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Bonding: Edexcel A‑Level Chemistry questions

Every Edexcel A-Level Chemistry exam question on 2A Bonding, 2016–2025, with its mark scheme and examiner’s report.

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2,028 questions

  1. Q2(e)

    June 2025 · Paper 1

    The whole paper ↗
    June 2025 Paper 1, question 2(e): Which of these isoelectronic ions has the largest ionic radius? (1) A S2– B Cl– C K+ D Ca2+
  2. Q2(f)

    June 2025 · Paper 1

    6 marks2A Bonding
    The whole paper ↗
    June 2025 Paper 1, question 2(f): Discuss the reasons for the differences between the boiling temperatures of the compounds in the table. Refer to intermolecular forces in your answer. Detailed
  3. Q2(a)

    June 2025 · Paper 2

    The whole paper ↗
    June 2025 Paper 2, question 2(a): Which of these isomers, with the formula C8H18, will have the lowest boiling temperature? (1) A (CH3)2CHCH2C(CH3)3 B (CH3)2CHCH2CH(CH3)CH2CH3 C CH3CH2CH2C(CH3)2
  4. Q2(b)

    June 2025 · Paper 2

    2 marks2A Bonding
    The whole paper ↗
    June 2025 Paper 2, question 2(b): Pentan‑1‑ol and hexane have the same number of electrons but pentan‑1‑ol is much less volatile than hexane. Explain this difference in volatility. (2)
  5. Q2(c)

    June 2025 · Paper 2

    The whole paper ↗
    June 2025 Paper 2, question 2(c): Iodine is a solid at room temperature but on gentle heating it vaporises. What bonds or forces are being broken? (1) A covalent bonds B ionic bonds C London for
  6. Q2(d)

    June 2025 · Paper 2

    4 marks2A Bonding
    The whole paper ↗
    June 2025 Paper 2, question 2(d): The boiling temperature of boron trichloride is 13 °C while that of phosphorus trichloride is 76 °C. Explain, in terms of the shapes of the molecules, why phosp
  7. Q4(b)

    June 2025 · Paper 2

    2 marks2A Bonding
    The whole paper ↗
    June 2025 Paper 2, question 4(b): Water molecules can undergo either heterolytic fission to form a hydroxide ion or homolytic fission to form a hydroxyl radical. Draw dot‑and‑cross diagrams of t
  8. Q8(f)

    June 2025 · Paper 2

    3 marks2A Bonding
    The whole paper ↗
    June 2025 Paper 2, question 8(f): Anethole is also present in some alcoholic drinks such as the Greek liquor, ouzo. The anethole is responsible for the so‑called ‘ouzo effect’. This effect is th
  9. Q2(d)(iii)

    June 2025 · Paper 3

    3 marks2A Bonding
    The whole paper ↗
    June 2025 Paper 3, question 2(d)(iii): Explain the expected solubilities in water of bombykol and prop-2-en-1-ol. (3)
  10. Q1(a)

    June 2025 · AS Paper 1

    The whole paper ↗
    June 2025 AS Paper 1, question 1(a): The definition of electronegativity is the ability of an atom to attract (1) A a single bonding electron from a covalent bond B a pair of electrons from a coval
  11. Q1(b)

    June 2025 · AS Paper 1

    2 marks2A Bonding
    The whole paper ↗
    June 2025 AS Paper 1, question 1(b): Draw a dot-and-cross diagram of silicon tetrachloride, showing outer shells of electrons only. Use crosses (×) for silicon electrons and dots (• ) for chlorine
  12. Q1(c)

    June 2025 · AS Paper 1

    3 marks2A Bonding
    The whole paper ↗
    June 2025 AS Paper 1, question 1(c): Explain, using electronegativity values, why both chlorine and silicon tetrachloride are non-polar molecules. (3)
  13. Q1(d)

    June 2025 · AS Paper 1

    2 marks2A Bonding
    The whole paper ↗
    June 2025 AS Paper 1, question 1(d): Explain why the boiling temperature of chlorine (−34 °C) is lower than that of silicon tetrachloride (57 °C). (2)
  14. Q2(a)(ii)

    June 2025 · AS Paper 1

    2 marks2A Bonding
    The whole paper ↗
    June 2025 AS Paper 1, question 2(a)(ii): Describe what holds the ions together in sodium metal and in sodium chloride. (2) Sodium metal Sodium chloride
  15. Q2(b)(iii)

