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Covalent and dative covalent bonds: Edexcel International A Level Chemistry questions

Edexcel International A Level Chemistry past-paper questions on 3.B.1 Covalent and dative covalent bonds, 2019–2025, with mark schemes and examiner’s reports where available.

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  1. Q23(b)(i)

    June 2025 · AS Unit 1

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  2. Q23(b)(ii)

    June 2025 · AS Unit 1

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  3. Q26(b)

    January 2025 · AS Unit 1

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  4. Q26(c)

    January 2025 · AS Unit 1

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  5. Q21(b)(ii)

    October 2024 · AS Unit 1

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  6. Q18(b)(i)

    October 2024 · Unit 5

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  7. Q18(a)(i)

    June 2024 · AS Unit 2

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  8. The start of question 15

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  9. Q22(d)

    June 2024 (R) · AS Unit 2

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  10. Q21(b)(i)

    January 2024 · AS Unit 1

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  11. Q21(b)(ii)

    January 2024 · AS Unit 2

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  12. Q5

    October 2023 · AS Unit 1

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  14. Q18(c)(i)

    October 2023 · AS Unit 1

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  15. Q18(c)(iii)

    October 2023 · AS Unit 1

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  16. Q23(b)(ii)

    January 2023 · AS Unit 1

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  17. Q25(a)(ii)

    January 2023 · AS Unit 1

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  18. Q20(c)(i)

    January 2023 · AS Unit 2

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  19. Q16(d)(ii)

