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Physical properties of Period 3 elements: AQA A‑Level Chemistry questions

AQA A-Level Chemistry past-paper questions on 3.2.1.2 Physical properties of Period 3 elements, 2008–2025, with mark schemes and examiner’s reports where available.

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  1. Q15

    June 2025 · Paper 3

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  3. Q19

    June 2024 · Paper 3

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  4. Q16

    June 2024 · AS Paper 1

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  5. Q19

    June 2023 · Paper 3

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  6. Q03.6

    November 2021 · Paper 1

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  7. Q18

    November 2021 · AS Paper 1

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  8. Q03.3

    November 2020 · Paper 1

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  9. Q03.4

    November 2020 · Paper 1

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  13. Q03.3

    June 2019 · Paper 1

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  14. Q17

    June 2018 · Paper 3

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  15. Q12

    June 2018 · AS Paper 1

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  17. Q06

    June 2017 · Paper 3

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All 48 questions on Physical properties of Period 3 elements, as a list
  1. June 2025, Paper 3, Q15 (1 mark): Which statement about trends from left to right across Period 3 is correct? [1 mark] A Atomic radius increases from Na to Si and then decreases B Atomic radius
  2. June 2025, Paper 3, Q16 (1 mark): Which statement about ionisation energies in Period 3 is not correct? [1 mark] A The first ionisation energy of Mg is greater than that of Na B The first ionisa
  3. June 2024, Paper 3, Q19 (1 mark): Consider the Period 3 elements from sodium to chlorine. Which statement is correct? [1 mark] A Sodium has the smallest atomic radius. B Aluminium has the highes
  4. June 2024, AS Paper 1, Q16 (1 mark): Which row correctly shows general trends in properties across Period 3? [1 mark] Atomic radius First ionisation energy A decreases increases B decreases decreas
  5. June 2023, Paper 3, Q19 (1 mark): Which statement is not correct about the Period 3 elements sodium to chlorine? [1 mark] A Sodium has the largest atomic radius. B Sodium has the lowest melting
  6. November 2021, Paper 1, Q03.6 (1 mark): Identify the element in Period 3, from sodium to chlorine, that has the largest atomic radius. [1 mark]
  7. November 2021, AS Paper 1, Q18 (1 mark): Which element in Period 3 has the highest melting point? [1 mark] A Aluminium B Silicon C Sodium D Sulfur
  8. November 2020, Paper 1, Q03.3 (2 marks): Explain why the atomic radius decreases across Period 3, from sodium to chlorine. [2 marks]
  9. November 2020, Paper 1, Q03.4 (1 mark): Identify the element in Period 3, from sodium to chlorine, that has the highest electronegativity. [1 mark]
  10. November 2020, AS Paper 1, Q01.1 (3 marks): There is a general trend for an increase in ionisation energy across Period 3. Give one example of an element that deviates from this trend. Explain why this de
  11. November 2020, AS Paper 1, Q18 (1 mark): Which of these elements has the highest melting point? [1 mark] A Argon B Chlorine C Silicon D Sulfur
  12. June 2019, Paper 1, Q03.2 (1 mark): Identify the element in Period 4 with the highest electronegativity value. [1 mark]
  13. June 2019, Paper 1, Q03.3 (3 marks): Identify the element in Period 4 with the largest atomic radius. Explain your answer. [3 marks] Element Explanation
  14. June 2018, Paper 3, Q17 (1 mark): Which of these Period 3 elements has the highest melting point? [1 mark] A Aluminium B Phosphorus C Sodium D Sulfur
  15. June 2018, AS Paper 1, Q12 (1 mark): The diagram shows how a property of Period 3 elements varies across the period. What is the property? [1 mark] A Atomic radius B Electronegativity C First ionis
  16. June 2018, AS Paper 1, Q18 (1 mark): Which element has the highest first ionisation energy? [1 mark] A Aluminium B Phosphorus C Silicon D Sulfur
  17. June 2017, Paper 3, Q06 (1 mark): Which is the correct order of melting points of these Period 3 elements? [1 mark] A phosphorus > sulfur > chlorine > argon B argon > chlorine > phosphorus > sul
  18. June 2017, AS Paper 1, Q01.3 (3 marks): State which of the elements magnesium and aluminium has the lower first ionisation energy. Explain your answer. [3 marks
  19. June 2017, AS Paper 1, Q21 (1 mark): 2 1 Which of these has the highest first ionisation energy? [1 mark] A Na B Al C Si D Cl
  20. June 2016, AS Paper 1, Q02.3 (4 marks): The first ionisation energies of some Period 3 elements are shown in Figure 1. Figure 1 Complete Figure 1 by plotting the approximate first ionisation energy va
  21. Specimen, Paper 1, Q02.1 (2 marks): Explain why the atomic radii of the elements decrease across Period 3 from sodium t chlorine. [2 mark 0 2 . 1
