Redox: OCR A‑Level Chemistry B questions
Every OCR A-Level Chemistry B exam question on DM Redox (specification points DM(c)–(f)), 2016–2025, with its mark scheme and examiner’s report.
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Calculations
Q35(a)(ii)
The whole paper ↗![June 2025 Paper 1, question 35(a)(ii): Write a balanced ionic equation for the reaction. [2]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h43301-jun25-35-aii-qp.webp?v=3)
Q5(b)(i)
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Q5(b)(ii)
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Q5(c)(i)
The whole paper ↗![June 2025 Paper 2, question 5(c)(i): From the article, give two advantages of Li-ion batteries over VRFBs as batteries for electric vehicles. Advantage 1 Advantage 2 [2]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h43302-jun25-05-ci-qp.webp?v=3)
Q5(c)(ii)
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Q5(d)
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Q4(a)
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Q5(b)(iii)
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Q1(a)(i)
The whole paper ↗![June 2024 Paper 3, question 1(a)(i): Name the electrode against which these values are measured. [1]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h43303-jun24-01-ai-qp.webp?v=3)
Q1(a)(ii)
The whole paper ↗![June 2024 Paper 3, question 1(a)(ii): What are the standard conditions at which these standard electrode potentials are measured? [2]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h43303-jun24-01-aii-qp.webp?v=3)
Q1(b)(i)
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Q1(b)(ii)
The whole paper ↗![June 2024 Paper 3, question 1(b)(ii): Suggest how the students make the salt bridge. [1]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h43303-jun24-01-bii-qp.webp?v=3)
Q1(b)(iii)
The whole paper ↗![June 2024 Paper 3, question 1(b)(iii): Use Table 1.1 to calculate E o for the cell. E o cell = V [1]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h43303-jun24-01-biii-qp.webp?v=3)
Q1(c)(i)
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Q1(c)(ii)
The whole paper ↗![June 2024 Paper 3, question 1(c)(ii): Suggest the purpose of the porous separator shown in the diagram. [1]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h43303-jun24-01-cii-qp.webp?v=3)
Q34(a)(i)
The whole paper ↗![June 2023 Paper 1, question 34(a)(i): Complete the labelled diagram to show the student’s cell. V Zn(s) Zn2+(aq) (1.0 mol dm–3) [3]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h43301-jun23-34-ai-qp.webp?v=3)
Q34(a)(ii)
The whole paper ↗![June 2023 Paper 1, question 34(a)(ii): Use the data in Table 34.1 to calculate E o cell for the student’s electrochemical cell. E o cell = V [1]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h43301-jun23-34-aii-qp.webp?v=3)
Q34(a)(iii)
The whole paper ↗![June 2023 Paper 1, question 34(a)(iii): State the types of particle that cause the transfer of charge through the wire and the solutions. The wire The solutions [2]](https://pub-e8a9dbab8e2a4d089f52b2a45e0d0b50.r2.dev/bank/h43301-jun23-34-aiii-qp.webp?v=3)
Q34(b)
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All 58 questions on Redox, as a list
- June 2025, Paper 1, Q35(a)(ii) (2 marks): Write a balanced ionic equation for the reaction. [2]
- June 2025, Paper 2, Q5(b)(i) (2 marks): When the VRFB is delivering a current, V(V) is reduced to V(IV) and V(II) is oxidised to V(III). Write the ionic equation and give the E o cell for the overall
- June 2025, Paper 2, Q5(b)(ii) (2 marks): A student sets up a cell to measure the E o cell for VO2+/ V3+ against Zn2+ / Zn at 298 K. Here is a diagram of the student’s cell. V zinc rod vanadium rod Zn2+
- June 2025, Paper 2, Q5(b)(iii) (4 marks): A student has powdered samples of the metals (silver, tin and zinc) shown in Table 5.1, and an +(aq). acidic solution of VO2 The student wants to obtain a solut
- June 2025, Paper 2, Q5(c)(i) (2 marks): From the article, give two advantages of Li-ion batteries over VRFBs as batteries for electric vehicles. Advantage 1 Advantage 2 [2]
- June 2025, Paper 2, Q5(c)(ii) (2 marks): From the article, give two advantages of VRFBs over Li-ion batteries for large-scale use in storing energy from an array of solar cells. Advantage 1 Advantage 2
- June 2025, Paper 2, Q5(d) (1 mark): Both types of battery have a separator in the middle. Give the formulae of the particles that pass through the separators in each battery when they are in use.