    October 2022 · AS Unit 1

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  20. Q12

    June 2022 · AS Unit 1

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All 44 questions on Covalent and dative covalent bonds, as a list
  1. June 2025, AS Unit 1, Q23(b)(i) (1 mark): Describe covalent bonding. (1)
  2. June 2025, AS Unit 1, Q23(b)(ii) (3 marks): Methane, ammonia and water are covalently bonded compounds. Draw the dot-and-cross diagrams for the molecules of methane (CH4), ammonia (NH3) and water (H2O). (
  3. January 2025, AS Unit 1, Q26(b) (2 marks): Molecules of S2F10 consist of two SF5 units linked by a S S bond. Complete the dot‑and‑cross diagram of S2F10 , showing the outer shell electrons. Use dots ()
  4. January 2025, AS Unit 1, Q26(c) (2 marks): Draw a dot‑and‑cross diagram of SF4, showing all the outer shell electrons. Use dots () for the sulfur electrons and crosses (×) for the fluorine electrons. (2
  5. October 2024, AS Unit 1, Q21(b)(ii) (3 marks): Draw the dot‑and‑cross diagram for Al2Cl6 . Use dots (•) for the electrons of aluminium and crosses (×) for the electrons of chlorine. (3)
  6. October 2024, Unit 5, Q18(b)(i) (2 marks): The dot-and-cross diagram for the thiocyanate ion can be drawn in more than one way. For example, the negative charge can be on the nitrogen atom as shown. – *
  7. June 2024, AS Unit 2, Q18(a)(i) (2 marks): Complete the dot‑and‑cross diagram for this structure. Use dots (•) for oxygen electrons and crosses (×) for chlorine electrons. (2) Cl O O
  8. June 2024, Unit 4, Q15(a)(i) (2 marks): Complete the table, indicating the type of bonding in the reactants and products of this reaction. (2) Substance SiO2 Mg Mg2Si MgO Bonding type covalent
  9. June 2024 (R), AS Unit 2, Q22(d) (2 marks): Urea, NH2CONH2 , can also be made from ammonia. Complete the dot‑and‑cross diagram for the urea molecule. (2) O C N N H H H H
  10. January 2024, AS Unit 1, Q21(b)(i) (3 marks): Draw a dot‑and‑cross diagram for this molecule. Show outer electrons only. (3)
  11. January 2024, AS Unit 2, Q21(b)(ii) (3 marks): Complete the table to indicate the type(s) of bonding and structure in the species involved in this reaction. (3) Species Bonding Structure Ca(s) covalent giant
  12. October 2023, AS Unit 1, Q5 (1 mark): What types of bonding are present in the compound ammonium chloride, NH4Cl? Ionic Covalent Dative covalent A    B    C    D   
  13. October 2023, AS Unit 1, Q16 (1 mark): A cyclic hydrocarbon has the structure shown. How many pi (π) and sigma (σ) bonds are present in the molecule? pi (π) bonds sigma (σ) bonds A 2 11 B 2 5 C 4 3 D
  14. October 2023, AS Unit 1, Q18(c)(i) (1 mark): Draw a dot-and-cross diagram of the molecule, BeCl2. (1)
  15. October 2023, AS Unit 1, Q18(c)(iii) (2 marks): Draw a diagram to show how two beryllium chloride molecules bond together to form the dimer, Be2Cl4, stating the type of bond involved. (2) Type of bond
  16. January 2023, AS Unit 1, Q23(b)(ii) (2 marks): Nitrogen molecules bind to zeolite using their outer electrons. Draw a dot‑and‑cross diagram of the bonding in a nitrogen molecule. Show outer electrons only. (
  17. January 2023, AS Unit 1, Q25(a)(ii) (2 marks): Aluminium chloride can exist as a dimer formed from two molecules of aluminium trichloride. Draw a diagram of this dimer, showing the bonding between the two mo
  18. January 2023, AS Unit 2, Q20(c)(i) (2 marks): Complete a possible dot-and-cross diagram for N3 Show outer electrons only. (2)   –    N N N       
  19. October 2022, AS Unit 1, Q16(d)(ii) (2 marks): Germane can donate a proton to ammonia, forming the ion GeH3 –. NH3 + GeH4 → NH4 + + GeH3 – –. Show the outer electrons only. Draw a dot‑and‑cross diagram of th
  20. June 2022, AS Unit 1, Q12 (1 mark): At 180 °C, aluminium chloride exists as Al2Cl6 . What is the structure of Al2Cl6 ? − Cl + A Cl Al Cl Cl Al Cl Cl Cl Cl B Cl Al Al Cl Cl Cl Cl Cl Cl C Al Al Cl C
  21. June 2022, AS Unit 1, Q20(c)(i) (2 marks): Draw a dot-and-cross diagram to show the bonding in a molecule of bromine. Only the outer electrons should be shown. (2)
  22. June 2022, AS Unit 1, Q21(a)(i) (2 marks): Describe the covalent bond between a silicon atom and an oxygen atom in silicon dioxide, in terms of the particles involved. (2)
  23. June 2022, AS Unit 1, Q21(a)(ii) (3 marks): Compare and contrast the covalent bonding in carbon dioxide and silicon dioxide in terms of orbital overlap. (3)
  24. January 2022, AS Unit 1, Q22(b)(i) (1 mark): In the elements silicon, phosphorus, sulfur and chlorine, the atoms are joined by covalent bonds. Describe the attraction between the atoms in a covalent bond.
  25. January 2022, AS Unit 1, Q22(c)(i) (2 marks): Complete the dot-and-cross diagram of a molecule of sulfur dichloride. Use dots (•) for the chlorine electrons and crosses (×) for the sulfur electrons. Show th
  26. January 2022, Unit 5, Q13(a) (1 mark): Draw a dot‑and‑cross diagram for arsine, AsH3 . (1)
  27. October 2021, AS Unit 1, Q7(b) (1 mark): Ammonium sulfate is used in the preparation of the double salt. What types of bond are present in ammonium sulfate? (1) A ionic only B covalent and ionic only C
  28. October 2021, AS Unit 1, Q12(b) (2 marks): In the gaseous state, beryllium chloride is molecular. Draw a dot-and-cross diagram to show the bonding in a molecule of beryllium chloride, BeCl2 . (2)
  29. October 2021, AS Unit 1, Q12(c) (2 marks): In the solid state, beryllium chloride forms a polymeric structure. The diagram shows part of this structure. Cl Cl Cl Cl Cl Be Be Be Be Cl Cl Cl Cl Cl The diag
  30. June 2021, AS Unit 1, Q22(c)(i) (1 mark): Draw a dot-and-cross diagram of a PCl4 Show only outer shell electrons. (1)
  31. June 2021, AS Unit 2, Q22(a) (2 marks): Complete the dot-and-cross diagram to show the bonding in phosgene. (2) O C Cl Cl
  32. January 2021, AS Unit 1, Q19(b)(ii) (2 marks): Draw a dot-and-cross diagram to show the bonding in a molecule of SbCl5 . Use dots (•) to represent the Sb electrons, and crosses (x) to represent the Cl electr
  33. January 2021, AS Unit 1, Q19(c)(i) (1 mark): State what is meant by the term dative covalent bond. (1)
  34. January 2021, AS Unit 1, Q19(c)(ii) (1 mark): Complete the diagram to show the dative covalent bonds in Sb2Cl10 . (1) Cl Cl Cl Cl Cl Sb Sb Cl Cl Cl Cl Cl
  35. January 2021, AS Unit 1, Q19(d) (1 mark): Arsenic also forms a pentachloride with the formula AsCl5 . Give one possible reason why nitrogen is the only Group 5 element that does not form a pentachloride
  36. January 2021, AS Unit 2, Q20(b)(i) (3 marks): Explain the type of bonding that occurs between the nitrogen atom and the hydrogen ion, when the positive ion forms. (3)
  37. October 2020, AS Unit 1, Q13 (1 mark): How many lone pairs of electrons are there in the outer shell of the sulfur atom in a molecule of H2S? A zero B one C two D four
  38. October 2020, AS Unit 1, Q19(c)(i) (2 marks): Draw a dot‑and‑cross diagram of the ammonium ion. Use dots (●) for the nitrogen electrons and crosses (×) for the hydrogen electrons. (2)
  39. January 2020, AS Unit 1, Q18(d) (1 mark): Chlorine occurs naturally as a diatomic molecule. Draw a dot-and-cross diagram to show the bonding in a molecule of chlorine. Show outer shell electrons only. (
  40. June 2019, AS Unit 1, Q3 (1 mark): Covalent bonding is best described as the electrostatic attraction between A oppositely charged ions B positive ions and delocalised electrons C a shared pair o
  41. June 2019, AS Unit 1, Q23(a) (1 mark): Draw an electron density map for a molecule of oxygen. (1)
  42. June 2019, AS Unit 1, Q23(c)(i) (2 marks): Complete the dot-and-cross diagram for the POCl3 molecule. Use crosses ( ) for the phosphorus electrons, dots ( ) for the chlorine electrons and circles ( ) for
  43. January 2019, AS Unit 1, Q22(b)(i) (1 mark): Draw a dot-and-cross diagram to show the bonding in a molecule of nitrogen. (1)
  44. January 2019, AS Unit 1, Q24(d)(ii) (2 marks): Describe how two AlCl3 molecules are joined together in the dimer. Include a diagram in your answer. (2)

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