    June 2025 · AS Paper 1

    2 marks2A Bonding
    The whole paper ↗
    June 2025 AS Paper 1, question 2(b)(iii): H → Al represents one of the bonds in AlH4 – . State the name of this type of bond and how the bond forms in this ion. (2)
  16. Q2(b)(iv)

    June 2025 · AS Paper 1

    The whole paper ↗
    June 2025 AS Paper 1, question 2(b)(iv): What are the shapes of the aluminium chloride molecule and the tetrahydridoaluminate(III) ion? (1) – Name of shape of AlCl3 Diagram of shape of AlH4 – H H A tri
  17. Q3(a)

    June 2025 · AS Paper 1

    The whole paper ↗
    June 2025 AS Paper 1, question 3(a): What are the intermolecular forces between water molecules? (1) A hydrogen bonds only B London forces and permanent dipoles only C London forces, permanent dipo
  18. Q3(b)

    June 2025 · AS Paper 1

    The whole paper ↗
    June 2025 AS Paper 1, question 3(b): Ethanol, CH3CH2OH, is soluble in water but ethanethiol, CH3CH2SH, is almost insoluble. The best explanation for the difference in solubility is that (1) A ethan
  19. Q7(c)

    June 2025 · AS Paper 1

    The whole paper ↗
    June 2025 AS Paper 1, question 7(c): Which isoelectronic ion has the smallest ionic radius? (1) A F– B Mg2+ C Na+ D O2–
  20. Q4(c)(i)

