH O HO HO Devise t
  5. June 2024, Unit 5, Q12(a) (1 mark): Which metal is involved in the formation of a Grignard reagent? (1) A chromium B copper C magnesium D manganese
  6. June 2024, Unit 5, Q12(b) (1 mark): What best describes the role of a Grignard reagent in increasing the length of a carbon chain? (1) A reducing agent B oxidising agent C nucleophile D electrophi
  7. January 2024, Unit 5, Q15(b) (7 marks): Cooking fresh ginger converts gingerol into zingerone, which is less pungent and has a sweeter flavour. Zingerone can be formed in a four‑step synthesis from co
  8. October 2023, Unit 5, Q20(b) (7 marks): Devise a synthesis to convert bromobenzene into benzamide. Include reagents, conditions and the structures of the intermediate compounds. O Br C NH2 bromobenzen
  9. June 2023, Unit 5, Q20 (1 mark): Which carbonyl compound and Grignard reagent would not react to form compound Y? OH compound Y Carbonyl compound Grignard reagent O BrMg A O B BrMg O C BrMgCH3
  10. January 2023, Unit 5, Q12(a) (1 mark): What type of reaction occurs with a Grignard reagent? (1) A electrophilic addition B free radical substitution C oxidation D nucleophilic addition
  11. January 2023, Unit 5, Q12(b) (1 mark): Benzaldehyde reacts with a Grignard reagent, followed by hydrolysis, to form 2-methyl-1-phenylbutan-1-ol. OH CH3 H H O C C C C C H H H H H H What is the formula
  12. June 2022, Unit 5, Q9(a) (1 mark): Which solvent is used in this preparation? (1) A ethanol B ether C pentane D propanone
  13. June 2022, Unit 5, Q9(c) (1 mark): The structure of 2-methylpropylmagnesium bromide is shown. MgBr Which statement best describes the circled carbon atom? (1) A positive and electrophilic B posit
  14. June 2022, Unit 5, Q9(d) (1 mark): Which compound reacts with 2‑methylpropylmagnesium bromide to form 4‑ethyl‑2‑methylheptan‑4‑ol? OH MgBr 2‑methylpropylmagnesium bromide 4‑ethyl‑2‑methylheptan‑4
  15. January 2022, Unit 5, Q16(a) (6 marks): Devise a reaction scheme to produce benzoic acid from benzene, via bromobenzene and then a Grignard reagent. Include the reagents and essential conditions for e
  16. October 2021, Unit 5, Q16 (1 mark): Grignard reagents react with A water giving primary alcohols B all aldehydes giving secondary alcohols C ketones giving secondary or tertiary alcohols D carbon
  17. January 2021, Unit 5, Q20(c) (5 marks): Devise a reaction scheme to prepare 2-methylbut-2-ene from butanone, using no more than four steps. Identify the reagents and essential conditions for each step
  18. October 2020, Unit 5, Q11 (1 mark): Which organic compound reacts with a Grignard reagent to give a product that forms a secondary alcohol on hydrolysis? A carbon dioxide B ethanal C methanal D pr

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