- June 2025, Paper 3, Q4(a) (2 marks): In the paperclip solution, IO4 – ions. IO3 The oxidation and reduction half equations for this reaction are: – + 2H+ + 2e– – + H2O IO4 IO3 Mn2+ + 4H2O – + 8H+ +
- June 2024, Paper 2, Q5(b)(iii) (3 marks): Write two half-equations to show how H2O2 can either act as an oxidising agent or a reducing agent ‘depending on the company it keeps’. Oxidising agent: Reducin
- June 2024, Paper 3, Q1(a)(i) (1 mark): Name the electrode against which these values are measured. [1]
- June 2024, Paper 3, Q1(a)(ii) (2 marks): What are the standard conditions at which these standard electrode potentials are measured? [2]
- June 2024, Paper 3, Q1(b)(i) (2 marks): Some students set up the cell below. The cell consists of a copper/copper ion half-cell and a lead/lead ion half-cell. The left-hand electrode is negative. – +
- June 2024, Paper 3, Q1(b)(ii) (1 mark): Suggest how the students make the salt bridge. [1]
- June 2024, Paper 3, Q1(b)(iii) (1 mark): Use Table 1.1 to calculate E o for the cell. E o cell = V [1]
- June 2024, Paper 3, Q1(c)(i) (3 marks): Use Table 1.1 to write ion-electron half equations for the reactions happening at the negative and positive electrodes. Then write the equation for the overall
- June 2024, Paper 3, Q1(c)(ii) (1 mark): Suggest the purpose of the porous separator shown in the diagram. [1]
- June 2023, Paper 1, Q34(a)(i) (3 marks): Complete the labelled diagram to show the student’s cell. V Zn(s) Zn2+(aq) (1.0 mol dm–3) [3]
- June 2023, Paper 1, Q34(a)(ii) (1 mark): Use the data in Table 34.1 to calculate E o cell for the student’s electrochemical cell. E o cell = V [1]
- June 2023, Paper 1, Q34(a)(iii) (2 marks): State the types of particle that cause the transfer of charge through the wire and the solutions. The wire The solutions [2]
- June 2023, Paper 1, Q34(b) (3 marks): Standard electrode potentials can be used to explain how some metals protect iron from rusting. A thin coating of zinc on the surface of iron will provide prote
- June 2023, Paper 1, Q34(d) (2 marks): A student carries out the analysis described in part (c) but uses hydrochloric acid instead of sulfuric acid to dissolve the sample of the alloy. Using the data
- June 2022, Paper 1, Q26 (1 mark): Manganate(VII) ions react with sulfate(IV) ions as shown in the unbalanced equation below. –(aq) + SO3 2–(aq) + H+(aq) Mn2+(aq) + SO4 2–(aq) + H2O(l) MnO4 2–(aq
- June 2022, Paper 1, Q29 (1 mark): Two half-cell equations are shown with their standard electrode potentials. E o = – 0.26 V V3+(aq) + e– V2+(aq) E o = +0.34 V VO2+(aq) + 2H+(aq) + e– V3+(aq) +
- June 2022, Paper 3, Q3(a)(i) (2 marks): Write half-equations for the reactions that take place in each half-cell. Show state symbols. oxidation reaction: reduction reaction: [2]
- June 2022, Paper 3, Q3(a)(ii) (2 marks): Explain the purpose of the salt bridge. [2]
- June 2022, Paper 3, Q3(a)(iii) (1 mark): Calculate E o cell for the copper/zinc cell in Fig. 3.1. E o cell = V [1]
- June 2022, Paper 3, Q3(b)(i) (1 mark): Metallic silver is added to aqueous iron(II) sulfate. [1]
- June 2022, Paper 3, Q3(b)(ii) (2 marks): Aqueous potassium chloride is added to acidified potassium manganate(VII) solution. [2]
- June 2022, Paper 3, Q3(c)(i) (2 marks): Explain how Equation 3.1 shows that E = E o under standard conditions. [2]
- June 2022, Paper 3, Q3(c)(ii) (2 marks): Calculate the electrode potential of a Zn2+(aq) / Zn(s) half-cell when [Zn2+(aq)] = 0.20 mol dm–3. E = V [2] Standard electrode potential, Half reaction E o / V
- June 2022, Paper 3, Q3(d) (4 marks): The rusting of iron is an electrochemical process. A solution of ‘ferroxyl’ indicator can be used to investigate the reactions taking place in rusting. This ind
- November 2021, Paper 1, Q31(b)(ii) (1 mark): Use the oxidation states to construct an equation for the oxidation of ammonium ions using atmospheric oxygen. An acidic solution containing nitrate ions is for
- November 2021, Paper 2, Q2(a)(i) (2 marks): Complete half-equation 3 in Table 2.1 by writing numbers on the dotted lines. [2]