    June 2025 · AS Paper 2

    2 marks2A Bonding
    The whole paper ↗
    June 2025 AS Paper 2, question 4(c)(i): As the number of carbon atoms increases in the homologous series of unbranched primary alcohols, the state at room temperature changes from liquid to solid. Exp
All 142 questions on Bonding, as a list
  1. June 2025, Paper 1, Q2(e) (1 mark): Which of these isoelectronic ions has the largest ionic radius? (1) A S2– B Cl– C K+ D Ca2+
  2. June 2025, Paper 1, Q2(f) (6 marks): Discuss the reasons for the differences between the boiling temperatures of the compounds in the table. Refer to intermolecular forces in your answer. Detailed
  3. June 2025, Paper 2, Q2(a) (1 mark): Which of these isomers, with the formula C8H18, will have the lowest boiling temperature? (1) A (CH3)2CHCH2C(CH3)3 B (CH3)2CHCH2CH(CH3)CH2CH3 C CH3CH2CH2C(CH3)2
  4. June 2025, Paper 2, Q2(b) (2 marks): Pentan‑1‑ol and hexane have the same number of electrons but pentan‑1‑ol is much less volatile than hexane. Explain this difference in volatility. (2)
  5. June 2025, Paper 2, Q2(c) (1 mark): Iodine is a solid at room temperature but on gentle heating it vaporises. What bonds or forces are being broken? (1) A covalent bonds B ionic bonds C London for
  6. June 2025, Paper 2, Q2(d) (4 marks): The boiling temperature of boron trichloride is 13 °C while that of phosphorus trichloride is 76 °C. Explain, in terms of the shapes of the molecules, why phosp
  7. June 2025, Paper 2, Q4(b) (2 marks): Water molecules can undergo either heterolytic fission to form a hydroxide ion or homolytic fission to form a hydroxyl radical. Draw dot‑and‑cross diagrams of t
  8. June 2025, Paper 2, Q8(f) (3 marks): Anethole is also present in some alcoholic drinks such as the Greek liquor, ouzo. The anethole is responsible for the so‑called ‘ouzo effect’. This effect is th
  9. June 2025, Paper 3, Q2(d)(iii) (3 marks): Explain the expected solubilities in water of bombykol and prop-2-en-1-ol. (3)
  10. June 2025, AS Paper 1, Q1(a) (1 mark): The definition of electronegativity is the ability of an atom to attract (1) A a single bonding electron from a covalent bond B a pair of electrons from a coval
  11. June 2025, AS Paper 1, Q1(b) (2 marks): Draw a dot-and-cross diagram of silicon tetrachloride, showing outer shells of electrons only. Use crosses (×) for silicon electrons and dots (• ) for chlorine
  12. June 2025, AS Paper 1, Q1(c) (3 marks): Explain, using electronegativity values, why both chlorine and silicon tetrachloride are non-polar molecules. (3)
  13. June 2025, AS Paper 1, Q1(d) (2 marks): Explain why the boiling temperature of chlorine (−34 °C) is lower than that of silicon tetrachloride (57 °C). (2)
  14. June 2025, AS Paper 1, Q2(a)(ii) (2 marks): Describe what holds the ions together in sodium metal and in sodium chloride. (2) Sodium metal Sodium chloride
  15. June 2025, AS Paper 1, Q2(b)(iii) (2 marks): H → Al represents one of the bonds in AlH4 – . State the name of this type of bond and how the bond forms in this ion. (2)
  16. June 2025, AS Paper 1, Q2(b)(iv) (1 mark): What are the shapes of the aluminium chloride molecule and the tetrahydridoaluminate(III) ion? (1) – Name of shape of AlCl3 Diagram of shape of AlH4 – H H A tri
  17. June 2025, AS Paper 1, Q3(a) (1 mark): What are the intermolecular forces between water molecules? (1) A hydrogen bonds only B London forces and permanent dipoles only C London forces, permanent dipo
  18. June 2025, AS Paper 1, Q3(b) (1 mark): Ethanol, CH3CH2OH, is soluble in water but ethanethiol, CH3CH2SH, is almost insoluble. The best explanation for the difference in solubility is that (1) A ethan
  19. June 2025, AS Paper 1, Q7(c) (1 mark): Which isoelectronic ion has the smallest ionic radius? (1) A F– B Mg2+ C Na+ D O2–
  20. June 2025, AS Paper 2, Q4(c)(i) (2 marks): As the number of carbon atoms increases in the homologous series of unbranched primary alcohols, the state at room temperature changes from liquid to solid. Exp
  21. June 2025, AS Paper 2, Q4(c)(ii) (2 marks): The boiling temperatures of three isomeric alcohols are shown. Alcohol Boiling temperature / K pentan‑1‑ol 411 2‑methylbutan‑1‑ol 401 2,2‑dimethylpropan‑1‑ol 38
