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Equilibria: Edexcel International A Level Chemistry questions

Every Edexcel International A Level Chemistry exam question on 9B Equilibria (specification points 9.9–9.11), 2019–2025, with its mark scheme and examiner’s report.

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4,117 questions

  1. Q11(a)

    June 2025 · AS Unit 2

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  2. Q11(b)

    June 2025 · AS Unit 2

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  3. Q17(c)(ii)

    June 2025 · AS Unit 2

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  4. Q21(e)(iii)

    January 2025 · AS Unit 2

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  5. Q2(a)

    October 2024 · AS Unit 2

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  6. Q2(b)

    October 2024 · AS Unit 2

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  7. Q19(b)(ii)

    October 2024 · AS Unit 2

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  8. Q19(b)

    June 2024 · AS Unit 2

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  9. Q19(c)(i)

    June 2024 · AS Unit 2

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  10. Q19(c)(ii)

    June 2024 · AS Unit 2

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  11. Q19(c)(iv)

    June 2024 · AS Unit 2

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  12. Q19(c)(v)

    June 2024 · AS Unit 2

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  13. Q3(a)(i)

    June 2024 · AS Unit 3

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  14. Q3(b)

    June 2024 · AS Unit 3

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  15. Q19(a)(i)

    June 2024 (R) · AS Unit 2

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  16. Q19(a)(ii)

    June 2024 (R) · AS Unit 2

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  17. Q14

    January 2024 · AS Unit 2

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  18. Q11(a)

    October 2023 · AS Unit 2

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  19. Q11(b)