- November 2021, Paper 2, Q2(b)(i) (3 marks): Complete the diagram of their apparatus. Indicate how standard conditions are obtained. [3]
- November 2021, Paper 2, Q2(b)(ii) (1 mark): Use the data in Table 2.1 to calculate the E o cell value for the cell in (b)(i). E o cell = V [1]
- November 2021, Paper 2, Q2(c) (4 marks): Zinc blocks are often fixed to the bottom of steel ships to stop the ships rusting in sea water. A student compares this process with the cell in part (b)(i). T
- November 2020, Paper 1, Q14 (1 mark): X is an iron nail partially covered in zinc. Y is a plain iron nail. iron nail X iron nail Y covering of zinc wire water water Which statement about rusting is
- November 2020, Paper 2, Q2(a)(i) (2 marks): There is something missing from the diagram. State what it is and describe what it is made of. [2]
- November 2020, Paper 2, Q2(a)(ii) (2 marks): State two conditions necessary for the cell to measure electrode potentials under standard conditions. 1 2 [2]
- November 2020, Paper 2, Q2(b)(ii) (1 mark): State and explain which way electrons flow in the wire when the standard cell is delivering a current. [1]
- November 2020, Paper 2, Q2(c) (4 marks): Silver bromide, AgBr, is usually described as ‘insoluble’ but a small amount can dissolve in water. The students have a saturated solution of AgBr. This contain
- November 2020, Paper 2, Q2(d)(i) (2 marks): Write an equation for the reaction that occurs when the cell delivers a current. [2]
- November 2020, Paper 2, Q2(d)(ii) (2 marks): Draw a labelled diagram to show how the IO3 You do not need to give concentrations. [2]
- June 2019, Paper 2, Q3(b)(i) (2 marks): The forward reaction in equation 3.1 does not occur under standard conditions. Use data from Table 3.1 to explain why. [2]
- June 2019, Paper 2, Q3(b)(ii) (2 marks): Suggest why the forward reaction in equation 3.1 does occur in the presence of concentrated hydrochloric acid. [2]
- June 2019, Paper 2, Q3(c)(i) (4 marks): The student uses a Cu2+(aq)/Cu(s) half-cell to confirm the Eo of a Cl 2(aq)/Cl −(aq) half-cell. Complete and label the diagram of the apparatus the student woul
- June 2019, Paper 2, Q3(c)(ii) (1 mark): Give the value of Eo cell for the cell in (c)(i). Eo cell = V [1]
- June 2019, Paper 2, Q3(c)(iii) (1 mark): State where the electrons move and which way they are moving when the cell delivers a current. [1]
- June 2019, Paper 2, Q3(c)(iv) (1 mark): A standard hydrogen electrode is used to measure Eo values, such as those in Table 3.1. Give the half-cell reaction that occurs at a hydrogen electrode. Show st
- June 2019, Paper 2, Q3(c)(v) (2 marks): The E value for the copper electrode at 298 K varies with the concentration of copper ions. The equation for this is shown below. E = Eo + 0.0128 l n [Cu2+] Cal
- June 2018, Paper 1, Q35(c)(i) (2 marks): Give the half-equations for the processes occurring during the rusting. [2]
- June 2018, Paper 1, Q35(c)(ii) (1 mark): What are the formulae of the green and orange solids? Green solid Orange solid [1]
- June 2018, Paper 1, Q35(c)(iii) (1 mark): Suggest why rusting takes place faster in seawater than in rainwater. [1]
- June 2018, Paper 1, Q35(e) (2 marks): Use the electrode potentials in the table below to explain why only the nickel reacts. E ϴ / V Half reaction Ni2+(aq) + 2e– Ni(s) – 0.25 2H+(aq) + 2e– 0.00 H2(g
- June 2018, Paper 3, Q2(a)(i) (1 mark): Suggest one advantage and one disadvantage of using a calomel electrode over a standard hydrogen electrode. Advantage Disadvantage [1]
- June 2018, Paper 3, Q2(c) (6 marks): The use of a standard hydrogen electrode for measuring standard electrode potentials is often not practicable. The diagram below shows a calomel electrode. This
- June 2017, Paper 1, Q10 (1 mark): A student is given the electrode potentials below. Cu2+ + 2e– E ө = +0.34 V Cu Ag+ + e– E ө = +0.80 V Ag The student sets up a cell from the two half cells. Whi
- June 2017, Paper 1, Q28 (1 mark): Which statement(s) about rusting is/are correct? Rust contains Fe3+ ions. 1 2 Oxygen molecules are reduced during rusting. Fe3+ + 3e–. 3 The first step in rusti
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