  22. June 2024, Paper 1, Q2(b) (1 mark): Which of these isoelectronic ions has the smallest ionic radius? (1) A S2− B Cl− C K+ D Ca2+
  23. June 2024, Paper 1, Q8(a) (2 marks): Draw dot-and-cross diagrams of the ions in magnesium hydroxide, showing the outer shell electrons only. Use × for magnesium electrons, ● for oxygen electrons an
  24. June 2024, Paper 2, Q3(a) (1 mark): Draw a dot‑and‑cross diagram of a molecule of hydrogen peroxide. (1)
  25. June 2024, Paper 2, Q7(d)(i) (2 marks): Explain why ethane‑1,2‑diol is soluble in water. A detailed description of the forces involved is not required. (2)
  26. June 2024, Paper 3, Q2(a) (3 marks): Explain how London forces arise. (3)
  27. June 2024, Paper 3, Q2(b) (2 marks): Explain which of the compounds A–D will have the highest boiling temperature. (2)
  28. June 2024, Paper 3, Q2(c) (3 marks): The apparatus shown may be used in an experiment to compare how far, if at all, a charged rod deflects different liquids. burette charged rod stream of liquid +
  29. June 2024, AS Paper 1, Q5(d) (1 mark): The strongest of the attractions between molecules in liquid chlorine dioxide is (1) A covalent bonding B hydrogen bonding C ionic bonding D permanent dipoles
  30. June 2024, AS Paper 1, Q5(e)(i) (2 marks): Complete a dot‑and‑cross diagram for the chlorate(III) ion, ClO2 – . Use crosses (×) for chlorine electrons, dots (•) for oxygen electrons and a triangle () fo
  31. June 2024, AS Paper 1, Q5(e)(ii) (3 marks): Predict the bond angle in this ion. Justify your answer. (3)
  32. June 2024, AS Paper 1, Q8(a)(i) (4 marks): Explain, using suitable labelled diagrams, why water is a good solvent for calcium chloride. (4)
  33. June 2024, AS Paper 1, Q8(a)(ii) (3 marks): Explain why methanol dissolves in water. Include a suitable labelled diagram. (3)
  34. June 2024, AS Paper 1, Q8(b)(i) (3 marks): Data about two isomeric alkanes are shown. Compound Formula Boiling temperature / K 2,2‑dimethylpropane C(CH3)4 283 pentane CH3(CH2)3CH3 309 Explain why pentane
  35. June 2023, Paper 1, Q3(c)(i) (2 marks): Draw a labelled diagram of a simple experiment to confirm this dissociation has occurred, stating the positive result. (2) Result
  36. June 2023, Paper 1, Q3(c)(ii) (1 mark): What is the shape of the ICl4 – ion? (1) A octahedral B square planar C tetrahedral D trigonal bipyramidal
  37. June 2023, Paper 1, Q6(b) (2 marks): The ionic salts sodium benzoate and potassium benzoate are both used as food preservatives. Explain why the melting temperature of sodium benzoate is higher tha
  38. June 2023, Paper 1, Q10(a) (1 mark): Draw the dot‑and‑cross diagram for an oxygen molecule, O2 . Show outer shell electrons only. (1)
  39. June 2023, Paper 1, Q10(b) (4 marks): The solubility of oxygen in water under standard conditions is 1.22 × 10–3 mol dm–3. Comment on this value by considering the type and strength of the intermole
  40. June 2023, Paper 2, Q7(a) (4 marks): Ethanal, CH3CHO, and ethanoic acid, CH3COOH, are both soluble in water but ethanoic acid has a much higher boiling temperature than ethanal. Explain these physi
  41. June 2023, Paper 3, Q3(c) (2 marks): Draw the dot‑and‑cross diagram of sulfuric acid, H2SO4 . Clearly differentiate between sulfur, oxygen and hydrogen electrons. Show outer shell electrons only. (
  42. June 2023, AS Paper 1, Q3(a)(iii) (2 marks): The equation for the reaction between aluminium and bromine is shown. 2Al + 3Br2 → Al2Br6 The compound is a dimer made up of two covalently bonded monomers join
  43. June 2023, AS Paper 1, Q3(b)(i) (2 marks): Explain how the trend in bond length relates to the trend in bond strength on descending the group. (2)
  44. June 2023, AS Paper 1, Q5(a) (1 mark): State what is meant by the term electronegativity. (1)
  45. June 2023, AS Paper 1, Q5(c) (2 marks): Describe what you understand by the term ‘continuum of bonding type’ in relation to electronegativities. (2)
  46. June 2023, AS Paper 1, Q5(d) (3 marks): The table gives data for chlorine and chlorine compounds of some Period 3 elements. The data show evidence that the type of bonding in compounds is a continuum