  22. Specimen, Paper 1, Q02.2 (2 marks): Explain why the melting point of sulfur (S8) is greater than that of phosphorus (P4). [2 mark 0 2 . 2
  23. June 2016, CHEM1 (old spec), Q5(a) (4 marks): State and explain the general trend in first ionisation energy across Period 3. [4 marks]
  24. June 2016, CHEM1 (old spec), Q5(b) (3 marks): Give one example of an element which deviates from the general trend in first ionisation energy across Period 3. Explain why this deviation occurs. [3 marks]
  25. June 2016, CHEM1 (old spec), Q5(d) (4 marks): Identify the Period 3 element that has the highest melting point. Explain your answer by reference to structure and bonding. [4 marks]
  26. June 2015, CHEM1 (old spec), Q1(a) (3 marks): State the element in Period 3 that has the highest melting point. Explain your answer. [3 marks] Element Explanation
  27. June 2015, CHEM1 (old spec), Q1(b) (3 marks): State the element in Period 3 that has the highest first ionisation energy. Explain your answer. [3 marks] Element Explanation
  28. June 2013, CHEM1 (old spec), Q6(a) (3 marks): Identify the Period 2 element, from carbon to fluorine, that has the largest atomic radius. Explain your answer. Element Explanation
  29. June 2012, CHEM1 (old spec), Q1(g) (3 marks): Predict whether an atom of 88Sr will have an atomic radius that is larger than, smaller than or the same as the atomic radius of 87Rb. Explain your answer. Atom
  30. January 2012, CHEM1 (old spec), Q2(a) (1 mark): Identify, from the Period 2 elements lithium to nitrogen, the element that has the largest atomic radius. (1 mark)
  31. January 2012, CHEM1 (old spec), Q2(d) (1 mark): Draw a cross on the diagram to show the melting point of nitrogen. (1 mark) Lithium Beryllium Boron Carbon Nitrogen Melting point / K 5000 4500 4000 3500 3000 2
  32. June 2011, CHEM1 (old spec), Q5(b) (3 marks): State and explain the general trend in first ionisation energies for the Period 3 elements aluminium to argon. Trend Explanation
  33. January 2011, CHEM1 (old spec), Q5(a) (3 marks): State the type of structure shown by a crystal of silicon. Explain why the melting point of silicon is very high.
  34. January 2011, CHEM1 (old spec), Q5(b) (3 marks): State the type of structure shown by crystals of sulfur and phosphorus. Explain why the melting point of sulfur is higher than the melting point of phosphorus.
  35. January 2011, CHEM1 (old spec), Q5(d) (3 marks): Explain why the melting point of aluminium is higher than the melting point of sodium.
  36. June 2010, CHEM1 (old spec), Q2(a) (1 mark): Draw a cross on the diagram to show the first ionisation energy of aluminium. (1 mark)
  37. January 2010, CHEM1 (old spec), Q1(c) (3 marks): State and explain the general trend in the first ionisation energies of the Period 3 elements sodium to chlorine. Trend Explanation
  38. June 2009, CHEM1 (old spec), Q1(c) (3 marks): 1 (c) State and explain the trend in atomic radius of the Period 3 elements from sodium to chlorine. Trend Explanation (3 marks)
  39. June 2009, CHEM1 (old spec), Q1(d) (3 marks): 1 (d) Explain why sodium has a lower melting point than magnesium. (3 marks)
  40. January 2009, CHEM1 (old spec), Q4(a)(ii) (3 marks): 4 (a) (ii) State and explain the general trend in first ionisation energies for the elements Na to P Trend Explanation (3 marks)
  41. January 2009, CHEM1 (old spec), Q4(a)(iii) (3 marks): 4 (a) (iii) State which one of the elements from Na to P deviates from this general trend and explain why this occurs. Element Explanation (3 marks)
  42. January 2009, CHEM1 (old spec), Q4(b) (3 marks): 4 (b) State which one of the elements from Na to P has the highest melting point and explain your answer. Element Explanation (3 marks)
  43. January 2009, CHM1 (2008 spec), Q5(b) (6 marks): 5 (b) There are trends in the melting point and in the electrical conductivity of the metals in Period 3. Using Na and Al as your examples, state these trends a
  44. June 2008, CHM1 (2008 spec), Q3(b) (2 marks): 3 (b) Explain why there is a general increase in the first ionisation energies of the Period 3 elements Na to Ar (2 marks)
  45. June 2008, CHM1 (2008 spec), Q4(a) (4 marks): 4 (a) State which has the larger atomic radius, a sodium atom or a chlorine atom. Explain your answer. Atom with larger atomic radius Explanation (4 marks)
  46. June 2008, CHM1 (2008 spec), Q4(b) (5 marks): 4 (b) (i) Give the electron arrangement of the sodium atom. 4 (b) (ii) State which has the larger radius, a sodium atom or a sodium ion (Na+). Explain your answ
  47. January 2008, CHM1 (2008 spec), Q6(a) (4 marks): 6 (a) Explain, in terms of its structure and bonding, why the melting point of silicon is very high. (4 marks)
  48. January 2008, CHM1 (2008 spec), Q6(b) (5 marks): (b) Select any two of the Period 3 elements phosphorus, sulphur and chlorine. State and explain which of your selected elements has the higher melting point. (5

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