    October 2023 · AS Unit 2

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  20. Q12

    October 2023 · AS Unit 2

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All 43 questions on Equilibria, as a list
  1. June 2025, AS Unit 2, Q11(a) (1 mark): Which of the following statements must be correct? (1) A the reactions stop B the sum of the masses of sulfur(IV) oxide and oxygen is equal to the mass of sulf
  2. June 2025, AS Unit 2, Q11(b) (1 mark): How does the use of a catalyst affect the equilibrium? (1) A only the rate of the forward reaction increases B the position of equilibrium moves to the right C
  3. June 2025, AS Unit 2, Q17(c)(ii) (4 marks): Methanol can be produced from the captured carbon dioxide by reaction with hydrogen using a copper catalyst. The equation for the reaction is shown. CO2(g) + 3H
  4. January 2025, AS Unit 2, Q21(e)(iii) (5 marks): A one‑step process is being developed. This is carried out at 101 kPa and 800 °C. CH4 + ½O2  CH3OH ΔH = –164.3 kJ mol–1 Deduce how the reaction conditions coul
  5. October 2024, AS Unit 2, Q2(a) (1 mark): What would be the effect of lowering the temperature? (1) A rate increases, yield increases B rate increases, yield decreases C rate decreases, yield increases
  6. October 2024, AS Unit 2, Q2(b) (1 mark): What would be the effect of increasing the pressure? (1) A rate increases, yield increases B rate increases, yield decreases C rate decreases, yield increases D
  7. October 2024, AS Unit 2, Q19(b)(ii) (2 marks): State and explain what happens to the position of equilibrium when sodium hydroxide solution, NaOH(aq), is added to this equilibrium mixture. (2)
  8. June 2024, AS Unit 2, Q19(b) (2 marks): Under these conditions, the conversion of ethene to ethanol is 5 % at equilibrium but the overall yield of ethanol for the process is 95 %. Suggest what happens
  9. June 2024, AS Unit 2, Q19(c)(i) (2 marks): Explain why the temperature used is a compromise. (2)
  10. June 2024, AS Unit 2, Q19(c)(ii) (2 marks): Explain why a manufacturer might suggest a pressure of greater than the compromise pressure of 7 MPa. (2)
  11. June 2024, AS Unit 2, Q19(c)(iv) (1 mark): Give one other reason for not operating the process at a pressure greater than 7 MPa. Do not include safety considerations in your answer. (1)
  12. June 2024, AS Unit 2, Q19(c)(v) (2 marks): Increasing the amount of water in the reaction mixture, without changing the pressure, might also be suggested. Suggest one advantage and one disadvantage of in
  13. June 2024, AS Unit 3, Q3(a)(i) (3 marks): Explain the observations you would make as the amount of chlorine gas in the U‑tube increases. (3)
  14. June 2024, AS Unit 3, Q3(b) (2 marks): Explain what you could do to the U‑tube to result in more brown liquid being observed. (2)
  15. June 2024 (R), AS Unit 2, Q19(a)(i) (2 marks): Explain what you would see on heating the mixture. (2)
  16. June 2024 (R), AS Unit 2, Q19(a)(ii) (2 marks): Explain what you would see on increasing the pressure. (2)
  17. January 2024, AS Unit 2, Q14 (1 mark): Which statement is not true for a system at dynamic equilibrium? A the position of equilibrium is affected by temperature, by pressure and by catalysts B the c
  18. October 2023, AS Unit 2, Q11(a) (1 mark): What is the effect of a decrease in temperature? (1) A rate increases and yield decreases B rate increases and yield increases C rate decreases and yield decrea
  19. October 2023, AS Unit 2, Q11(b) (1 mark): What is the effect of an increase in pressure? (1) A rate increases and yield decreases B rate increases and yield increases C rate decreases and yield decrease
  20. October 2023, AS Unit 2, Q12 (1 mark): A mixture of 1.0 cm3 of 0.20 mol dm–3 potassium chromate(VI) and 5.0 cm3 of 1.0 mol dm–3 sulfuric acid forms the equilibrium shown. 2–(aq) + 2H+(aq)  Cr2O7 2–(
  21. October 2023, AS Unit 2, Q20(c) (3 marks): Between 1960 and 2020 the amount of carbon dioxide in the atmosphere rose from 320 parts per million (ppm) to 420 ppm. The recent rapid increase in the atmosphe
  22. June 2023, AS Unit 3, Q4(d) (2 marks): Dissolving calcium hydroxide in water is an exothermic process. Describe what you would see if the saturated solution of calcium hydroxide was heated from room
  23. January 2023, AS Unit 2, Q22(a)(i) (1 mark): Give the reason why excess steam is used in the first reaction. (1)
  24. January 2023, AS Unit 2, Q22(a)(ii) (1 mark): Predict which of T1 and T2 is the higher temperature. Justify your answer. (1)
  25. January 2023, AS Unit 2, Q22(b)(i) (1 mark): Suggest one reason why CO2 is removed. (1)
  26. January 2023, AS Unit 2, Q22(c) (2 marks): In Stage 2, the hydrogen from Stage 1 reacts with nitrogen (from the air) to produce ammonia. The conditions for this reaction are: • a temperature of 700 K • a
  27. January 2023, AS Unit 2, Q22(f) (2 marks): The NO from the first reaction in Stage 3 is cooled and then converted to nitrogen dioxide, NO2 , by reaction with more O2 . 2NO(g) + O2(g)  2NO2(g) Nitric aci
  28. January 2023, AS Unit 2, Q22(h) (2 marks): Suggest two reasons why it is more profitable to carry out all four stages at the same site, instead of using different sites for each stage in the industrial p
  29. October 2022, AS Unit 2, Q21(a)(ii) (4 marks): Step 2 is a reversible reaction. 2SO2(g) + O2(g)  2SO3(g) ∆H = −196 kJ mol−1 State the effect on the position of equilibrium when the temperature and pressure
  30. June 2022, AS Unit 2, Q11 (1 mark): A mixture of hydrogen and iodine is left in a sealed container at 300 °C until equilibrium is established. H2(g) + I2(g)  2HI(g) The equilibrium mixture is the
  31. June 2022, AS Unit 2, Q18(d) (2 marks): Ethanol can be manufactured by reacting ethene with steam. C2H4(g) + H2O(g)  C2H5OH(g) ΔrH = −45 kJ mol−1 This reaction is usually carried out in industry at 3
  32. January 2022, AS Unit 2, Q18 (1 mark): Which conditions give the highest yield for the forward reaction? NH4Cl(s)  NH3(g) + HCl(g) ΔH = +176 kJ mol−1 A high temperature, high pressure B high tempera
  33. January 2022, AS Unit 2, Q19 (1 mark): Nitrogen dioxide and dinitrogen tetroxide exist in equilibrium. 2NO2(g)  N2O4(g) brown gas colourless gas When an equilibrium is set up in a gas syringe, the m
  34. January 2022, AS Unit 2, Q24(e)(i) (1 mark): Complete the equation for this reversible reaction. State symbols are not required. (1) (NH2)2CO + H2O
  35. October 2021, AS Unit 2, Q22(e)(i) (6 marks): Typical conditions are 300 °C and 60 atm with a catalyst of phosphoric acid. Explain why these conditions are used, by describing the effect of changing the tem
  36. October 2021, AS Unit 2, Q22(f)(ii) (2 marks): Under these conditions, only about 5 % of the ethene is converted into ethanol as it passes over the catalyst. Suggest how the overall yield of this process can
  37. June 2021, AS Unit 2, Q22(b)(i) (4 marks): State and explain how the reaction conditions could be changed to maximise the equilibrium yield of phosgene in this reaction. (4)
  38. January 2021, AS Unit 2, Q19(a) (6 marks): Explain the chemical reasons for the conditions used and why such a low initial yield is acceptable in the industrial process. (6)
  39. October 2020, AS Unit 2, Q17(a)(i) (2 marks): Explain why high pressure is used. (2)
  40. October 2020, AS Unit 2, Q17(a)(ii) (3 marks): Discuss the factors leading to a choice of 250 °C in this process. (3)
  41. January 2020, AS Unit 2, Q18(c)(iii) (2 marks): Explain the effect of increasing the pressure on the equilibrium yield of ammonia. (2)
  42. June 2019, AS Unit 2, Q3 (1 mark): A large amount of P is added to a small amount of Q. A reversible reaction occurs in which P reacts to form Q. P U Q Which graph shows how the concentrations of
  43. June 2019, AS Unit 2, Q4 (1 mark): Which equilibrium shifts to the right-hand side when the pressure in the system decreases at constant temperature? A N2(g) + 3H2(g) U 2NH3(g) B F2(g) + H2(g) U

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