  47. June 2023, AS Paper 1, Q7(a) (1 mark): Draw a dot‑and‑cross diagram of the ionic compound potassium chloride. Show outer shell electrons only. (1)
  48. June 2023, AS Paper 1, Q7(b) (4 marks): Deduce the order of increasing size of the ions: Br–, Ca2+, Cl–, K+ Justify your answer. (4)
  49. June 2023, AS Paper 2, Q7(a) (1 mark): Which are the intermolecular force(s) between butan‑1‑ol molecules in the liquid phase? (1) A hydrogen bonding only B hydrogen bonding and permanent dipole‑dipo
  50. June 2022, Paper 1, Q3(e)(i) (1 mark): Which diagram shows the trend in the boiling temperatures of the hydrogen halides? (1) A B 300 300 Boiling Boiling 250 250 temperature temperature 200 200 / K /
  51. June 2022, Paper 1, Q4(a) (1 mark): Ionic bonding is the strong electrostatic attraction between (1) A anions and cations B atoms and delocalised electrons C cations and delocalised electrons D tw
  52. June 2022, Paper 1, Q4(b) (2 marks): An aqueous solution of copper(II) chromate(VI) was electrolysed using the apparatus shown in the diagram. 6 V DC + – F E copper(II) chromate(VI) solution Deduce
  53. June 2022, Paper 1, Q4(c) (1 mark): Some ionic radii are given in the table. Ion Ionic radius / nm Na+ 0.102 Mg2+ 0.072 Cl– 0.180 Br– 0.195 Deduce the formula of the compound, formed from the ions
  54. June 2022, Paper 1, Q4(e) (6 marks): Water has two significant anomalous properties: • it has a higher melting temperature than hydrogen sulfide, H2S, even though it has fewer electrons in its mole
  55. June 2022, Paper 1, Q7(b) (2 marks): The bonding in chromate(VI) ions, CrO4 Draw a possible dot‑and‑cross diagram for a chromate(VI) ion. (2)
  56. June 2022, Paper 2, Q2(b) (2 marks): Explain why 2,2‑dimethylpropane has a much lower boiling temperature than its isomer pentane. Detailed descriptions of the forces involved are not required. (2)
  57. June 2022, Paper 2, Q4(b) (2 marks): Draw dot‑and‑cross diagrams for a molecule of nitrogen gas and for the nitride ion, N3–, in sodium nitride, Na3N. Use dots () for nitrogen electrons and crosse
  58. June 2022, Paper 2, Q4(c) (4 marks): Ammonia accepts a proton to form an ammonium ion. NH3 + H+ → NH4 + Explain why the ammonia molecule and the ammonium ion have different shapes and different bon
  59. June 2022, Paper 2, Q5(a) (2 marks): About 200 cm3 of water and 200 cm3 of cooking oil were placed in a large beaker and two layers formed. The cooking oil formed the upper layer. An ice cube made
  60. June 2022, Paper 2, Q6(d)(i) (4 marks): Explain, by reference to the data and any intermolecular forces involved, the difference in the boiling temperatures. (4)
  61. June 2022, Paper 2, Q6(d)(ii) (2 marks): Explain, with the aid of a diagram, why propanone is completely miscible with water. (2)
  62. June 2022, Paper 3, Q2(a)(ii) (3 marks): Explain the shape of the cobalt(II) ion, [Co(H2O)6]2+ , using electron‑pair repulsion theory. (3)
  63. June 2022, AS Paper 1, Q5(a) (1 mark): The table gives the melting temperatures of some Group 7 hydrogen halides. Compound Melting temperature / K HF 190 HCl 158 HBr 185 Predict the melting temperatu
  64. June 2022, AS Paper 1, Q5(b) (1 mark): The compounds in the table are isomers. Compound Structural formula Boiling temperature / °C hexane CH3CH2CH2CH2CH2CH3 69 CH3CH2CH2CHCH3 2‑methylpentane 61 CH3
  65. June 2022, AS Paper 1, Q5(c) (6 marks): Methanol, CH3OH, is miscible with water in all proportions. Sodium chloride is much less soluble in methanol than in water. Explain these statements using your
  66. June 2022, AS Paper 1, Q7(c)(i) (1 mark): Draw a dot‑and‑cross diagram for the nitrate(V) ion, NO3 –, showing outer electrons only. (1) – O N O O
  67. June 2022, AS Paper 1, Q8(b)(i) (1 mark): Hydrogen chloride gas does not conduct electricity. Hydrochloric acid is a good conductor of electricity. Give a reason for this change in conductivity. (1)
  68. November 2021, Paper 1, Q3(a) (2 marks): Catalytic converters contain metals such as platinum. Describe the bonding in platinum. You may include a diagram in your answer. (2)
  69. November 2021, Paper 2, Q5(c)(ii) (2 marks): Explain why compound X is likely to have a higher boiling temperature than hydrocarbons of a similar molecular mass and shape. A detailed description of how the
