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Lattice energy: Edexcel A‑Level Chemistry questions

Every Edexcel A-Level Chemistry exam question on 13A Lattice energy, 2016–2025, with its mark scheme and examiner’s report.

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2,028 questions

  1. Q7(a)

    June 2025 · Paper 1

    The whole paper ↗
    June 2025 Paper 1, question 7(a): Which statement defines the lattice energy of an ionic solid? (1) A the energy absorbed when 1 mol of an ionic substance is formed from its gaseous ions B the e
  2. Q7(b)

    June 2025 · Paper 1

    The whole paper ↗
    June 2025 Paper 1, question 7(b): Which substance has the lattice energy with the most exothermic value? (1) A NaCl B NaI C KCl D KI
  3. Q7(c)

    June 2025 · Paper 1

    The whole paper ↗
    June 2025 Paper 1, question 7(c): Which ionic solid would have the greatest difference between the theoretical and experimental lattice energies? (1) A NaCl B NaI C KCl D KI
  4. Q2(a)

    June 2024 · Paper 1

    The whole paper ↗
    June 2024 Paper 1, question 2(a): Explain the trend in the values of the first electron affinities of the elements shown. (4) First electron affinity / kJ mol−1 Element chlorine −349 bromine −32
  5. Q8(b)

    June 2024 · Paper 1

    The whole paper ↗
    June 2024 Paper 1, question 8(b): Which definition correctly describes the enthalpy change of solution, ΔsolH ? (1) Enthalpy change of solution, ΔsolH The enthalpy change when 1 mol of gaseous i
  6. Q8(c)(i)

    June 2024 · Paper 1

    The whole paper ↗
    June 2024 Paper 1, question 8(c)(i): Complete the Born–Haber cycle for magnesium fluoride with formulae, state symbols, electrons and correctly labelled arrows. The cycle is not drawn to scale. (4)
  7. Q8(c)(ii)

    June 2024 · Paper 1

    The whole paper ↗
    June 2024 Paper 1, question 8(c)(ii): Calculate the value of ΔfH [MgF2(s)]. (1)
  8. Q8(c)(iii)

    June 2024 · Paper 1

    The whole paper ↗
    June 2024 Paper 1, question 8(c)(iii): The experimental and theoretical values of the lattice energy for MgF2 and MgI2 are given in the table. Explain the differences in these values. (4) Experimenta
  9. Q9(a)(i)

    June 2023 · Paper 1

    The whole paper ↗
    June 2023 Paper 1, question 9(a)(i): Complete the diagram by adding appropriate species and state symbols to the empty boxes. (2)
  10. Q9(a)(ii)

    June 2023 · Paper 1

    The whole paper ↗
    June 2023 Paper 1, question 9(a)(ii): Explain why the value for the first electron affinity of oxygen is negative and the value for the second electron affinity is positive. (3)
  11. Q9(a)(iii)

    June 2023 · Paper 1

    The whole paper ↗
    June 2023 Paper 1, question 9(a)(iii): Calculate a value for the standard enthalpy change of atomisation of silver, ΔatH d, using the Born–Haber cycle. (3)
  12. Q9(b)(i)

    June 2023 · Paper 1

    The whole paper ↗
    June 2023 Paper 1, question 9(b)(i): Give two assumptions used in the model to calculate the theoretical lattice energy. (2)
  13. Q9(b)(ii)

    June 2023 · Paper 1

    The whole paper ↗
    June 2023 Paper 1, question 9(b)(ii): Explain the difference in the two values for the lattice energy of silver chloride by considering the possible bonding models. (3)
  14. Q4(c)

    June 2023 · Paper 3

    The whole paper ↗
    June 2023 Paper 3, question 4(c): Explain how the enthalpy change of hydration of magnesium ions in magnesium sulfate is different from the enthalpy change of hydration of calcium ions in calciu
  15. Q5(c)(i)

    June 2022 · Paper 1

    The whole paper ↗
    June 2022 Paper 1, question 5(c)(i): Name the two properties of ions that affect the value of their enthalpy change of hydration. (2)
  16. Q5(c)(ii)

    June 2022 · Paper 1

    The whole paper ↗
    June 2022 Paper 1, question 5(c)(ii): Calculate the enthalpy change of hydration for chloride ions by completing the energy cycle, including labels, and using the data in the table. (3) ΔsolnH KCl(s
  17. Q9(a)(i)

    November 2021 · Paper 1

    The whole paper ↗
    November 2021 Paper 1, question 9(a)(i): State what can be deduced by the close similarity of the lattice energy values for barium iodide. (1)
  18. Q9(a)(ii)

    November 2021 · Paper 1

    The whole paper ↗
    November 2021 Paper 1, question 9(a)(ii): Explain why there is a significant difference in the lattice energy values for magnesium iodide. (4)
  19. Q9(b)(i)

    November 2021 · Paper 1

    The whole paper ↗
    November 2021 Paper 1, question 9(b)(i): Complete the diagram of the Born‑Haber cycle for copper(II) oxide. Include labels of enthalpy changes with arrows indicating the direction of change, and the re
  20. Q9(b)(ii)

