Grignard reagents and lengthening carbon chains: Edexcel International A Level Chemistry questions
Edexcel International A Level Chemistry past-paper questions on 20.1.2 Grignard reagents and lengthening carbon chains, 2019–2025, with mark schemes and examiner’s reports where available.
Paper
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Calculations
Q18(e)
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Q18(f)
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Q19(c)
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Q12(a)
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Your answerQ12(b)
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Your answerQ15(b)
The whole paper ↗Q20(b)
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- Your answer
Q12(a)
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Your answerQ12(b)
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Your answerQ9(a)
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Your answerQ9(c)
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Your answerQ9(d)
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Your answerQ16(a)
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- Your answer
Q20(c)
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- Your answer
All 18 questions on Grignard reagents and lengthening carbon chains, as a list
- June 2025 (A), Unit 5, Q18(e) (1 mark): Name the type of reagent used in Step 5. (1)
- June 2025 (A), Unit 5, Q18(f) (1 mark): Draw a possible structure of K that could be formed in Step 5. (1)
- January 2025, Unit 5, Q19 (6 marks): Grignard reagents are used to increase the length of the carbon chain in organic molecules. An outline synthesis of propanoic acid from ethanoic acid is shown.
- October 2024, Unit 5, Q19(c) (7 marks): Raspberry ketone can also be synthesised in the laboratory using a Grignard reagent via a multi-step process. The overall reaction is shown. OH O HO HO Devise t
- June 2024, Unit 5, Q12(a) (1 mark): Which metal is involved in the formation of a Grignard reagent? (1) A chromium B copper C magnesium D manganese
- June 2024, Unit 5, Q12(b) (1 mark): What best describes the role of a Grignard reagent in increasing the length of a carbon chain? (1) A reducing agent B oxidising agent C nucleophile D electrophi
- January 2024, Unit 5, Q15(b) (7 marks): Cooking fresh ginger converts gingerol into zingerone, which is less pungent and has a sweeter flavour. Zingerone can be formed in a four‑step synthesis from co
- October 2023, Unit 5, Q20(b) (7 marks): Devise a synthesis to convert bromobenzene into benzamide. Include reagents, conditions and the structures of the intermediate compounds. O Br C NH2 bromobenzen
- June 2023, Unit 5, Q20 (1 mark): Which carbonyl compound and Grignard reagent would not react to form compound Y? OH compound Y Carbonyl compound Grignard reagent O BrMg A O B BrMg O C BrMgCH3
- January 2023, Unit 5, Q12(a) (1 mark): What type of reaction occurs with a Grignard reagent? (1) A electrophilic addition B free radical substitution C oxidation D nucleophilic addition
- January 2023, Unit 5, Q12(b) (1 mark): Benzaldehyde reacts with a Grignard reagent, followed by hydrolysis, to form 2-methyl-1-phenylbutan-1-ol. OH CH3 H H O C C C C C H H H H H H What is the formula
- June 2022, Unit 5, Q9(a) (1 mark): Which solvent is used in this preparation? (1) A ethanol B ether C pentane D propanone
- June 2022, Unit 5, Q9(c) (1 mark): The structure of 2-methylpropylmagnesium bromide is shown. MgBr Which statement best describes the circled carbon atom? (1) A positive and electrophilic B posit
- June 2022, Unit 5, Q9(d) (1 mark): Which compound reacts with 2‑methylpropylmagnesium bromide to form 4‑ethyl‑2‑methylheptan‑4‑ol? OH MgBr 2‑methylpropylmagnesium bromide 4‑ethyl‑2‑methylheptan‑4
- January 2022, Unit 5, Q16(a) (6 marks): Devise a reaction scheme to produce benzoic acid from benzene, via bromobenzene and then a Grignard reagent. Include the reagents and essential conditions for e
- October 2021, Unit 5, Q16 (1 mark): Grignard reagents react with A water giving primary alcohols B all aldehydes giving secondary alcohols C ketones giving secondary or tertiary alcohols D carbon
- January 2021, Unit 5, Q20(c) (5 marks): Devise a reaction scheme to prepare 2-methylbut-2-ene from butanone, using no more than four steps. Identify the reagents and essential conditions for each step
- October 2020, Unit 5, Q11 (1 mark): Which organic compound reacts with a Grignard reagent to give a product that forms a secondary alcohol on hydrolysis? A carbon dioxide B ethanal C methanal D pr
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