  70. November 2021, Paper 2, Q6(a) (2 marks): Draw a dot-and-cross diagram of a molecule of carbon monoxide. Use dots (•) for the carbon electrons and crosses (×) for the oxygen electrons. (2)
  71. November 2021, Paper 3, Q3(b)(i) (1 mark): Draw a dot-and-cross diagram of an aluminium chloride molecule, AlCl3. Show the outer shell electrons only. (1)
  72. November 2021, Paper 3, Q3(b)(ii) (2 marks): Predict the shape of an AlCl3 molecule and the Cl−Al−Cl bond angle. (2) Shape of AlCl3 Cl−Al−Cl bond angle
  73. November 2021, Paper 3, Q3(c)(i) (1 mark): Draw a diagram to show how two AlCl3 molecules are joined together in the dimer. (1)
  74. November 2021, Paper 3, Q3(c)(ii) (1 mark): State the type of bond that joins the two AlCl3 molecules together. (1)
  75. November 2021, Paper 3, Q6(a)(ii) (2 marks): A mixture of 2-nitrophenol and 4-nitrophenol is produced in Stage 1. They are separated by steam distillation. The boiling temperature of 2-nitrophenol is 215°C
  76. November 2021, AS Paper 1, Q3(a)(ii) (3 marks): Draw diagrams showing the 3-dimensional shape of an ammonia molecule and of an amide ion, NH2 –. Include any lone pairs of electrons in each species. (3) ammoni
  77. November 2021, AS Paper 1, Q3(a)(iii) (1 mark): What is the H–N–H bond angle in an ammonia molecule? (1) A 104.5° B 107° C 109.5° D 120°
  78. November 2021, AS Paper 1, Q3(a)(iv) (2 marks): Explain the difference between the H–N–H bond angle in ammonia and in the amide ion. (2)
  79. November 2021, AS Paper 1, Q4(c)(i) (2 marks): Plot a graph of atomic number of the Group 6 element on the x-axis against melting temperature of the dihydrogen compound on the y-axis. (2) 300 250 Melting tem
  80. November 2021, AS Paper 1, Q4(c)(ii) (1 mark): Give an estimate of the melting temperature of H2S. (1)
  81. November 2021, AS Paper 1, Q7(a) (2 marks): State the meaning of the term ‘ionic bond’. (2)
  82. November 2021, AS Paper 2, Q5(c) (1 mark): Draw a dot‑and‑cross diagram for sulfur dioxide, showing outer electrons only. (1)
  83. November 2021, AS Paper 2, Q7(b) (3 marks): Explain why methanol and water are ‘soluble in all proportions’. You must include a diagram in your answer. (3)
  84. October 2020, Paper 1, Q3(a) (4 marks): Describe the bonding in the element chromium and use your answer to justify why it has such a high melting temperature. You may find it helpful to draw a labell
  85. October 2020, Paper 1, Q4(c) (6 marks): The solubility of two compounds in different solvents was investigated. A summary of the findings is shown. Compound Soluble in water Soluble in hexane 2-methyl
  86. October 2020, Paper 1, Q5(b)(i) (2 marks): Draw dot-and-cross diagrams for the ions in magnesium hydroxide. Show the outer electrons only. (2)
  87. October 2020, Paper 1, Q7(b)(i) (1 mark): The two O−C−H bond angles, x and y, in the ester are approximately (1) A 180° and 90° B 120° and 90° C 120° and 109.5° D 109.5° and 109.5°
  88. October 2020, Paper 1, Q8(b)(i) (2 marks): Complete the dot-and-cross diagram for the ethanedioate ion. Show the outer electrons only. (2) 2− O O C C O O
  89. October 2020, Paper 2, Q1(a) (2 marks): Draw a dot-and-cross diagram to show the bonding in a molecule of methanol. Show outer shell electrons only. (2)
  90. October 2020, Paper 2, Q1(b) (1 mark): Predict which bond has the shortest bond length in a molecule of methanol. (1)
  91. October 2020, Paper 2, Q1(c)(i) (1 mark): State the strongest type of intermolecular force that occurs between molecules of methanol and water. (1)
  92. October 2020, Paper 2, Q1(c)(ii) (3 marks): Draw a labelled diagram to show the interaction named in (c)(i) between one molecule of methanol and one molecule of water. Include any relevant lone pairs and
  93. October 2020, AS Paper 1, Q3(a)(i) (2 marks): Explain what is meant by a covalent bond. (2)
  94. October 2020, AS Paper 1, Q3(a)(ii) (1 mark): Draw a dot‑and‑cross diagram for hydrazine, showing the outer electrons only. Use crosses (×) to represent the electrons from nitrogen and dots ( • ) to represe