    November 2021 · Paper 1

    The whole paper ↗
    November 2021 Paper 1, question 9(b)(ii): Calculate the lattice energy of copper(II) oxide. (1)
All 31 questions on Lattice energy, as a list
  1. June 2025, Paper 1, Q7(a) (1 mark): Which statement defines the lattice energy of an ionic solid? (1) A the energy absorbed when 1 mol of an ionic substance is formed from its gaseous ions B the e
  2. June 2025, Paper 1, Q7(b) (1 mark): Which substance has the lattice energy with the most exothermic value? (1) A NaCl B NaI C KCl D KI
  3. June 2025, Paper 1, Q7(c) (1 mark): Which ionic solid would have the greatest difference between the theoretical and experimental lattice energies? (1) A NaCl B NaI C KCl D KI
  4. June 2024, Paper 1, Q2(a) (4 marks): Explain the trend in the values of the first electron affinities of the elements shown. (4) First electron affinity / kJ mol−1 Element chlorine −349 bromine −32
  5. June 2024, Paper 1, Q8(b) (1 mark): Which definition correctly describes the enthalpy change of solution, ΔsolH ? (1) Enthalpy change of solution, ΔsolH The enthalpy change when 1 mol of gaseous i
  6. June 2024, Paper 1, Q8(c)(i) (4 marks): Complete the Born–Haber cycle for magnesium fluoride with formulae, state symbols, electrons and correctly labelled arrows. The cycle is not drawn to scale. (4)
  7. June 2024, Paper 1, Q8(c)(ii) (1 mark): Calculate the value of ΔfH [MgF2(s)]. (1)
  8. June 2024, Paper 1, Q8(c)(iii) (4 marks): The experimental and theoretical values of the lattice energy for MgF2 and MgI2 are given in the table. Explain the differences in these values. (4) Experimenta
  9. June 2023, Paper 1, Q9(a)(i) (2 marks): Complete the diagram by adding appropriate species and state symbols to the empty boxes. (2)
  10. June 2023, Paper 1, Q9(a)(ii) (3 marks): Explain why the value for the first electron affinity of oxygen is negative and the value for the second electron affinity is positive. (3)
  11. June 2023, Paper 1, Q9(a)(iii) (3 marks): Calculate a value for the standard enthalpy change of atomisation of silver, ΔatH d, using the Born–Haber cycle. (3)
  12. June 2023, Paper 1, Q9(b)(i) (2 marks): Give two assumptions used in the model to calculate the theoretical lattice energy. (2)
  13. June 2023, Paper 1, Q9(b)(ii) (3 marks): Explain the difference in the two values for the lattice energy of silver chloride by considering the possible bonding models. (3)
  14. June 2023, Paper 3, Q4(c) (2 marks): Explain how the enthalpy change of hydration of magnesium ions in magnesium sulfate is different from the enthalpy change of hydration of calcium ions in calciu
  15. June 2022, Paper 1, Q5(c)(i) (2 marks): Name the two properties of ions that affect the value of their enthalpy change of hydration. (2)
  16. June 2022, Paper 1, Q5(c)(ii) (3 marks): Calculate the enthalpy change of hydration for chloride ions by completing the energy cycle, including labels, and using the data in the table. (3) ΔsolnH KCl(s
  17. November 2021, Paper 1, Q9(a)(i) (1 mark): State what can be deduced by the close similarity of the lattice energy values for barium iodide. (1)
  18. November 2021, Paper 1, Q9(a)(ii) (4 marks): Explain why there is a significant difference in the lattice energy values for magnesium iodide. (4)
  19. November 2021, Paper 1, Q9(b)(i) (4 marks): Complete the diagram of the Born‑Haber cycle for copper(II) oxide. Include labels of enthalpy changes with arrows indicating the direction of change, and the re
  20. November 2021, Paper 1, Q9(b)(ii) (1 mark): Calculate the lattice energy of copper(II) oxide. (1)
  21. November 2021, Paper 1, Q9(c) (2 marks): A different energy cycle can be used to calculate lattice energy. Ca2+(g) + 2Br–(g) CaBr2(s) Ca2+(aq) + 2Br–(aq) Value / kJ mol–1 Enthalpy change enthalpy chang
  22. November 2021, Paper 3, Q1(c) (2 marks): Write the equation for the first electron affinity of chlorine. Include state symbols. (2)
  23. October 2020, Paper 1, Q4(b) (1 mark): What is the value, in kJ mol−1, for the standard enthalpy change of solution of magnesium chloride? Mg2+(g) + 2Cl−(g) MgCl2(s) Mg2+(aq) + 2Cl−(aq) = −2526 kJ mo
  24. June 2019, Paper 1, Q8(a)(i) (2 marks): Identify and correct the two errors in this Born-Haber cycle. (2)
  25. June 2019, Paper 1, Q8(a)(ii) (1 mark): Calculate the first electron affinity, in kJ mol–1, of hydrogen, using the values given in the cycle. (1)
  26. June 2019, Paper 1, Q8(d) (1 mark): Lattice energies provide an indication of ionic bond strength. Which are the lattice energies of the hydrides NaH, KH and MgH2? (1) Lattice energy / kJ mol–1 So
  27. June 2018, Paper 1, Q6(b)(iii) (2 marks): Calculate the enthalpy change of solution of magnesium hydroxide, using the following data. Energy or enthalpy change Value / kJ mol−1 Lattice energy of Mg(OH)2
  28. June 2018, Paper 1, Q8(b) (1 mark): The diagram, which is not drawn to scale, shows the Born-Haber cycle for lithium fluoride. The energy changes are given in kJ mol−1. Li+(g) + F(g) + e− +79 Y Li
  29. June 2018, Paper 1, Q8(c) (6 marks): The table shows the theoretical and experimental lattice energy values of two compounds. Theoretical lattice energy Experimental lattice energy Compound / kJ mo
  30. June 2017, Paper 1, Q6(b)(i) (3 marks): Complete the Born-Haber cycle for magnesium bromide with formulae, electrons and labelled arrows. The cycle is not drawn to scale. (3) Mg(g) + Br2(l) ¨atH [Mg(s
  31. June 2017, Paper 1, Q6(b)(ii) (2 marks): Calculate the first electron affinity of bromine, in kJ mol–1. (2)

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