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Predicting mass spectra of diatomic molecules: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 2.1.3 Predicting mass spectra of diatomic molecules, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. Q22(d)

    June 2025 · AS Unit 1

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  2. The start of question 15

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  3. Q19(a)

    January 2024 · AS Unit 1

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  4. Q9

    October 2023 · AS Unit 1

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  5. Q10(c)

    October 2022 · AS Unit 1

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  6. Q20(c)(iii)

    June 2022 · AS Unit 1

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  7. Q2

    June 2021 · AS Unit 1

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  8. Q18(f)(i)

    January 2020 · AS Unit 1

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  10. Q11

    June 2019 · AS Unit 1

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All 11 questions on Predicting mass spectra of diatomic molecules, as a list
  1. June 2025, AS Unit 1, Q22(d) (2 marks): Chlorine can be analysed in a mass spectrometer. On the grid shown, draw the spectrum you would expect to see for the molecular ion peaks for a chlorine molecul
  2. June 2024, Unit 5, Q15(d)(i) (2 marks): Explain the relative intensities of the peaks at m / z values of 162, 164 and 166. (2)
  3. January 2024, AS Unit 1, Q19(a) (2 marks): 2‑Chloropropane has a relative molecular mass of 78.5 g mol–1. Chlorine has two common isotopes, 35Cl and 37Cl. There are three times more 35Cl atoms than 37Cl
  4. October 2023, AS Unit 1, Q9 (1 mark): A sample of the element chlorine, Cl2, was analysed in a mass spectrometer. Chlorine has two isotopes. What is the total number of peaks, due to ions with a sin
  5. October 2022, AS Unit 1, Q10(c) (1 mark): Naturally‑occurring chlorine has two isotopes, 35Cl and 37Cl. How many peaks due to the singly-charged molecular ions are seen in the mass spectrum of chlorine,
  6. June 2022, AS Unit 1, Q20(c)(iii) (2 marks): On the mass spectrum grid, draw the peaks for the bromine molecular ions, showing the relative peak heights. The bromine isotopes in this sample have the same r
  7. June 2021, AS Unit 1, Q2 (1 mark): Iodine exists as one isotope with mass number 127. Chlorine exists as two isotopes with mass numbers 35 and 37. How many molecular ion (ICl3 +) peaks are there
  8. January 2020, AS Unit 1, Q18(f)(i) (2 marks): Complete the mass spectrum for a sample of chlorine gas to show the expected molecular ion peaks due to Cl2 + . (2) 100 90 80 70 60 Relative 50 abundance 40 30
  9. January 2020, AS Unit 1, Q18(f)(ii) (2 marks): Suggest why there could be a small peak at m / z = 36 in the mass spectrum of chlorine gas. (2)
  10. June 2019, AS Unit 1, Q11 (1 mark): The two stable isotopes of bromine have relative masses of 79 and 81. Which is the correct pattern of peaks in the mass spectrum of molecular bromine? Relative
  11. January 2019, AS Unit 1, Q24(c)(i) (2 marks): A sample of nitrogen trichloride contained only nitrogen atoms with mass number 14, and chlorine atoms with mass numbers 35 and 37. Give the formula and mass/ch

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