  95. October 2020, AS Paper 1, Q3(a)(iii) (1 mark): Estimate the H N H bond angle in hydrazine. (1) Bond angle =
  96. October 2020, AS Paper 1, Q3(b) (3 marks): Hydrazine is very soluble in water. Explain, using a labelled diagram and naming the relevant intermolecular interactions, why hydrazine is very soluble in wate
  97. October 2020, AS Paper 1, Q8(c)(ii) (1 mark): Name all the types of bond present in calcium carbonate. (1)
  98. October 2020, AS Paper 1, Q8(c)(iii) (1 mark): Give a reason, in terms of the bonding, why a high decomposition temperature is required. (1)
  99. October 2020, AS Paper 2, Q5(b)(i) (1 mark): Add the dipole to a molecule of iodine monochloride. (1) I Cl
  100. June 2019, Paper 1, Q1(d) (1 mark): Which of these isoelectronic ions has the largest ionic radius? (1) A N3– B O2– C Na+ D Al3+
  101. June 2019, Paper 1, Q6(a) (4 marks): Water might be expected to have a lower boiling temperature than hydrogen sulfide but it actually has a higher boiling temperature. Comment on this statement by
  102. June 2019, Paper 1, Q6(b) (4 marks): Explain why both water and carbon dioxide molecules have polar bonds but only water is a polar molecule. (4)
  103. June 2019, Paper 1, Q6(c) (2 marks): Pure water ionises to form H3O+ and OH– ions, although only to a very small extent. Draw the dot-and-cross diagrams of these ions. Use dots (•) for the hydrogen
  104. June 2019, Paper 2, Q7(a) (2 marks): Draw a dot-and-cross diagram for nitrosyl chloride, showing only the outer shell electrons. N (2)
  105. June 2019, Paper 3, Q5(e)(i) (1 mark): Draw a dot-and-cross diagram of the BH4 Use crosses (×) for the boron electrons, dots (•) for the hydrogen electrons and triangles ( V ) for the additional elec
  106. June 2019, AS Paper 1, Q8(a) (3 marks): Explain the difference in the melting temperatures of magnesium oxide and potassium bromide. (3)
  107. June 2019, AS Paper 1, Q9(a)(ii) (4 marks): A dot-and-cross diagram for the chlorate(V) ion (ClO3 – O ⎡ Key ⎢ = chlorine electrons O Cl O ⎢ = an added electron ⎢ ⎣ = oxygen electrons Cl Predict the shape
  108. June 2019, AS Paper 1, Q9(e)(i) (2 marks): Describe, using diagrams to illustrate your answer, the interactions between each of the ions and the solvent when sodium chlorate(I) dissolves in water. (2)
  109. June 2019, AS Paper 1, Q9(e)(ii) (2 marks): The displayed formulae of ethanol and chloroethane are shown. H H H H H C C Cl H C C O H H H H H ethanol chloroethane Ethanol is very soluble in water whereas c
  110. June 2019, AS Paper 2, Q1(a)(ii) (3 marks): Explain why isomers of the alkane in (a)(i) have lower boiling temperatures and so are found in the petrol fraction. (3)
  111. June 2018, Paper 1, Q7(b)(i) (2 marks): Complete the dot-and-cross diagram of a molecule of boric acid. Show the outer shell electrons only. Use dots (•) for the hydrogen electrons, crosses (×) for th
  112. June 2018, Paper 1, Q7(b)(ii) (1 mark): What are the O B O and B O H bond angles in a molecule of boric acid? (1) O B O bond angle B O H bond angle A 109.5° 104.5° B 109.5° 180° C 120° 104.5° D 120° 1
  113. June 2018, Paper 1, Q7(c) (1 mark): Boric acid is a solid with melting temperature 171 °C. What are the strongest interactions between the molecules in solid boric acid? (1) A covalent bonds B hyd
  114. June 2018, Paper 3, Q1(a)(i) (3 marks): Describe how London forces form between halogen molecules. (3)
  115. June 2018, Paper 3, Q1(a)(ii) (2 marks): The boiling temperatures of chlorine and bromine are shown in the table. Halogen Boiling temperature / °C chlorine −34 bromine 59 Explain why bromine has a high
  116. June 2018, AS Paper 1, Q1(a) (2 marks): State what is meant by the term covalent bond. (2)
  117. June 2018, AS Paper 1, Q1(b) (2 marks): Draw a diagram of the ammonia molecule, clearly showing its shape. Include any lone pairs of electrons and the value of the bond angle. (2)
  118. June 2018, AS Paper 1, Q1(c) (1 mark): The dot-and-cross diagram of BF3 is F F B F What is the bond angle in BF3? (1) A 90° B 107° C 109.5° D 120°
  119. June 2018, AS Paper 1, Q1(d)(i) (2 marks): Ammonia and boron trifluoride react to form a compound NH3BF3 which contains a dative covalent bond. Each of the molecules, NH3 and BF3, has a different feature
  120. June 2018, AS Paper 1, Q1(d)(ii) (2 marks): During this reaction, the bond angles about the nitrogen atom and the boron atom change. State the new H N H and F B F bond angles. (2)
  121. June 2018, AS Paper 1, Q7 (6 marks): *7 The compounds hydrogen fluoride, water and methane, all have simple molecular structures, but they have significantly different boiling temperatures. Discuss
  122. June 2018, AS Paper 1, Q8(a)(ii) (3 marks): Draw dot-and-cross diagrams of the ions in sodium fluoride, showing all the electrons. Use your diagram to explain why the ions are described as isoelectronic.
  123. June 2018, AS Paper 1, Q8(a)(iii) (1 mark): Which diagram shows the trend in ionic radius for the isoelectronic ions N3− to Al3+? (1) A B Ionic Ionic radius radius F− (Ne) Na+ Mg2+ Al3+ F− (Ne) Na+ Mg2+ A
  124. June 2018, AS Paper 1, Q8(a)(iv) (2 marks): Explain your answer to (a)(iii) in terms of the structure of the ions. (2)
  125. June 2018, AS Paper 1, Q8(b) (2 marks): The strength of ionic bonding in different compounds can be compared by using the amount of energy required to separate the ions. Some values for this energy ar
  126. June 2017, Paper 1, Q1(b)(i) (2 marks): Explain why a phosphorus(III) chloride molecule has this shape and bond angle. (2)
  127. June 2017, Paper 1, Q1(b)(ii) (1 mark): Which describes the polarity of the P—Cl bond and the polarity of the phosphorus(III) chloride molecule? (1) Polarity of P—Cl bond Polarity of molecule A non-po
  128. June 2017, Paper 1, Q6(a)(i) (1 mark): Draw a dot-and-cross diagram to show the bonding in magnesium bromide. Only outer shell electrons are required. (1)
  129. June 2017, Paper 2, Q3(d) (3 marks): Explain why ethene has a boiling temperature of −104 °C, whereas ethanol has a boiling temperature of 78 °C. (3)
  130. June 2017, AS Paper 1, Q2(a)(i) (1 mark): The O–H bond in water is polar because, when compared with the hydrogen atom, the oxygen atom has (1) A a higher mass number B a larger atomic radius C greater
  131. June 2017, AS Paper 1, Q2(a)(ii) (2 marks): Draw a diagram of a hydrogen bond between two water molecules in ice. Show the value of the H–O–H angle within a molecule and the value of the O–H–O angle betwe
  132. June 2017, AS Paper 1, Q2(a)(iii) (2 marks): Explain why hydrogen bonding causes ice to be less dense than liquid water. (2)
  133. June 2017, AS Paper 1, Q5(a)(ii) (1 mark): The bonding in magnesium results from (1) A strong electrostatic attractions between oppositely charged ions B strong electrostatic attractions between the nucl
  134. June 2017, AS Paper 1, Q6(a)(ii) (1 mark): Draw a dot-and-cross diagram for BCl3 showing only the outer shell electrons of the atoms. (1)
  135. June 2017, AS Paper 1, Q6(a)(iii) (2 marks): Use your diagram to explain why BCl3 has a trigonal planar shape with bond angles of 120q. (2)
  136. June 2017, AS Paper 1, Q6(c) (6 marks): Aluminium fluoride and aluminium chloride are both crystalline solids at room temperature. Aluminium fluoride sublimes to form a gas at 1291qC (1564 K), whilst
  137. June 2017, AS Paper 2, Q1 (1 mark): Which compound does not have hydrogen bonding between its molecules? Name of compound Formula of compound A fluoromethane CH3F B hydrogen fluoride HF C hydrogen
  138. June 2017, AS Paper 2, Q2 (1 mark): Which molecule has a linear shape? A H2S B SO2 C CO2 D CH2 CH2
  139. June 2016, AS Paper 1, Q1(d) (3 marks): State what is meant by the term electronegativity and hence explain the polarity, if any, of the bonds in chlorine trifluoride, ClF3. (3)
  140. June 2016, AS Paper 1, Q5(c) (3 marks): Complete the dot-and-cross diagram for the bonding in nitric acid, showing only outer shell electrons. Use (•) for the oxygen electrons, (x) for the nitrogen el
  141. June 2016, AS Paper 1, Q6(a) (2 marks): The diagram shows bond angles in ammonia and water. N O 107° 104.5° H H H H H Explain why the bond angle in water is less than the bond angle in ammonia. (2)
  142. June 2016, AS Paper 1, Q6(b) (3 marks): Explain why the O–H and S–H bond lengths are different. S O 133.6 pm 95.7 pm H H H H (3)

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